鄱阳湖区PAHs的多介质迁移和归趋模拟

为分析鄱阳湖区PAHs(多环芳烃)的多介质迁移和归趋行为,以可获取模型验证数据的BaP(苯并芘)、BaA(苯并蒽)、Chr()、Pyr(芘)、Fla(荧蒽)、Phe(菲)6种典型PAHs为研究对象,采用逸度模型Level Ⅲ,预测和模拟鄱阳湖区环境多介质中PAHs的分布和归趋状况. 结果表明:鄱阳湖区水相中ρ(BaP)、ρ(BaA)、ρ(Chr)、ρ(Pyr)、ρ(Fla)、ρ(Phe)的计算值分别为0.043 3、0.050 9、0.021 4、0.149 0、0.122 0、0.295 0 μg/L,与实测值基本一致. 气相、土壤相及沉积物相中6种PAHs的计算值与实测值吻合较好,模型可靠. 土壤相和沉积物相中PAHs残留量(以n计)占该区总残留量的92.6%,远高于气相和水相. PAHs在鄱阳湖区多介质中的相间迁移通量以气相→土相、水相→沉积物相、沉积物相→水相为主. 鄱阳湖区各介质中高环PAHs主要源于外来污水和外来废气输入,外来污水输入量(以n计)和外来废气输入量分别占59.4%和33.6%. 中环和低环PAHs主要源于当地的废气排放和外来污水输入. 土壤相和沉积物相是鄱阳湖区PAHs主要的汇,由土壤和沉积物的内源释放而可能引起的二次污染应引起重视.      

大气中过氧化氢的生成、污染特征及其影响因素

过氧化氢(H₂O₂)是自由基的源和汇,是对流层大气中重要的氧化剂. 采用文献研究法对1990年以来H₂O₂的文献进行搜集整理,对其生成途径、污染特征及其影响因素进行了研究. 结果表明:H₂O₂在大气、云水和颗粒物中均有存在,大气中的H₂O₂主要通过O₃和甲醛光解、VOC同OH·/O₃等反应生成. 大气中φ(H₂O₂)一般在nd～8×10-9内波动,晴天φ(H₂O₂)呈早晚低、午后高的日变化特征;φ(H₂O₂)随φ(O₃)、太阳辐射和气温的增加而升高,随φ(NO_x)、φ(VOCs)和相对湿度的升高而降低;H₂O₂氧化SO₂为SO₄2-是液相化学中最重要的反应,可以导致酸沉降以及二次气溶胶浓度的升高. 在气相光化学反应中,H₂O₂/HNO₃(体积分数比)可以指示O₃生成是VOCs控制还是NO_x控制. 今后需对OH·浓度、NO₂和O₃的光解速率等影响H₂O₂关键因素开展监测研究,此外,还需对我国特殊大气环境下H₂O₂对SO₄2-生成的贡献、不同地区H₂O₂/HNO₃指示O₃生成对NO_x或VOCs敏感性等方面开展更多的研究.      

An empirical study of spatial-temporal growth patterns of a voluntary residential green infrastructure program

Voluntary residential green infrastructure (GI) stormwater management retrofit programs can help cities comply with environmental regulations while also improving quality of life. Previous research has identified influential factors in residents’ willingness to adopt GI, but few have simultaneously studied the spatial and temporal dynamics of GI. I use a six-year record of participation in a voluntary residential GI program in Washington DC to explore how neighborhood characteristics and social influence affect GI adoption over time. Statistical regression and Monte Carlo permutation resampling techniques are used to explain the spatial-temporal patterns of growth of the program. I demonstrate empirical evidence that participation location is increasingly determined by the locations of previous participants. These findings suggest that past participants will increasingly influence spatial clustering of GI in the city.     

核电厂防人因失误管理有效性探讨

介绍了核电人因管理的发展历史,在国际核电业界防人因失误管理标准的基础上,结合部分国内外核电厂的防人因失误管理实践,探讨了影响核电厂人因管理的模型,对业界普遍存疑的概念进行了辨析,分析了影响人因管理有效性的关键因素,提出了提高核电厂防人因失误管理有效性的建议以及良好实践。     

Analyzing the relationships between travel mode indicators and the number of passenger transport fatalities at the city level

Objective: A number of efforts have been conducted on travel behavior and transport fatalities at the neighborhood or street level, and they have identified different factors such as roadway characteristics, personal indicators, and design indicators related to transport safety. However, only a limited number of studies have considered the relationship between travel behavior indicators and the number of transport fatalities at the city level. Therefore, this study explores this relationship and how to fill the mentioned gap in current knowledge.

Method: A generalized linear model (GLM) estimates the relationships between different travel mode indicators (e.g., length of motorway per inhabitants, number of motorcycles per inhabitant, percentage of daily trips on foot and by bicycle, percentage of daily trips by public transport) and the number of passenger transport fatalities. Because this city-level model is developed using data sets from different cities all over the world, the impacts of gross domestic product (GDP) are also included in the model.

Conclusions: Overall, the results imply that the percentage of daily trips by public transport, the percentage of daily trips on foot and by bicycle, and the GDP per inhabitant have negative relationships with the number of passenger transport fatalities, whereas motorway length and the number of motorcycles have positive relationships with the number of passenger transport fatalities.     

The more I want,the less I have left to give: The moderating role of psychological entitlement on the relationship between psychological contract violation,depressive mood states,and citizenship behavior

Research has emphasized the negative effects of organizations' broken promises and failed obligations on employee attitudes and behaviors. However, not all employees respond in the same manner. This paper integrates research on psychological contracts and psychological entitlement to examine how individuals with exceedingly high demands and expectations react to a perceived letdown by the organization. Drawing on conservation of resources theory, we argue that a psychological contract violation is associated with employee depressive mood states, which, in turn, influence the amount of citizenship behavior displayed. We further posit that psychological entitlement moderates the link between contract violation and depressive mood states. Using Hayes' PROCESS macro to assess a moderated mediation model, findings from a multi‐source field study support our predictions. This research contributes to the work on psychological contracts and psychological entitlement on multiple fronts. Suggestions for future research and practical implications for managers are discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

Drink driving and risky behavior among university students in southwestern Nigeria—Implications for policy development

Background: Drink driving contributes significantly to road traffic injuries. Little is known about the relationship between drink driving and other high-risk behaviors in non-Western countries. The study aimed to assess the relationship between drink driving and other risky behaviors including making phone calls, sending text messages, nonuse of protective gear, and driving against traffic.

Methods: A cross-sectional survey of risky behavior among undergraduates was conducted. A stratified random sampling method was used to identify young undergraduates who had driven a motorized vehicle in the past year. The Alcohol Use Disorder Identification Test (AUDIT) and other tools developed by researchers were used to identify the risky behaviors.

Results: Of 431 respondents, 10.7% had engaged in drink driving in the past 12 months. The most common risky behavior was making phone calls (63.7%), followed by nonuse of helmets (54.7%), driving against traffic (49.2%), nonuse of seat belts (46.8%), and sending text messages (26.1%). Alcohol use was significantly associated with making phone calls (U = 1.148; P < .0001), sending text messages (U = 1.598; P = .021), nonuse of helmets (U = 1.147; P < .0001), driving against traffic (U = 1.234; P < .0001), and nonuse of seat belts (U = 3.233; P = .001). Drink driving was associated with all risky behaviors except nonuse of seat belts (U = 1.842; P = .065).

Conclusion: Alcohol use and drink driving were associated with multiple risky driving behaviors. This provides useful insight for policy development and presents additional challenges for traffic injury prevention.     

从行为科学角度浅论家具生产企业安全管理

家具生产企业的安全状况如何,直接影响企业的经济效益,影响着生产员工的情绪稳定.本文旨在运用行为科学理论,剖析家具生产企业事故发生的原因,并提出了避免出现安全事故的相应措施,促进家具企业的健康发展.     

人群疏散中"非适应性"行为的研究

本文从人与人的相互作用和社会学、心理学的角度,对人群疏散中“非适应性”行为的理论、计算机模型、模拟原理等进行了较为深入的研究,并以具体实例说明了Building Exodus软件在人群疏散模拟分析中的具体应用,为完善该研究方向的计算机模型和促进软件的开发提供理论和方法的指导.文章得出的结论是：“非适应”人群行为的研究需要从心理学和社会学的角度建立人群中个人行为与社会行为的理论框架.“非适应”人群行为的研究方法必须与紧急情况相结合,而紧急情况是一个由多个人员组成的复杂系统,大量人群环境的模拟需要涉及到人与人之间,人与环境之间的相互作用.     

钢筋混凝土桥墩刚度和强度折减系数确定

为了解析地预测钢筋混凝土桥墩在反复荷载作用下的非线性滞回特性 ,笔者运用实验中得到的力 -位移滞回曲线 ,对随轴压比、配筋率和配箍率的变化而变化的刚度和强度折减系数 ,进行了回归分析 ,并提出了计算表达式。按照笔者的理论力 -位移滞回模型 ,能预测现存钢筋混凝土桥墩的刚度和强度折减情况 ,对桥梁钢筋混凝土桥墩的可靠性和抗震性能的检验 ,有实用价值