Hierarchical Ag-SiO2@Fe3O4 magnetic composites for elemental mercury removal from non-ferrous metal smelting flue gas

Hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites were selected for elemental mercury(Hg~0) removal from non-ferrous metal smelting flue gas in this study. Results showed that the hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites had favorable Hg~0 removal ability at low temperature. Moreover, the adsorption capacity of hierarchical magnetic composite is much larger than that of pure Fe_3O_4 and SiO_2@Fe_3O_4. The Hg~0 removal efficiency reached the highest value as approximately 92% under the reaction temperature of 150°C, while the removal efficiency sharply reduced in the absence of O_2. The characterization results indicated that Ag nanoparticles grew on the surface of SiO_2@Fe_3O_4 support. The large surface area of SiO_2 supplied efficient reaction room for Hg and Ag atoms. Ag–Hg amalgam is generated on the surface of the composites. In addition, this magnetic material could be easily separated from fly ashes when adopted for treating real flue gas, and the spent materials could be regenerated using a simple thermal-desorption method.     

Dissolved organic matter removal using magnetic anion exchange resin treatment on biological effluent of textile dyeing wastewater

This study investigated the removal of dissolved organic matter（DOM） from real dyeing bio-treatment effluents（DBEs） with the use of a novel magnetic anion exchange resin（NDMP）.DOMs in two typical DBEs were fractionized using DAX-8/XAD-4 resin and ultrafiltration membranes. The hydrophilic fractions and the low molecular weight（MW）（〈3 kDa） DOM fractions constituted a major portion（〉50%） of DOMs for the two effluents. The hydrophilic and low MW fractions of both effluents were the greatest contributors of specific UV254absorbance（SUVA254）,and the SUVA254 of DOM fractions decreased with hydrophobicity and MW. Two DBEs exhibited acute and chronic biotoxicities. Both acute and chronic toxicities of DOM fractions increased linearly with the increase of SUVA254 value. Kinetics of dissolved organic carbon（DOC） removal via NDMP treatment was performed by comparing it with that of particle active carbon（PAC）. Results indicated that the removal of DOC from DBEs via NDMP was 60%,whereas DOC removals by PAC were lower than 15%. Acidic organics could be significantly removed with the use of NDMP. DOM with large MW in DBE could be removed significantly by using the same means. Removal efficiency of NDMP for DOM decreased with the decrease of MW. Compared with PAC,NDMP could significantly reduce the acute and chronic bio-toxicities of DBEs. NaCl/NaOH mixture regenerants,with selected concentrations of 10% NaCl（m/m）/1%NaOH（m/m）,could improve desorption efficiency.     

磁种和磁处理技术在废水处理中的应用

综述了微细粒磁性颗粒（磁种）在水中对许多污染物具有吸附和絮凝作用，用一些物理和化学方法可使其作用范围扩大。吸附剂与磁咱结合细菌吸附磁性离子等手段可实现加种，磁种作用与磁处理工艺相结合，扩大了磁场处理废水的范围，提高了废水处理的技术经济效益。     

A 2.5-D interpretation of the Basque country magnetic anomaly (northern Spain): geodynamical implications

The Basque country magnetic anomaly follows a NW-SE trend over the Basque country (northern Spain) with intensities up to 250 nT measured at 3000 m above sea level. The paired negative part of the anomaly is located to the north and presents intensities down to −60 nT. A model of the magnetic properties of the crust in the area, taking into account previous geological and geophysical data, indicates a wedge of material with a magnetic susceptibility of 0.07 SI emplaced along a NE-directed basal thrust. The anomalous wedge is composed of basic and/or ultrabasic Cretaceous intrusives and lower crustal rocks, and reaches a minimum depth which increases towards the northwest from 5–7 to 12 km. According to previous works, geological features of the rocks on top of the anomalous wedge indicate that during the Cretaceous this zone constituted a deep marine environment which underwent important crustal thinning related to rifting. The transition towards the southwest was to a normal continental platform. Alpine deformation gave rise to displacement on a basal thrust, which can be correlated with the lower contact of the magnetic wedge, and emplacement of this wedge towards the northeast. The southeastern termination of the anomaly can be related to the lateral termination of the basic rocks which constitute the anomalous wedge in a transform fault related to the rifting event.     

When does bearing magnets affect the size of deflection in clock-shifted homing pigeons?

Pigeons whose internal clock is shifted by 6 h show deflections from the direction of untreated controls, yet these deflections are often smaller than predicted. Magnets temporarily disabling the magnetic compass increased these the deflections significantly (R. Wiltschko and Wiltschko 2001), indicating a compromise between sun compass and magnetic compass. – Recently, Ioalé et al. (2006) claim that they could not replicate our findings. The reason lies in a difference in the behavior of the clock-shifted pigeons without magnets: in the study of Ioalè et al. (2006), their deflections was already almost as large as that of our pigeons carrying magnets. This difference is probably caused by the limited experience of the pigeons of Ioalè et al. (2006): Their birds, in contrast to ours, had not used their sun’ compass during extended homing flights at various times of the year and, not having been faced with the necessity to compensate the saisonal changes of the sun’s arc, gave the sun compass more weight than our birds did.A comment to the paper by Ioalè, Odetti and Gagliardo (2006) Behav Ecol Sociobiol 60: 516–521.     

Orientation behavior of homing pigeons at the Gernsheim anomaly

Pigeons were released at four release sites within the Gernsheim anomaly, a magnetic 'hill' with a peak 199 nT above the regional reference field and gentle 'slopes' to all sides, situated 44 km south of the Frankfurt loft. Local magnetic conditions at the sites differed in total intensity and in direction and steepness of the intensity gradient. At all sites, the pigeons were well oriented, showing counterclockwise deviations from the home directions that were most pronounced in the western part of the anomaly. There was no systematic difference in orientation behavior or homing performance between the sites within the anomaly and a control site outside. No effect of the local gradient direction was found, nor did the difference in intensity between home loft and the release site affect behavior. This argues against the use of magnetic navigational factors. However, pigeons released for the first time within the anomaly tended to have longer mean vectors with increasingly steeper gradients, which could mean that the birds might somehow have realized the anomalous nature of the local magnetic conditions and ignored them, relying on non-magnetic cues instead.Communicated by R. Gibson     

磁化除垢器在循环水系统的应用

介绍了利用磁化除垢、防垢法研制出的磁化除垢器的基本原理。此产品在工业、民用以及循环水，换热器、暖气、空调等系统上应用，取得了显著的效果。     

Modification of a magnetic carbon composite for ciprofloxacin adsorption

A magnetic carbon composite, Fe₃O₄/C composite, was fabricated by one-step hydrothermal synthesis, modified by heat treatment under an inert atmosphere (N₂), and then used as an adsorbent for ciprofloxacin (CIP) removal. Conditions for the modification were optimized according to the rate of CIP removal. The adsorbent was characterized by Fourier transform infrared spectroscopy, X-ray diffraction measurements, vibrating-sample magnetometry, scanning electron microscopy, transmission electron microscopy, and N₂ adsorption/desorption isotherm measurements. The results indicate that the modified adsorbent has substantial magnetism and has a large specific area, which favor CIP adsorption. The effects of solution pH, adsorbent dose, contact time, initial CIP concentration, ion strength, humic acid and solution temperature on CIP removal were also studied. Our results show that all of the above factors influence CIP removal. The Langmuir adsorption isotherm fits the adsorption process well, with the pseudo second-order model describing the adsorption kinetics accurately. The thermodynamic parameters indicate that adsorption is mainly physical adsorption. Recycling experiments revealed that the behavior of adsorbent is maintained after recycling for five times. Overall, the modified magnetic carbon composite is an efficient adsorbent for wastewater treatment.     

隔爆低频永磁同步电动机矢量控制方式研究

为了解决隔爆低频（TBD）型永磁同步电动机（PMSM）中如何利用精确的转子位置和速度信号去实现磁场定向的问题,分析了永磁同步电动机的矢量控制理论,讨论了无传感器矢量控制方案,提出了基于空间电压矢量脉宽调制（SVPWM）技术的矢量控制方案,采用TMS320LF2812为核心处理器进行矢量控制系统的硬件设计,采用DSP编程实现该系统的软件设计,进行了基于无传感器矢量控制系统的仿真研究及实验波形分析。结果表明：无传感器矢量控制方案具有很好的动态特性,能够稳定运行,满足驱动系统的要求。