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排序方式: 共有218条查询结果,搜索用时 15 毫秒
61.
62.
Asko Noormets Olevi Kull Mark E. Kubiske 《Environmental pollution (Barking, Essex : 1987)》2010,158(4):992-999
The effect of elevated CO2 and O3 on apparent quantum yield (?), maximum photosynthesis (Pmax), carboxylation efficiency (Vcmax) and electron transport capacity (Jmax) at different canopy locations was studied in two aspen (Populus tremuloides) clones of contrasting O3 tolerance. Local light climate at every leaf was characterized as fraction of above-canopy photosynthetic photon flux density (%PPFD). Elevated CO2 alone did not affect ? or Pmax, and increased Jmax in the O3-sensitive, but not in the O3-tolerant clone. Elevated O3 decreased leaf chlorophyll content and all photosynthetic parameters, particularly in the lower canopy, and the negative impact of O3 increased through time. Significant interaction effect, whereby the negative impact of elevated O3 was exaggerated by elevated CO2 was seen in Chl, N and Jmax, and occurred in both O3-tolerant and O3-sensitive clones. The clonal differences in the level of CO2 × O3 interaction suggest a relationship between photosynthetic acclimation and background O3 concentration. 相似文献
63.
Minori Uchimiya Leonid Gorb Mohammad M. Qasim 《Environmental pollution (Barking, Essex : 1987)》2010,158(10):3048-3053
Extensive studies have been conducted in the past decades to predict the environmental abiotic and biotic redox fate of nitroaromatic and nitramine explosives. However, surprisingly little information is available on one-electron standard reduction potentials (Eo(R-NO2/R-NO2−)). The Eo(R-NO2/R-NO2−) is an essential thermodynamic parameter for predicting the rate and extent of reductive transformation for energetic residues. In this study, experimental (linear free energy relationships) and theoretical (ab initio calculation) approaches were employed to determine Eo(R-NO2/R-NO2−) for nitroaromatic, (caged) cyclic nitramine, and nitroimino explosives that are found in military installations or are emerging contaminants. The results indicate a close agreement between experimental and theoretical Eo(R-NO2/R-NO2−) and suggest a key trend: Eo(R-NO2/R-NO2−) value decreases from di- and tri-nitroaromatic (e.g., 2,4-dinitroanisole) to nitramine (e.g., RDX) to nitroimino compound (e.g., nitroguanidine). The observed trend in Eo(R-NO2/R-NO2−) agrees with reported rate trends for reductive degradation, suggesting a thermodynamic control on the reduction rate under anoxic/suboxic conditions. 相似文献
64.
Tara Sankar Pathak Jin San Kim Se-Jong Lee Dae-Jin Baek Ki-Jung Paeng 《Journal of Polymers and the Environment》2008,16(3):198-204
Alginic acid and metal alginates are prepared from fresh algae using extraction method. A FTIR spectrum indicates that alginic
acid is converted into the metal alginate. Comparing calcium and cobalt alginates, asymmetric stretching of free carboxyl
group of calcium alginate at 1630 cm−1 is shifted to 1585 cm−1 in cobalt alginate, due to the change of charge density, radius and atomic weight of the cation, creating a new environment
around the carbonyl group. The strong exothermic peak of alginic acid in DSC thermogram indicates the decomposition of biopolymer,
whereas strong exothermic peak of metal alginate in DSC thermogram attributed to the decomposition of biopolymer and formation
of respective carbonate. Based on DSC study, the decomposition of cobalt alginate occurs at higher temperature comparing to
those of sodium and calcium alginate, which may conclude into the higher stability of cobalt alginate. TGA results reveal
that, cobalt alginate is more stable than calcium and sodium alginate at 300 °C temperature. Surface morphology (at same magnification),
as well as porosity (%) and pore size distribution results change with metals present in different metal alginates. 相似文献
65.
Xiaoping Hu Satoshi Osaki Miki Hayashi Mureo Kaku Susumu Katuen Hiroshi Kobayashi Fusako Kawai 《Journal of Polymers and the Environment》2008,16(2):103-108
We intended to find thermophilic degraders of terephthalate-containing Biomax® films. Films in mesh bags were buried in composts (inside temperature: approximately 55–60 °C), resulting in the degradation of them in 2 weeks. Fluorescent microscopy of films recovered from composts showed that microorganisms gradually covered the surface of a film during composting. DGGE analysis of microorganisms on the composted film indicated the presence of Bacillus species as main species (approximately 80% of microbial flora) and actinomycetes (approximately 10–20%) as the second major flora. Isolation of Biomax®-utilizing bacteria was focused on these two genera: two actinomycetes and one Bacillus species were isolated as pure best degraders from the composted polymer films, which were fragmented into small pieces. All the strains were thermophilic and identified, based on their 16S rDNA analyses. Degradation of polymer films was confirmed by (1) accelerated fragmentation of films in composts, compared with a control (no inoculum) and resultant decrease in molecular weights, (2) growth in a powdered Biomax® medium, compared with a control without powdered Biomax®, and (3) production of terephthalate in a powdered Biomax® medium. In this way, we concluded that these bacteria were useful for degradation of thermostable Biomax® products. 相似文献
66.
Growth, accumulation and intracellular speciation and distribution of copper (Cu) in Sesbania drummondii was studied using scanning-electron microscopy (SEM), X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS). The growth of seedlings was assessed in terms of biomass accumulation. The growth of the seedling was enhanced by 73.5% at a low Cu concentration (50 mg l−1) compared to the control treatment. Additionally, seedling growth was inhibited by 18% at 300 mg l−1 Cu with respect to the control. Copper concentration in roots and shoots was increased with increasing Cu concentration in the growth solution. The accumulation of Cu was found to be higher in roots than in the shoots. At a concentration of 300 mg l−1 Cu, the roots accumulated 27,440 mg Cu kg−1 dry weight (dw) while shoots accumulated 1282 mg Cu kg−1 dw. Seedlings were assessed for photosynthetic activity by measuring chlorophyll a fluorescence parameters: Fv/Fm and Fv/F0 values. Photosynthetic integrity was not affected by any of the Cu treatments. The X-ray absorption spectroscopic (XAS) studies showed that Cu was predominantly present as Cu(II) in Sesbania tissue. In addition, from the XAS studies it was shown that the Cu exists in a mixture of different coordination states consisting of Cu bound to sugars and small organic acids with some possible precipitated copper oxide. From the EXAFS studies, the coordination of Cu was determined to have four equatorial oxygen(nitrogen) ligands at 1.96 Å and two axial oxygen ligands at 2.31 Å. Scanning-electron microscopy studies revealed the distribution of Cu within the seedlings tissues, predominantly accumulated in the cortical and vascular (xylem) regions of root tissues. In the stem, most of the Cu was found within the xylem tissue. However, the deposition of Cu within the leaf tissues was in the parenchyma. The present study demonstrates the mechanisms employed by S. drummondii for Cu uptake and its biotransformation. 相似文献
67.
A.?K.?MohantyEmail author P.?Tummala W.?Liu M.?Misra P.?V.?Mulukutla L.?T.?Drzal 《Journal of Polymers and the Environment》2005,13(3):279-285
Biocomposites from soy based bioplastic and chopped industrial hemp fiber were fabricated using twin-screw extrusion and injection molding process. Soy based bioplastics were prepared through cooking with plasticizer and blending with biodegradable poly(ester amide). Mechanical, thermal properties and fracture surface morphology of the “green”/biocomposites were evaluated with universal testing system (UTS), dynamic mechanical analysis (DMA), Environmental Scanning Electron Microscopy (ESEM). It was found that the tensile strength and modulus, flexural strength and modulus, impact strength and heat deflection temperature of industrial hemp fiber reinforced biocomposites significantly improved. The fracture surfaces showed no signs of matrix on the fiber surface suggesting poor interfacial adhesion. 相似文献
68.
Urban geochemistry: research strategies to assist risk assessment and remediation of brownfield sites in urban areas 总被引:1,自引:1,他引:0
Thornton I Farago ME Thums CR Parrish RR McGill RA Breward N Fortey NJ Simpson P Young SD Tye AM Crout NM Hough RL Watt J 《Environmental geochemistry and health》2008,30(6):565-576
Urban geochemical maps of Wolverhampton and Nottingham, based on multielement analysis of surface soils, have shown distribution
patterns of “total” metals concentrations relating to past and present industrial and domestic land use and transport systems.
Several methods have been used to estimate the solubility and potential bioavailability of metals, their mineral forms and
potential risks to urban population groups. These include sequential chemical extraction, soil pore water extraction and analysis,
mineralogical analysis by scanning electron microscopy, source apportionment by lead isotope analysis and the development
of models to predict metal uptake by homegrown vegetables to provide an estimate of risk from metal consumption and exposure.
The results from these research strategies have been integrated with a geographical information system (GIS) to provide data
for future land-use planning. 相似文献
69.
This study evaluates the possibility of using contaminated soil by treated tannery wastewater and the use of tannery sludge in agriculture. The plants of Vigna radiata var. PDM 54 grown on contaminated soil and irrigated with ground water have not shown the translocation of toxic metal (Cr) in the upper part. The biomass of the plant increased when irrigated with treated tannery wastewater compared to ground water, whereas no significant change was observed in chlorophyll and protein contents. In both the varieties (var. PDM 54 and var. NM 1) of V. radiata grown on tannery sludge amendments, the growth parameters exhibited a pronounced positive growth response up to 35% tannery sludge amendments compared with the plants grown on garden soil. Despite the Cr accumulation at lower amendments, no toxicity symptoms were observed in both the varieties of the plants. Higher amendments affected various growth parameters, NR activity, and carbohydrate content of the plants. The results suggest that the plants of V. radiata (var. PDM 54) may be grown on contaminated soil or lower sludge amendments and irrigated with ground water. No translocation of toxic metal Cr was found in the seeds of the plants grown in up to 25% tannery sludge. However, periodical monitoring is required before the consumption of seeds. Overall, the results showed that plant growth patterns were influenced to some extent by the level of soil contamination and the water used for irrigation. 相似文献
70.
淹没式膜生物反应器中膜污染机理的研究 总被引:6,自引:2,他引:4
为减小微生物絮体对膜的污染,设计了一种具有沉降室的膜生物反应器,膜A与膜B分别淹没在上清液和污泥混合液中以相同的抽吸方式运行,与预期结果相反,膜A比膜B的污染速度还快.为探讨膜污染机理,考察了污泥混合液中不同组分对膜污染的影响,利用扫描电镜和原子力显微镜分析了膜面污染层的特征.结果发现,在污泥混合液与上清液中膜面污染层在微观结构上存在显差异,其方差平均粗糙度Rms分别为132.3nm和75.2nm.经膜污染机理分析认为:微生物絮体和大分子有机物会在膜面形成污染层,该污染层作为“二次膜”影响膜过滤性能.上清液中细小的微生物絮体和大分子有机物形成的污染层相对致密,会加剧膜污染. 相似文献