全文获取类型
收费全文 | 75篇 |
免费 | 2篇 |
国内免费 | 30篇 |
专业分类
安全科学 | 11篇 |
环保管理 | 15篇 |
综合类 | 41篇 |
基础理论 | 17篇 |
污染及防治 | 18篇 |
评价与监测 | 1篇 |
社会与环境 | 3篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2013年 | 2篇 |
2012年 | 6篇 |
2011年 | 9篇 |
2010年 | 2篇 |
2009年 | 6篇 |
2008年 | 5篇 |
2007年 | 3篇 |
2006年 | 2篇 |
2005年 | 2篇 |
2004年 | 4篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
排序方式: 共有107条查询结果,搜索用时 15 毫秒
101.
The long term exposure of arsenic via drinking water has resulted in wide occurrence of arsenisim globally, and the oxidation of the non-ionic arsenite (As(III)) to negatively-charged arsenate (As(V)) is of crucial importance for the promising removal of arsenic. The chemical oxidants of ozone, chlorine, chlorine dioxide, and potassium permanganate may achieve this goal; however, their application in developing countries is sometimes restricted by the complicate operation and high cost. This review paper focuses on the heterogeneous oxidation of As(III) by solid oxidants such as manganese oxide, and the adsorption of As(V) accordingly. Manganese oxide may be prepared by both chemical and biological methods to achieve good oxidation performance towards As(III). Additionally, manganese oxide may be combined with other metal oxides, e.g., iron oxide, to improve the adsorption capability towards As(V). Furthermore, manganese oxide may be coated onto porous materials of metal organic frameworks to develop novel adsorbents for arsenic removal. To achieve the application in engineering works, the adsorbents granulation may be achieved by drying and calcination, agglomeration, and the active components may also be in situ coated onto the porous materials to maintain the oxidation and adsorption activities as much as possible. The novel adsorbents with heterogeneous oxidation and adsorption capability may be carefully designed for the removal of arsenic in household purifiers, community-level decentralized small systems, and the large-scale drinking water treatment plants (DWTPs). This review provides insight into the fundamental studies on novel adsorbents, the development of innovative technologies, and the demonstration engineering works involved in the heterogeneous oxidation and adsorption, and may be practically valuable for the arsenic pollution control globally. 相似文献
102.
利用超细γ-Al2O3/CuO催化剂催化降解染料废水的研究 总被引:9,自引:0,他引:9
采用超细γ-Al2O3为载体,担载CuO,制备去除难生化降解有机废水COD用的高效催化剂(γ-Al2O3/CuO),以水溶性偶氮染料活性艳红X-3B为处理对象,研究了操作参数对X-3B去除率的影响,以此形成有效的染料废水降解工艺,并用于指导实际废水的处理。利用制备的多相催化剂处理COD为5700mg/l、色度为3100位的实际染料废水,COD和色度去除率分别约为77%和99%。 相似文献
103.
采用零价铁(Fe~0)与过硫酸盐构建异相类芬顿体系,由Fe0腐蚀释放Fe~(2+)催化S_2 O_8~(2-)产生硫酸根自由基快速降解偶氮染料活性艳橙,考察了初始p H值、Fe~0投加量、过硫酸盐投加量和温度对降解过程的影响。结果表明,当活性艳橙初始浓度为100 mg/L、pH值为7、Fe~0投加量为0.5 g/L、过硫酸盐投加量为1 mmol/L和反应温度为30℃时,反应60 min后活性艳橙降解率达到92.6%。酸性条件和提高反应温度均有利反应的进行,而且活性艳橙的降解率在初始pH值为9时也高于90%。反应过程符合准一级动力学,表观反应速率常数k为0.0513 min~(-1)(30℃)。UV-Vis扫描显示,活性艳橙的发色基团在反应过程中被破坏。由Fe~0与S_2O_8~(2-)构成的异相Fenton体系可作为一种高效手段用于染料废水的处理。 相似文献
104.
In this paper, we present a simple theoretical extension from the Economic Geography literature to characterize the main features of pollution havens (lax environmental regulation, good market access to high-income countries and corruption opportunities). Using structural and reduced-form estimations, we find that pollution havens are not a “popular myth” for European firms, laxer environmental standards significantly explain the location choice of polluting affiliates. We analyze in depth the role of trade costs (using various bilateral and multilateral measures), a 1% increase in access to the European market from a pollution haven fosters relocation there by 0.1%. We also find that corruption lowers environmental standards, which strongly attract polluting firms: a 1% increase of corruption fuels relocation by 0.28%. We test the economic significance of these empirical findings via simulations. The protection of the European market (e.g., a carbon tax on imports) to stop relocations to pollution havens must be high (a decrease of the European market for Morocco and Tunisia equivalent to 13%) not to say prohibitive (31% for China). 相似文献
105.
《组织行为杂志》2017,38(7):950-976
The client relationships and tacit knowledge of professionals are professional service firms' (PSFs') major value creating resources producing challenges in generating post‐merger and acquisition value and risks of reducing the productivity or losing key professionals and their clients. The recent emergence of publicly owned PSFs and rapid growth through consolidating smaller privately owned firms potentially increases this risk by integrating small firms and their professionals into large public companies that may be governed very differently. This study explores post‐acquisition integration processes: professional behaviours and associated performance implications in two highly acquisitive publicly owned accounting companies. In one company, the integration process was rapid and heavily directed by senior management, while in the second company, integration was more gradual, initially undirected but then facilitated by senior management. The findings suggest that integration processes can impact the behaviour of professionals and acquiring firm performance. This research contributes to the understanding of post‐acquisition integration processes in PSFs and decision‐making and professional behaviour in recently emerged publicly owned PSFs. The study contributes to knowledge‐based theory by identifying factors that can affect the decision authority of executives and how organisational behaviour can constrain the implementation of executive integration decisions. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
106.
Lihui Gao Yijun Cao Lizhang Wang Shulei Li 《Frontiers of Environmental Science & Engineering》2022,16(6):77
107.
Use of catalytic wet air oxidation (CWAO) for pretreatment of high-salinity high-organic wastewater 下载免费PDF全文
Chenglin Sun Wenjing Sun Hongxia Lv Lei M Xiangdong Tan Chengyu Jin Huiling Wu Lili Chen Mengyang Liu Huangzhao Wei 《环境科学学报(英文版)》2022,34(10):105-114
Catalytic wet air oxidation (CWAO) coupled desalination technology provides a possibility for the effective and economic degradation of high salinity and high organic wastewater. Chloride widely occurs in natural and wastewaters, and its high content jeopardizes the efficacy of Advanced oxidation process (AOPs). Thus, a novel chlorine ion resistant catalyst B-site Ru doped LaFe1-xRuxO3-δ in CWAO treatment of chlorine ion wastewater was examined. Especially, LaFe0.85Ru0.15O3-δ was 45.5% better than that of the 6%RuO2@TiO2 (commercial carrier) on total organic carbon (TOC) removal. Also, doped catalysts LaFe1-xRuxO3-δ showed better activity than supported catalysts RuO2@LaFeO3 and RuO2@TiO2 with the same Ru content. Moreover, LaFe0.85Ru0.15O3-δ has novel chlorine ion resistance no matter the concentration of Cl− and no Ru dissolves after the reaction. X-ray diffraction (XRD) refinement, X-ray photoelectron spectroscopy (XPS), transmission electron microscope (TEM), and X-ray absorption fine structure (XAFS) measurements verified the structure of LaFe0.85Ru0.15O3-δ. Kinetic data and density functional theory (DFT) proved that Fe is the site of acetic acid oxidation and adsorption of chloride ions. The existence of Fe in LaFe0.85Ru0.15O3-δ could adsorb chlorine ion (catalytic activity inhibitor), which can protect the Ru site and other active oxygen species to exert catalytic activity. This work is essential for the development of chloride-resistant catalyst in CWAO. 相似文献