酸性环境下Q2黄土压缩特性试验研究∗

针对酸性污染土物理力学性质恶化的现象,采用室内人工模拟受酸液污染土样的方法,开展土常规试验、压缩试验探究Q2黄土在酸液浸泡时间和酸液浓度双因素作用下,试样孔隙比、含水率等基本物理及压缩系数、压缩模量等指标和压缩e—p曲线的变化规律,以及水-酸耦合作用对黄土压缩性的影响规律。结果表明:浸泡时间一定时,随酸液浓度增大,含水率、孔隙比、压缩系数在逐渐增大,压缩模量在减小。浸泡12 d时,酸液浓度0.1 mol/L增加至3 mol/L,压缩系数a1-2由0.355 MPa-1增大到1.275 MPa-1,压缩模量Es1-2由5.580 MPa减小至1.855 MPa;酸液浓度一定时,随浸泡时间延长,含水率、孔隙比、压缩系数在逐渐增大,压缩模量在减小。酸液浓度3 mol/L时,浸泡时间从1 d至12 d,压缩系数a1-2由0.308 MPa-1增大到1.275 MPa-1,压缩模量Es1-2由6.301 MPa减小至1.855MPa;水-酸耦合作用提高了黄土压缩性,且在充分浸泡条件下,酸液对黄土压缩性的影响远大于水的影响。研究结果可为酸蚀黄土区工程建设提供相关参考。     

三峡水域氮磷污染对水华暴发/消涨行为的协同影响

藻类生长/消退与藻类对氮、磷的吸收比率ω₁和ω₂相关,ω_i正/负增长分别对应藻类生长时从水体中吸收氮磷的加速阶段和藻类分解时向水体释放氮磷的消退阶段,在特定磷氮比(P/N)范围出现ω₁和ω₂同时突变有可能从理论上解释水华的暴发/消退.根据三峡流域实测数据和藻类吸收氮磷的关联函数,在三维空间表征了随氮磷浓度协同作用导致的ω₁和ω₂在特定P/N区域同时突变所揭示出的水华暴发/消退现象,从而直观、合理地解释了:①适当的P/N范围才可能暴发水华;②如果P/N区间同时满足ω₁和ω₂正向急剧增长的要求,藻类疯长,而ω₁和ω₂同时朝负值方向急剧降低,水华消退;③水华暴发/消退的速率为同一数量级,且水华暴发/消退在氮、磷浓度达到某一敏感范围时将表现出明显的周期性振荡.这些性态可能更真实地反映出水华暴发/消退时藻类对营养盐的吸收/释放机理.     

Combined effect of nonionic surfactant Tween 80 and DOM on the behaviors of PAHs in soil--water system

Batch experiments were performed to examine the desorption behavior of phenanthrene and pyrene in soil–water system in the presence of nonionic surfactant Tween 80 and dissolved organic matter (DOM) derived from pig manure or pig manure compost. Addition of 150 mg l⁻¹ Tween 80 desorbed 5.8% and 2.1% of phenanthrene and pyrene from soil into aqueous phase, respectively, while the addition of both Tween 80 and DOM derived from pig manure compost and pig manure could further enhance the desorption of phenanthrene to 15.8% and 16.2%, respectively, and 6.4% and 10.9%, respectively, for pyrene. In addition, our finding also suggested that subsequent addition of Tween 80 into the soil–water system could further enhance PAHs desorption. The enhancement effect of the co-existence of Tween 80 and DOM was more than the additive effect of the Tween 80 and DOM individually. It is likely that the formation of DOM–surfactant complex in the soil–water system may be a possible reason to explain such desorption enhancement phenomenon. Therefore, it is anticipated that the coexistence of both Tween 80 and DOM derived from pig manure or pig manure compost in soil environment will enhance the bioavailability of PAHs as well as other hydrophobic organic contaminants (HOCs) by enhancing the desorption during remediation process.     

长江流域交通发展问题探析

长江流域是我国经济最活跃,各种要素配置最具有潜力的地区,但在强烈的发展势头下,也存在着不少问题。通过对长江流域交通运输业全面的分析,对长江流域地区交通运输所面临的问题作了具体的剖析,认为交通运输就是长江流域地区阻碍经济社会可持续发展的主要因素之一,主要表现在没有形成综合交通运输网络,东西向交通运输方式单一;交通运输建设滞后于经济发展;流域内区域差异明显阻碍了区域一体化发展等方面,最后根据存在的问题提出了几点建议和发展措施。     

灰色聚类法在堆肥腐熟度评价中的应用

提出运用灰色聚类法综合评价堆肥腐熟度.选取表观指数、碳氮比变化率、平均耗氧速率、氨氮变化率、高温嗜粪菌计数及霉菌计数6项评价指标,对浦东、塘湾、玉垒、丹阳4个厂家的堆肥产品进行了聚类分析并给出了评价结果.其中,浦东、玉垒、丹阳3个厂家的堆肥产品归入Ⅱ级较好腐熟,而塘湾厂家的产品归入Ⅲ级基本腐熟.通过与模糊综合评价法比较可知,灰色聚类法不仅具有模糊综合评价法的优点,又克服了其不足之处,是堆肥腐熟度评价的一种好方法.     

The influence of gas storage parameters on gas emission rate from borehole

Gas emission rate from borehole is one of the most important indexes for the coal and gas outburst prediction. The mathematical model of gas flow in the coal seam, gas flow into the measuring chamber, gas pressure change in the measuring chamber, and gas flow out of the chamber through the pipe is established. Gas migration in the coal seam, gas pressure in borehole chamber and gas flow in pipe is simulated using the finite difference method. Gas emission rate is obtained under dynamic boundary conditions. The influence of gas storage parameters on gas emission rate from borehole is analyzed. Results show that: the gas pressure and the permeability coefficient have great impacts on the value of gas flow quantity in borehole. The larger the original gas pressure of coal seam and the permeability coefficient of coal seam are, the greater the maximum value of gas emission rate form borehole and the later the maximum appears.     

基于模糊-理想点法的海下采场顶板稳定性分析

为准确评价复杂地质条件下海下采场顶板的稳定性,提出将模糊数学中的隶属度与理想点法相结合的模型。针对海下采场的特殊地质条件,综合考虑水文地质因素、工程地质因素、采场结构因素以及其他因素4个方面,选取9个评价指标。通过对指标进行隶属度化处理,由变异系数法确定指标权重,建立顶板分级模型。最后,根据三山岛金矿5个采场现场调查以及室内试验获得的指标数据,应用该模型对顶板稳定级别进行评判。结果表明,该模型的评判等级结果与工程实际相符,从而验证模型可用于海下采场顶板的稳定性分析。     

The Empirical Analysis of the Impacts of Income Distribution Gap on Consumption Demand： Based on the Statistic Data of Chinese Urban Residents in 2000-2010

This paper analyzes the impact of income distribution gap on consumption demand from a theoretical view, and draws the conclusion that there is an inverse relationship between income distribution gap a...     

Numerical study of choked two-phase flow of hydrocarbons fluids through orifices

Valves and orifices are the most widely devices of flow control used in oil and gas industry. In particular, they are installed in relief piping system in order to control the discharge flow during potential plant overpressuring scenarios, thus ensuring plant safety. It is a common practice to flow liquid and gas mixtures through such restriction devices.Rigorous models are available to precisely size pressure relief devices operating in single phase flow; however for two-phase flow, no models are considered sufficiently reliable for predicting the relevant flow conditions.In the present paper, two-phase flow of hydrocarbons fluids through an orifice under critical conditions has been numerically investigated.The existing literature has been analyzed and data on two-phase flow of highly volatile mixtures of hydrocarbons through openings have been collected. A comparison has been carried out with numerical simulations carried out by the multiphase flow simulation tool OLGA by SPT.The Henry–Fauske model has been used as orifice choke model and the orifice discharge flow coefficient, required as input by OLGA, has been calculated by Chisholm's model.Comparison between OLGA's results and experimental data shows that Henry–Fauske model markedly underestimates the mass flow rate through the orifice, if Chisholm's model is used to calculate discharge coefficient. It was found that the error of the model could be minimized using different values of orifice discharge coefficient (C_d).A new discharge flow coefficient model, suitable for choked two-phase flow across orifices, is proposed in this study and it has been determined to match the above mentioned experimental measurements.     

分子电性距离矢量预测多氯萘的正辛醇/空气分配系数

应用分子电性距离矢量(MEDV)对多氯萘(PCNs)的76种同系物进行结构表征,通过多元线性回归方法建立了PCNs的正辛醇/空气分配系数(lgKoA)与MEDV之间的定量结构一性质关系(QSPR),该模型具有显著的相关性(n=24,R=0.997,SD=0.088,F=417.546).采用逐步回归的方法(SMR)从原...