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141.
142.
重金属离子在腐植酸上吸附的研究 总被引:32,自引:0,他引:32
对4种代表性重金属离子在腐植酸上吸附、pH对竞争吸附的影响及其吸附机理进行了研究。结果表明,Cu2+、Pb2+、Zn2+的吸附等温线为F型,而Cd2+等温线为L型;2.5<pH<3.5时,竞争吸咐次序为Cu2+>Pb2+>Cd2+>Zn2+;pH>5.0时,Cd2+>Cu2+>Zn2+>Pb2+;Cu2+在腐植酸上的吸附主要是以与腐植酸形成配合物的方式相互结合。 相似文献
143.
The characterization of the Chlorella vulgaris solution was carried out using synchronous-scan spectroscopy. The range of concentration of algae and Fe(III) in aqueous solutions were 5 × 108–8 × 109 cells l−1 and 10–60 μM, respectively. Effective characterization method used was synchronous-scan fluorescence spectroscopy. The wavelength difference (Δλ) of 90 nm was maintained between excitation and emission wavelengths; 90 nm was found to be the best Δλ for effective characterization of Chlorella vulgaris solution with or without quencher species (e.g., Fe(III), humic acid (HA)) for the first time. The peak was observed at about EX 236.6 nm/EM 326.6 nm for synchronous-scan fluorescence spectra. The fluorescence quenching of algae in system of algae–Fe(III)–HA was studied using synchronous-scan spectroscopy for the first time. Fe(III) was clearly the effective quencher. The relationship between I0/I (quenching efficiency) and c (concentration of Fe(III) added) was a linear correlation for the algae solution with Fe(III). Also, Aldrich humic acid was found to be an effective quencher. pH effect on synchronous-scan fluorescence intensity of algal solution with Fe(III) and/or HA was evident. 相似文献
144.
Van Stempvoort DR Lesage S Novakowski KS Millar K Brown S Lawrence JR 《Journal of contaminant hydrology》2002,54(3-4):249-276
The enhanced solubility of petroleum-derived compounds in humic acid solutions is the basis for a new groundwater remediation technology. In this unique pilot-scale test, a stationary contaminant source consisting of diesel fuel was placed below the water table in a model sand aquifer (1.2 x 5.5 x 1.8-m deep) and flushed with water at a flow rate of 2 cm/h over 5 years. At 51 days, laboratory grade humic acid was added to the water and maintained at a level of approximately 0.8 g/l. The addition of humic acid had only a small impact on the aqueous transport of the BTEX components, which were rapidly dissolved from the diesel, but had a large effect on the flushing of PAHs, including methylated naphthalenes (MNs). Binding to aqueous humic acid enhanced the solubilization of MNs two- to tenfold. During aqueous transport, biodegradation of the BTEX and PAHs occurred, limiting the lateral and longitudinal extent of the diesel contaminant plume in the model aquifer. It appears that through enhanced solubilization, the overall biodegradation rate of the MNs was increased. As the various MNs were depleted from the diesel source, the MN plume shrank and then disappeared. 相似文献
145.
四氯化碳的生产与应用及其淘汰策略 总被引:2,自引:0,他引:2
四氯化碳是一种消耗臭氧层物质,其生产和消费都面临着严峻的淘汰形势。简要叙述了四氯化碳的生产技术,以四氯化碳为原料生产大宗化学品和精细化学品的转化技术,四氯化碳作为化工助剂在我国的应用情况以及相应的淘汰方法和技术进展。 相似文献
146.
The prothrombin time of the normal human pooled plasma was shortened by Aldrich humic acid well water humic substances and lignin at final concentrations ranging from 5 × 10–3 mg mL–1 to 5 × 10–2 mg mL–1, with a maxmum effect at 1 × 10–2 mg mL–1. At this concentration the shortening was 5.5 s, 4.4 s, and 3.5 s by Aldrich humic acid, well water humic substances and lignin respectively. However, monomeric components of humic acid such as syringic acid, protocatechuic acid, pyrogallol, vanillic acid, gallic acid, resorcinol, ferulic acid, catechol, caffeic acid and p-coumaric acid did not have such ability to shorten prothrombin time at the same final concentration ranges. Certain reducing agents such as t-butanol (2.5 × 10– –2.0 × 10–2 mg mL–1), glutathione (8.0 × 10–2–1 .0 mg mL–1), ascorbic acid (4.2 × 10–2–5.0 × 10–1 mg mL–1) and dithiothreitol (1.0 × 10–2–1.7 × 10–1mg mL–1) could prevent the shortening effects of humic substances or lignin on prothrombin time. These results suggested that humic substances and lignin with a polymerised structure had an ability to affect activities of some blood coagulating enzymes. 相似文献
147.
Elina?PortjanskajaEmail author Marina?Krichevskaya Sergei?Preis Juha?Kallas 《Environmental Chemistry Letters》2004,2(3):123-127
The photocatalytic oxidation of humic substances in aqueous solutions and natural waters with TiO2 attached to buoyant, hollow glass micro-spheres was studied. A maximum oxidation efficiency of 3.6 mg W–1 h–1 was achieved in neutral or alkaline media at a plane surface concentration of the catalyst attached to the micro-spheres of 25 g m–2. Proceeding by different mechanisms in acidic and alkaline media, the photocatalytic oxidation efficiency did not benefit from an excessive presence of hydroxyl radical promoters, hydrogen peroxide and alkali. 相似文献
148.
149.
腐殖酸对土壤挥发汞植物有效性的影响研究 总被引:4,自引:0,他引:4
土壤挥发汞对植物是非常有效的,并能通过食物链威胁人体健康,因此,本试验设计了“密闭箱的水培试验”定量研究了腐殖酸及其组份对土壤挥发汞生物活性的影响,结果发现:腐殖酸能有效地抑制土壤汞的挥发,降低植株对土壤挥发汞的吸收,其作用机理在于土壤挥发汞的形态转化,通过对转化条件的调节,可以达到控制土壤挥发汞向食物的链转移的目的。 相似文献
150.
Aijing Li Jian Hou Jianjie Fu Yinan Wang Yifei Hu Taifeng Zhuang Menglong Li Maoyong Song Guibin Jiang 《环境科学学报(英文版)》2023,35(2):11-18
Many per-and polyfluoralkyl substances(PFASs) may disrupt maternal thyroid hormone homeostasis in pregnancy. Concerns should be raised regarding the PFASs exposure in pregnant women because thyroid hormones are involved in the early development of the fetus. In this study, we measured the concentrations of 13 PFASs, including five novel shortchain PFASs, in serum from 123 pregnant women in Beijing, China. Linear regression models were used to investigate the association between thyroid-stimulati... 相似文献