5种不同晶型的纳米二氧化钛对金属铜生物积累的影响

纳米二氧化钛(nTiO_2)作为一种具有独特物理化学性质的纳米材料被广泛应用。然而,在生产、使用的过程中,nTiO_2会不可避免地进入于水环境中。重金属是水体中常见的污染物之一,nTiO_2进入水体后是否会与水体中的重金属发生相互作用,进而影响重金属的生物积累,目前相关报道还很少。本论文以大型溞为模式生物,考察了5种不同晶型nTiO_2对常见的重金属铜生物积累影响。结果表明,nTiO_2对Cu2+的吸附降低了试验液中Cu2+浓度。但5种不同晶型nTiO_2的吸附能力并不一样,其中锐钛矿晶型(A-S)的吸附能力最高,这可能是由于结构缺陷和表面羟基的存在,为Cu2+提供了更多的结合位点,从而提高了A-S的吸附能力。nTiO_2的存在降低了金属铜在大型溞体内的积累,这可能是由于nTiO_2对金属铜的吸附,降低了自由Cu2+的生物可利用性。由于nTiO_2样品之间比表面积的差异,不同晶型之间单位nTiO_2引起的铜积累有显著性差异性(P0.05),其中锐钛矿和金红石之比为4:1混合晶型(M1)最高,A-S最低。     

滏阳河河流水体中重金属污染特征及其对青海弧菌和斜生栅藻的毒性效应

为调查滏阳河水系的重金属污染状况,研究河流重金属污染对水生生物的毒性,根据河流结构、水文条件、排污口分布并考虑空间分布的均匀性,选取66个采样位点,采集河水及对应的表层沉积物样品,分析了样品中的重金属含量。用斜生栅藻和青海弧菌Q67作为模式生物,根据滏阳河水重金属污染较严重的邯郸近郊2号采样点采集水样的重金属含量配制系列重金属浓度的模拟河水进行重金属污染河水的生态毒性测试。结果表明,在全部66个采样点中,29个采样点河水重金属含量超过国家地表水III类水体重金属含量标准,主要污染元素是Hg、Pb、Cr、Zn。几乎所有采样点河水Mn和Fe含量都大大高于国家集中式生活饮用水地表水源地补充项目规定的标准限值。根据2号采样点河水样品中的重金属含量配成的模拟河水对青海弧菌Q67的EC₅₀值为6.65%,为毒性极强的污染物。模拟河水样品对斜生栅藻的抑制作用较小,在实验的最高浓度下(1000倍河水重金属含量)暴露4 d尚未引起半数藻细胞死亡。随河水重金属浓度上升,斜生栅藻超氧化物歧化酶(SOD)活性总体上呈现先升高后降低的趋势,丙二醛(MDA)含量变化则与此相反,反映河水重金属污染可引起藻细胞的氧化损伤。叶绿素a和b含量则随暴露浓度的提高逐渐降低。在重金属浓度达到2号采样点河水的10%时,斜生栅藻叶绿素a含量已有显著降低,MDA含量显著升高,海河流域重金属污染对生态系统的影响应予以重视。河水发光菌Q67的生长抑制率、斜生栅藻的叶绿素a和MDA含量可以作为评估河流重金属污染生态危害的指标。     

论环境资源的有偿使用

本文分析了环境资源的稀缺性及其具有的使用价值,指出只有在资源分配中引入市场的价值规律,才能公平地、有效地使用环境资源,避免掠夺性的占用。文章呼吁研究建立我国环境资源及排污许可证的交易市场。      

稳定塘的水力模型及其参数的确定

稳定塘的水力模型对于稳定塘的设计、运行和评价具有重要作用。该文在对稳定塘的各种水力模型分析的基础上,利用试验数据,对各种水力模型进行了识别与评价。结果表明:稳定塘的水力流态接近于完全混合态,基本上相当于2个或3个完全混合反应器的串联,无量纲扩散数d一般介于0．1～0．5之间。      

关于深化环保投资体制改革的若干思考

在分析现行环保投资体制改革进程的基础上,提出了深化我国环保投资体制改革的总体目标、基本内容及其外部条件。为了保证足够的环保投入,提高环保投资效益,当前,政府部门应抓住改革的有利时机,稳妥、适时和有重点地推进环保投资体制的深化改革。      

深圳城区噪声污染分析

通过对近年深圳市区域环境噪声及道路交通噪声的监测数据分析,发现深圳市交通声源是长期影响城市区域环境噪声的主要因素,其根源在于城市机动车辆增加迅速,路网过密,而配套设施跟不上,造成对城区域环境噪声污染相对集中,城区声环境日趋恶化。      

高地应力条件下Q系统在某勘探洞围岩分类中的应用

西南地区某水电站勘探洞高地应力是一个突出问题,高地应力洞段岩体属于坚硬岩或较坚硬岩,主要破坏方式是岩爆。高地应力区非岩爆岩体中未见结构性流变和软岩塑性流动等变形破坏现象,岩体质量较好。通过对岩体质量分类Q系统在该勘探洞高地应力洞段的应用,发现Q系统对于高地应力区非岩爆段岩体没有给出相应的SRF值;岩爆的发育条件是多方面的,但Q系统对岩爆的发育条件考虑较单一,所以它在高地应力区岩爆段的分类结果不能准确地体现出岩爆的等级和围岩类别。基于这2个问题,本文对Q系统做了相应的修改,以适应该勘探洞围岩分类,从修改后Q系统的分类结果看,效果良好。     

Standardizing the Methodology of Sperm Cell Test with Paracentrotus Lividus

The sperm cell toxicity test with Paracentrotus lividus is widely used in Italy to assess the quality of complex aqueous matrices, but at present there is a shortage of standardized methodologies for the bioassay performance. In this work several critical points were considered, in order to verify the reliability of this bioassay and to improve its standardization.In particular, we have studied the differences in EC50 values at different sperm: egg ratios and with different quantities of gametes; the influence of sperm and eggs on fertilization rate and the influence of different recipients materials (plastic or glass). At the same time, it was evaluated if the obtained EC50 values were in accordance with those reported in literature.Experiments performed yielded EC50 values for copper ranging from 16.54 μ g/l to 69.59 μ g/l, with a total mean value ± SD of 39.79 μ g/l ± 11.17. These data fit with those found in literature for other echinoid species. According to the same authors, poor fertilization was probably due to the effects on sperm and not on eggs, and moreover the linear regression analysis performed on each experiment suggested that the best amount of eggs to use in the test was 1000.Results from the comparison between the performance of the test in plastic or glass tubes showed an higher success in fertilization rate using borosilicate glass tubes.     

Equilibrium study and kinetics of Cu removal from water by zeolite prepared from oil shale ash

Engineered zeolite was produced from oil shale ash by reaction with sodium hydroxide in a closed vessel reactor. This adsorbent was used for removal of copper ions from aqueous solution. The maximum adsorption capacity was 504.6 mg Cu²⁺/g zeolite. Kinetic studies showed that the rate of adsorption of copper is increased with increasing the solution pH and temperature, quantity of the zeolite and agitation speed. The kinetic data were fitted to homogeneous micropore model and found that the mass transfer coefficient and diffusivity of the Cu²⁺ are directly affected by the kinetic parameters. The increase in solution concentration will decrease the mass transfer coefficient while diffusivity is increased.