北京市生活垃圾处理的环境影响评价

目前北京市生活垃圾产生量不断增加,处理设施能力日渐不足,生活垃圾管理正面临着减量化与资源化必然趋势。在未来5～10年内,堆肥处理、焚烧处理和综合处理等方式将取代卫生填埋成为北京市垃圾处理的主要方式。本研究采用生命周期评价的方法,对北京市4处垃圾处理设施采用的不同工艺（卫生填埋、好氧堆肥、焚烧处理和综合处理）的环境影响进行比较。评价结果表明4,种处理方式中填埋、堆肥、焚烧和综合处理的环境影响负荷分别为4.82×10-2、1.10×10-21、.31×10-1和2.31×10-2,焚烧处理的总环境影响潜值最大,填埋处理次之,综合处理再次,堆肥处理最小。4种处理方式的资源耗竭系数分别为-2.39×10-51、.11×10-5、-3.45×10-4和-1.04×10-6,焚烧处理的资源耗竭系数最小。     

激光类全新耗材和再生耗材对环境影响的生命周期评价

以激光类打印耗材——TN350为例,应用生命周期评价方法,对全新TN350和再生TN350进行生命周期资源消耗与污染物排放清单分析,在此基础上进行生命周期环境影响评价。重点考虑6种环境影响类型：全球变暖、酸化、富营养化、光化学臭氧、固体废弃物、工业烟尘和粉尘。结果表明,相对于全新TN350,再生TN350的原油消耗量削...     

Life cycle toxicity assessment of pesticides used in integrated and organic production of oranges in the Comunidad Valenciana, Spain

The relative impacts of 25 pesticides including acaricides, fungicides, herbicides, insecticides, and post-harvest fungicides, used in the production of oranges in Spain were assessed with current life cycle impact assessment (LCIA) tools. Chemical specific concentrations were combined with pesticide emission data and information on chemical toxicity to assess human toxicity and freshwater ecotoxicity impacts. As a case study, the relative impacts of two orange production systems in the region of Valencia, integrated pest management (IP) and organic production (OP), were assessed. The evaluation of active ingredients showed that on average acaricides have the highest human toxicity impact scores, while for freshwater ecotoxicity insecticides show the highest impact. In both impact categories the lowest impact scores were calculated for herbicides. In the production of 1 kg of orange fruits, where several kinds of pesticides are combined, results show that post-harvest fungicides can contribute more than 95% to the aggregate human toxicity impacts. More than 85% of aquatic ecotoxicity is generated by fungicides applied before harvest. The potential to reduce impacts on freshwater ecosystems is seven orders of magnitude, while impacts on human health can be reduced by two orders of magnitude. Hence, this stresses the importance of a careful pre-selection of active ingredients. In both impact categories, organic production represents the least toxic pest-control method.     

Influence of aggregated particles on biodegradation activities for dimethylarsinic acid (DMA) in Lake Kahokugata

Aquatic arsenic cycles mainly depend on microbial activities that change the arsenic chemical forms and influence human health and organism activities. The microbial aggregates degrading organic matter are significantly related to the turnover between inorganic arsenic and organoarsenic compounds. We investigated the effects of microbial aggregates on organoarsenic mineralization in Lake Kahokugata using lake water samples spiked with dimethylarsinic acid (DMA). The lake water samples converted 1 μmol L⁻¹ of DMA to inorganic arsenic for 28 d only under anaerobic and dark conditions in the presence of microbial activities. During the DMA mineralization process, organic aggregates >5.0 μm with bacterial colonization increased the densities. When the organic aggregates >5.0 μm were eliminated from the lake water samples using filters, the degradation activities were reduced. DMA in the lake water would be mineralized by the microbial aggregates under anaerobic and dark conditions. Moreover, DMA amendment enhanced the degradation activities in the lake water samples, which mineralized 50 μmol L⁻¹ of DMA. The DMA-amended aggregates >5.0 μm completely degraded 1 μmol L⁻¹ of DMA with a shorter incubation time of 7 d. The supplement of KNO₃ and NaHCO₃ to lake water samples also shortened the DMA-degradation period. Presumably, the bacterial aggregates involved in the chemical heterotrophic process would contribute to the DMA-biodegradation process in Lake Kahokugata, which is induced by the DMA amendment.     

Modeling biogeochemical processes of phosphorus for global food supply

Harvests of crops, their trade and consumption, soil erosion, fertilization and recycling of organic waste generate fluxes of phosphorus in and out of the soil that continuously change the worldwide spatial distribution of total phosphorus in arable soils. Furthermore, due to variability in the properties of the virgin soils and the different histories of agricultural practices, on a planetary scale, the distribution of total soil phosphorus is very heterogeneous. There are two key relationships that determine how this distribution and its change over time affect crop yields. One is the relationship between total soil phosphorus and bioavailable soil phosphorus and the second is the relationship between bioavailable soil phosphorus and yields. Both of these depend on environmental variables such as soil properties and climate. We propose a model in which these relationships are described probabilistically and integrated with the dynamic feedbacks of P cycling in the human ecosystem. The model we propose is a first step towards evaluating the large-scale effects of different nutrient management scenarios. One application of particular interest is to evaluate the vulnerability of different regions to an increased scarcity in P mineral fertilizers. Another is to evaluate different regions’ deficiency in total soil phosphorus compared with the level at which they could sustain their maximum potential yield without external mineral inputs of phosphorus but solely by recycling organic matter to close the nutrient cycle.     

二元水循环模式下的水生态系统服务功能评价

在强人类活动干预下,流域水循环越来越呈现出“自然-人工”二元驱动结构,相应的水生态系统服务功能也呈现出明显的二元特征,这对其驱动机制和定量评价研究提出新的挑战。在深入分析流域二元水循环及水生态系统服务功能内涵的基础上,综合国内外研究现状,分析了当前研究中存在的不足;分析了自然水循环及其伴生过程和社会水循环过程对水生态系统服务功能的驱动机制,提出基于单过程单目标的四边形计算模式;基于二元水循环的多过程间多向反馈特征对水生态系统服务功能的交叉影响,构建了适用于河流、水库以及湿地等不同类型的水生态系统服务功能二元水循环评估指标体系;结合当前研究中存在的问题,提出需重点加强水生态系统服务功能评价方法以及驱动因子等方面的基础研究。     

Designing a supercritical steam cycle to integrate the energy requirements of CO2 amine scrubbing

Absorption by chemical solvents combined with CO₂ long-term storage appears to offer interesting and commercial applicable CO₂ capture technology. However one of the main disadvantages is related to the large quantities of heat required to regenerate the amine solvent that means an important power plant efficiency penalty. Different studies have analyzed alternatives to reduce the heat duty on the reboiler and the thermal integration requirements on existing power cycles. In these studies integration principles have been well set up, but there is a lack of information about how to achieve an integrated design and the thermal balances of the modified cycle flowsheet. This paper proposes and provides details about a set of modifications of a supercritical steam cycle to overcome the energy requirements through energetic integration with the aim of reducing the efficiency and power output penalty associated with CO₂ capture process. Modifications include a new designed low-pressure heater flowsheet to take advantage of the CO₂ compression cooling for postcombustion systems and integration of amine reboiler into a steam cycle. It has been carried out several simulations in order to obtain power plant performance depending on sorbent regeneration requirements.     

Life cycle assessment of a pulverized coal power plant with post-combustion capture, transport and storage of CO2

In this study the methodology of life cycle assessment has been used to assess the environmental impacts of three pulverized coal fired electricity supply chains with and without carbon capture and storage (CCS) on a cradle to grave basis. The chain with CCS comprises post-combustion CO₂ capture with monoethanolamine, compression, transport by pipeline and storage in a geological reservoir. The two reference chains represent sub-critical and state-of-the-art ultra supercritical pulverized coal fired electricity generation. For the three chains we have constructed a detailed greenhouse gas (GHG) balance, and disclosed environmental trade-offs and co-benefits due to CO₂ capture, transport and storage. Results show that, due to CCS, the GHG emissions per kWh are reduced substantially to 243 g/kWh. This is a reduction of 78 and 71% compared to the sub-critical and state-of-the-art power plant, respectively. The removal of CO₂ is partially offset by increased GHG emissions in up- and downstream processes, to a small extent (0.7 g/kWh) caused by the CCS infrastructure. An environmental co-benefit is expected following from the deeper reduction of hydrogen fluoride and hydrogen chloride emissions. Most notable environmental trade-offs are the increase in human toxicity, ozone layer depletion and fresh water ecotoxicity potential for which the CCS chain is outperformed by both other chains. The state-of-the-art power plant without CCS also shows a better score for the eutrophication, acidification and photochemical oxidation potential despite the deeper reduction of SO_x and NO_x in the CCS power plant. These reductions are offset by increased emissions in the life cycle due to the energy penalty and a factor five increase in NH₃ emissions.     

Predicting sublethal effects of herbicides on terrestrial non-crop plant species in the field from greenhouse data

Guidelines provided by OECD and EPPO allow the use of data obtained in greenhouse experiments in the risk assessment for pesticides to non-target terrestrial plants in the field. The present study was undertaken to investigate the predictability of effects on field-grown plants using greenhouse data. In addition, the influence of plant development stage on plant sensitivity and herbicide efficacy, the influence of the surrounding vegetation on individual plant sensitivity and of sublethal herbicide doses on the biomass, recovery and reproduction of non-crop plants was studied. Results show that in the future, it might well be possible to translate results from greenhouse experiments to field situations, given sufficient experimental data. The results also suggest consequences at the population level. Even when only marginal effects on the biomass of non-target plants are expected, their seed production and thereby survival at the population level may be negatively affected.     

Comparison of regression coefficient and GIS-based methodologies for regional estimates of forest soil carbon stocks

Estimates of forest soil organic carbon (SOC) have applications in carbon science, soil quality studies, carbon sequestration technologies, and carbon trading. Forest SOC has been modeled using a regression coefficient methodology that applies mean SOC densities (mass/area) to broad forest regions. A higher resolution model is based on an approach that employs a geographic information system (GIS) with soil databases and satellite-derived landcover images. Despite this advancement, the regression approach remains the basis of current state and federal level greenhouse gas inventories. Both approaches are analyzed in detail for Wisconsin forest soils from 1983 to 2001, applying rigorous error-fixing algorithms to soil databases. Resulting SOC stock estimates are 20% larger when determined using the GIS method rather than the regression approach. Average annual rates of increase in SOC stocks are 3.6 and 1.0 million metric tons of carbon per year for the GIS and regression approaches respectively.