响应面法优化仿酶Fe_3O_4/Fe~0非均相类Fenton降解P-NP

采用原位氧化沉淀法制备出仿酶Fe_3O_4/Fe~0,并采用扫描电子显微镜和X射线衍射对样品进行表征,结果表明,Fe_3O_4与Fe~0负载牢固且保持良好的晶型。采用响应面分析法对仿酶Fe_3O_4/Fe~0催化降解P-NP的工艺条件进行优化,方差分析得到二次模型显著,优化条件为:催化剂用量1.2 g/L,反应温度30℃,初始pH=2.9,初始H_2O_2浓度10 mmol/L,对硝基苯酚去除率的实际值与预测值几乎一致。     

建筑事故应激生理反应基础实验研究

拟通过事故应激和生理指标测量来定量评估建筑个体的应急素质。通过实验测量个体应激前后生理指标的变化情况,创新提出个体事故应激反应计算公式,定量计算出个体应激反应大小,并探讨其和性别及有无专业知识背景的关系。结果发现,所有4个生理指标实验后与前相比均发生非常显著的变化(P0.01),其中心率、收缩压、舒张压均升高,鼻尖皮温降低。男性的应激反应程度显著小于女性(P0.05),有安全专业知识背景的个体应激反应非常显著地小于没有安全专业知识背景的(P0.01)。研究结果还可以用来对个体的应激反应水平进行区间划分,以进行有针对性的培训和合理的岗位匹配。     

一株耐盐高效苯酚降解菌的筛选、鉴定、响应面法优化与降酚动力学研究

从海利(常德)有限公司污水处理池水样中分离得到1株耐盐高效苯酚降解菌,该菌可在盐度1%~8%、p H4.0~10.0、温度15~40℃条件下以苯酚为唯一碳源生长,命名为zht I.通过形态特征、生理生化反应、16S r DNA鉴定和BLAST序列比对构建系统发育树,确定菌株zht I为一株不动杆菌Acinetobacter guillouiae;利用Plackett-Burman实验确定葡萄糖浓度、苯酚浓度、p H值为影响菌株zht I降解苯酚的主要因素;采用中心组合实验设计,结合Box-Behnken实验设计及响应面法分析,确定菌株zht I在苯酚浓度801.6 mg·L~(-1)、葡萄糖浓度5.56%、p H值7.3、接种量6%、温度30℃、盐度3%条件下培养72 h,菌株zht I对苯酚的降解率达到93.23%.经降解动力学研究发现菌株zht I对苯酚的最大耐受浓度为1700 mg·L~(-1),菌株zht I降解苯酚的动力学模型符合典型的底物抑制模型,降酚动力学参数为:μmax=2.142 h~(-1),KS=126.952 mg·L~(-1),Ki=476.191 mg·L~(-1).     

Young drivers' responses to anti-speeding advertisements: Comparison of self-report and objective measures of persuasive processing and outcomes

Objective: Self-report measures are typically used to assess the effectiveness of road safety advertisements. However, psychophysiological measures of persuasive processing (i.e., skin conductance response [SCR]) and objective driving measures of persuasive outcomes (i.e., in-vehicle Global Positioning System [GPS] devices) may provide further insights into the effectiveness of these advertisements. This study aimed to explore the persuasive processing and outcomes of 2 anti-speeding advertisements by incorporating both self-report and objective measures of speeding behavior. In addition, this study aimed to compare the findings derived from these different measurement approaches.

Methods: Young drivers (N = 20, M age = 21.01 years) viewed either a positive or negative emotion–based anti-speeding television advertisement. While viewing the advertisement, SCR activity was measured to assess ad-evoked arousal responses. The RoadScout GPS device was then installed in participants' vehicles for 1 week to measure on-road speed-related driving behavior. Self-report measures assessed persuasive processing (emotional and arousal responses) and actual driving behavior.

Results: There was general correspondence between the self-report measures of arousal and the SCR and between the self-report measure of actual driving behavior and the objective driving data (as assessed via the GPS devices).

Conclusions: This study provides insights into how psychophysiological and GPS devices could be used as objective measures in conjunction with self-report measures to further understand the persuasive processes and outcomes of emotion-based anti-speeding advertisements.     

土体-结构界面接触对地下结构动力反应的影响

迄今为止,关于土体与结构交界面的接触效应对地下结构地震反应的影响尚未引起研究者们的重视,成果鲜有报道。本文基于接触面对法和非线性有限元波动分析方法,建立了考虑土体与结构界面接触效应的地下结构非线性地震反应分析模型和计算方法,并利用大型有限元软件ANSYS进行了求解。分析结果表明:土体与结构界面的接触效应对地下结构地震反应有明显影响,可能增大地下结构节点的峰值加速度、峰值位移和峰值应力反应;随着接触摩擦系数的增大,接触点的相对滑移逐渐减小,而接触应力的变化则无明显规律。     

Interactive Effects of Harvest and Deer Herbivory on the Population Dynamics of American Ginseng

Abstract:  Few demographic models for any species consider the role of multiple, interacting ecological threats. Many forest herbs are heavily browsed by white-tailed deer ( Odocoileus virginianus ) and a number of these are also harvested for the medicinal, floral, or horticultural trades. Previous studies of the viability of American ginseng ( Panax quinquefolius ) have separately examined the effects of harvesting and deer herbivory. We followed individually marked ginseng plants in 6 populations for 8 years and documented deer browse levels, conducted helicopter surveys to estimate the deer herd size, and documented 2 ginseng harvests. We used this long-term data set to develop a stochastic demographic model that quantified the separate and interactive role of these threats to ginseng viability. Although harvesting and deer herbivory negatively affected ginseng population growth, their effects were not additive. Deer herbivory negatively affected population growth in the absence but not in the presence of harvesting. Life table response experiments revealed that in the presence of harvesting, deer herbivory had some positive effects on vital rates because browsed plants were less apparent to harvesters. Ginseng populations that were harvested responsibly (i.e., planting seeds from harvested individuals) had higher growth rates than those that were harvested irresponsibly. We concluded that both deer populations and harvesting must be managed to ensure sustainable populations of American ginseng. Our findings underscore the importance of long-term monitoring to assess threats to viability and the need for a broad ecological understanding of the complexity of ecosystem management.     

An emergency response plan for cascading post-earthquake fires in fuel storage facilities

Natural disasters such as large earthquakes may rapidly result in cascading events such as post-earthquake fires (PEFs) to trigger. This is particularly the case in industrial facilities which is well known as natural-hazard triggered technological accidents (NaTechs). This study provides a response framework for NaTechs caused by earthquake in fuel storage facilities. To do this, seismic vulnerability of fuel storage tanks and possible damage fashions are studied. Considering fuel leakages can result in PEFs, possible scenarios are simulated numerically using Process Hazard Analysis Software Tool (PHAST). A case study including 20 fuel tanks adjacent one to another is investigated to simulate a domino effect when different arbitrary tanks start to ignite; hence, the worst case scenario can be determined. Based on the results of the case studied, inability to extinguish the possible PEFs over less than 9 min can lead to spreading them to the adjacent tanks. The results indicate that it takes about 40 min the adjacent tanks involve in the fires. Therefore, it is of paramount importance to provide an emergency response plan in advance to properly respond to the fires. The study here also highlights the role of preventive strategies in reducing the associated risks of PEFs in industrial facilities.     

高温碟型双金属片动作响应特性技术研究

高温碟形双金属片是火警温度继电器的核心元件，结构复杂，为了研究其受热动作响应特性，采用有限元分析方法，通过Solidworks结合ANSYS对双金属片进行热-结构耦合场分析，获得了碟形双金属片的受热动作响应特性，并且通过不断改变高温碟形双金属片的外形结构进行求解分析，根据分析结果总结高温碟形双金属片的结构与其受热动作响应特性之间的关系，为高温碟形双金属片的结构参数设计和数据调节提供理论依据。     

随机地震激励下相邻隔震结构被动控制研究

利用隔震结构和非隔震结构间的相互作用来减小地震作用下的结构响应,考虑地震激励的随机性,基于Clough-Penzien谱模型,推导了相邻结构随机响应的拓展状态方程,采用两种优化控制目标,分析得到了相邻隔震结构体系间连接控制装置的控制参数与结构随机响应的关系及其对控制效果的影响,并分别从地震响应时程和振动累计能量时程角度研究了相应地多自由度相邻隔震结构复合被动控制体系,在不同优化准则及不同控制方案下,结构体系的减震控制效果。研究结果表明,相邻隔震结构复合被动控制体系,可以获得较好的减震控制效果,阻尼系数在减震控制中起主要作用,但存在最优取值,并不是越大越好;采用以左、右子结构振动总能量最小为优化准则,在顶层+中间层安装控制装置的控制方案,可以有效地减小相邻结构的地震响应,得到的控制效果较好。     

基于AHP-模糊方法的某化工园区应急能力评估

化工园区应急能力评估是化工园区风险评估及应急管理的重要内容,化工园区建立应急能力评估体系一方面可以提高园区企业及管理部门的应急响应能力,另一方面可以增强政府各部门对事故的应急管理能力。在对某化工园区现场调研的基础上,结合国内外研究成果,确定了化工园区应急能力的多级指标,并运用AHP-模糊方法对该园区进行了应急能力评估。