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Matthaios P. Kavvalakis Manolis N. Tzatzarakis Eleftheria P. Theodoropoulou Emmanouil G. Barbounis Andreas K. Tsakalof Aristidis M. Tsatsakis 《Chemosphere》2013
Imidacloprid (IMI) is a relatively new neuro-active neonicotinoid insecticide and nowadays one of the largest selling insecticides worldwide. In the present study a LC–APCI–MS based method was developed and validated for the quantification of imidacloprid and its main metabolite 6-chloronicotinic acid (6-CINA) in urine and hair specimens. The method was tested in biomonitoring of intentionally exposed animals and subsequently applied for biomonitoring of Cretan urban and rural population. 相似文献
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Monitoring urban growth and detecting land-cover changes on the Istanbul metropolitan area 总被引:1,自引:0,他引:1
Istanbul is the most populated city of Turkey with a population of around 10.58 M (2000) living on around 5,750 km2. In 1980, the population was only 4.7 M and then it has been more than doubled in only two decades. The population has been
increasing as a result of mass immigration. An urbanization process continues and it causes serious increases in urban areas
while decreasing the amount of green areas. This rapid, uncontrolled, and illegal urbanization accompanied by insufficient
infrastructure has caused degradation of forest and barren lands in the metropolitan area, especially through the last two
decades. The watershed basins inside the metropolitan area and the transportation network have accelerated the land-cover
changes, which have negative impacts on water quality of the basins. Monitoring urban growth and land cover change will enable
better management of this complex urban area by the Greater Istanbul Metropolitan Municipality (GIMM). A temporal assessment
of land-cover changes of Istanbul has been documented in this study. The study mainly focuses on the acquisition and analysis
of Landsat TM and Landsat GeoCover LC satellite images reflecting the significant land-cover changes between the years of
1990 and 2005. Raster data were converted to vector data and used in Geographic Information Systems (GIS). A database was
created for Istanbul metropolitan area to plan, manage, and utilize statistical attribute data covering population, water,
forest, industry, and topographic position. Consequently an overlay analysis was carried out and land use/cover changes through
years have been detected for the case study area. The capability of Landsat images in determining the alterations in the macro
form of the city are also discussed. 相似文献
25.
The effect of hexadecyltrimethyleamine bromide (HDTMAB) on the removal of A lexandrium sp. LC3 under cupric glutamate stress was investigated. Toxic effect of cupric glutamate on A lexandrium sp. LC3 was significantly promoted in the presence of HDTMAB, especially at 3.0 cmc of HDTMAB. It was found that the sulfhydryl group content of the cell decreased, while the malonaldehyde content and membrane permeability increased when A lexandrium sp. LC3 was treated with HDTMAB and cupric glutamate complex, compared with cupric glutamate alone. The data suggest that HDTMAB might stimulate the damage of A lexandrium sp. LC3 by enhancing the membrane permeability. 相似文献
26.
海洋中的多环芳烃(PAHs)具有较强的生物毒性,且海洋动物早期发育阶段是对环境因素变化响应的最敏感阶段。为探究海洋多环芳烃类有机污染物对仿刺参(Apostichopus japonicus)早期发育阶段原肠胚的毒性影响,采用半静态毒性实验方法,分别考察了4种多环芳烃苯并[a]芘、3-甲基菲、惹烯及2-甲基蒽对仿刺参原肠胚的24、48、72、96 h急性毒性效应。结果表明,在10、50、100、200μg·L~(-1)暴露浓度下,随着暴露时间的延长和暴露浓度的升高,4种多环芳烃对仿刺参原肠胚产生不同程度的急性毒性效应,仿刺参原肠胚存活率与4种多环芳烃浓度之间分别存在显著的剂量-效应关系(P0.05)。苯并[a]芘对仿刺参原肠胚在24、48 h的半致死浓度(LC_(50))分别为294.4、225.64 mg·L~(-1),3-甲基菲在24、48、72、96 h的LC_(50)分别为404.5、300.7、81.4、17.6mg·L~(-1),惹烯在24、48、72 h的LC_(50)分别为243.1、230、186 mg·L~(-1),2-甲基蒽在24、48、72、96 h的LC_(50)分别244、231.6、152.6、142.9 mg·L~(-1)。4种多环芳烃的安全浓度(SC)分别为39.76、49.8、61.8、62.6μg·L~(-1),其毒性大小顺序为苯并[a]芘3-甲基菲惹烯2-甲基蒽。基于定量构效关系(QSAR)的研究结果可知多环芳烃化合物的毒性差异可能与分子结构等性质有关。该实验为深入研究多环芳烃对海洋环境的毒性效应提供了理论依据。 相似文献
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We investigate the stock market response to firm disclosure of positive environmental information and the link from that information to environmental outcomes. We classify environmental media releases by informational content and value relevance, and assess the abnormal stock returns of each type of event. While announcements of future environmental activities lead to the largest favorable stock market reactions, there is no guaranteed link from this type of information to environmental outcomes. Further analysis of the abnormal returns shows that the magnitude of the stock market reaction depends on firm financial characteristics across all event types rather than on firm environmental performance. Our results indicate that the ability for voluntary environmental information disclosure to induce environmental self-regulation is limited to the extent that firms are able to follow through with their announcements of planned environmental activities. 相似文献
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We analyze the effect of CEO education on environmental decision-making. Using a unique sample of Danish firms from 1996 to 2012, we find that CEO education significantly improves firms' energy efficiency. We seek to derive causality using health shocks: the hospitalization of highly educated CEOs induces a drop in energy efficiency, whereas the hospitalization of less educated CEOs does not have any significant effect. Exploring the mechanisms at play, we show that our results are largely driven by advanced education in business degrees. Moreover, we show that CEO education is associated with greater environmental awareness: highly educated CEOs exhibit greater concerns for climate change, as measured by a survey of social preferences, and drive more environmentally efficient cars. Taken together, our findings suggest that education shapes managerial styles giving rise to greater sustainability in corporate actions. 相似文献
29.
研究了二氯喹啉酸对湘云鲫的急性毒性和 (1/8~ 1/2 )LC50 浓度下对湘云鲫鳃、肝脏中Na K ATPase和Mg2 ATPase活性的影响。结果表明 :(1)在 2 3± 1℃条件下 ,二氯喹啉酸对湘云鲫的 2 4、4 8、72、96h的LC50 分别为 15 1.6 4、15 0 .92、14 9.6 0、14 9.14mg·L-1,是一种低毒性农药 ;(2 )鱼鳃和肝脏中Na K ATPase、Mg2 ATPase活性的抑制随浓度的增加而加强 ,表现出显著的浓度 -效应关系 ,是一种较好的生物指示剂。此外 ,还讨论了二氯喹啉酸抑制ATPase活性的机制 相似文献
30.
味精废水中重金属及金属污染对处理利用的影响 总被引:1,自引:0,他引:1
本文应用等离子光谱(ICP)测试三个厂家味精生产废水中21种金属元素的水平,其中金属元素的总水平分别达19192mg.l^-1,3190mg.l^-1和3161mg.l^-1,对照国内外有关的四项水质标准,三厂家味精生产废水中存在着Fe,Zn等多种重金属或其他金属元素严重超标现象,味精生产废水对青芋存在急性毒性,24,48,72和96h的半致死味精废水浓度LC50分别为6.9%,3.2%,2.5% 相似文献