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51.
Khoirakpam Kesho Singh Kula Kamal Senapati Chandan Borgohain Kanak Chandra Sarma 《环境科学学报(英文版)》2017,29(2):333-340
Chlorophenols, typically 4-chlorophenols are highly toxic and non-biodegradable organic contaminants which pose serious threat to the environment, particularly when released into aqueous medium. The removal of these pollutants by efficient method has received worldwide concern in recent past. A new Fe_3O_4–Cr_2O_3 magnetic nanocomposite was synthesized by wet chemical method under ultrasonic irradiation. Microstructure and morphology of the nanocomposite were characterized by powder X-ray diffraction(XRD),Fourier transform infrared(FT-IR), and a transmission electron microscope(TEM). Magnetic and optical properties were studied by a vibrating sample magnetometer(VSM) and an ultraviolet–visible(UV–Vis) spectrophotometer respectively. The magnetic nanocomposite(MNC) was used as photocatalyst for effective decomposition of 4-chlorophenol in water under ultraviolet(UV) irradiation. 相似文献
52.
铁磁形状记忆合金研究进展与展望(Ⅲ):应用研究 总被引:1,自引:0,他引:1
阐述了铁磁形状记忆合金(Ferromagnetic Shape Memory Alloy,简写为FSMA)在智能材料及其应用领域的优越性.重点介绍了FSMA装置研发和基于FSMA装置的体系分析理论的发展历程和研究现状.仔细分析了各种FSMA装置频率、输出力和最大位移等关键技术指标,讨论了基于电磁学、热力学和力学原理的包... 相似文献
53.
Esquivel DM Wajnberg E do Nascimento FS Pinho MB Lins de Barros HG Eizemberg R 《Die Naturwissenschaften》2007,94(2):139-142
Six behavioural experiments were carried out to investigate the magnetic field effects on the nest-exiting flight directions
of the honeybee Schwarziana quadripunctata (Meliponini). No significant differences resulted during six experiment days under varying geomagnetic field and the applied static inhomogeneous
field (about ten times the geomagnetic field) conditions. A surprising statistically significant response was obtained on
a unique magnetic storm day. The magnetic nanoparticles in these bees, revealed by ferromagnetic resonance, could be involved
in the observed effect of the geomagnetic storm. 相似文献
54.
LI Yu-jiang YANG Min ZHANG Xiao-jin WU Tao CAO Nan WEI N BI Yan-jun WANG Jing 《环境科学学报(英文版)》2006,18(1):23-28
A hydrotalcite with Mg/AI molar ratio 2 was prepared by co-precipitation method and was characterized by XRD, TG/DTA, Zeta potential and BET surface area. The hydrotalcite was calcined at 500℃, with the dehydration from interlayer, the dehydroxilation from the brucite-like layer and the decomposition of carbonate successively, transformed into the mixed oxide type. The removal of thiocyanate from aqueous solution by using the original hydrotalcite and calcined hydrotalcite (HTC-500) was investigated. The results showed that the thiocyanate adsorption capacity of calcined hydrotalcite was much higher than that of the original form. Calcined hydrotalcite was particularly effective at removing thiocyanate, and that the effective range of pH for the thiocyanate removal are between 5.5-10.0. The experimental data of thiocyanate removal fit nicely with Langmuir isotherm, and the saturated adsorption uptake was 96.2 mg SCN-/g HTC-500. The adsorption of thiocyanate by calcined hydrotalcite follows first-order kinetics. And the intercalation to the structure recovery for calcined hydrotalcite. But the presence of additional anions could affect the adsorption behavior of thiocyanate. 相似文献
55.
Moti L. Rijal Erwin Appel Ulrich Blaha 《Environmental pollution (Barking, Essex : 1987)》2010,158(5):1756-1762
Sediments affected by fluctuations of hydrocarbon contaminated groundwater were studied at a former military site. Due to remediation, groundwater table fluctuation (GWTF) extends over approximately one meter. Three cores were collected, penetrating through the GWTF zone. Magnetic parameters, sediment properties and hydrocarbon content were measured. We discovered that magnetic concentration parameters increased towards the top of the GWTF zone. Magnetite is responsible for this enhancement; rock magnetic parameters indicate that the newly formed magnetite is in a single domain rather than a superparamagnetic state. The presence of hydrocarbons is apparently essential for magnetite to form, as there is clearly less magnetic enhancement in the core, which is outside of the strongly contaminated area. From our results we conclude that the top of the fluctuation zone has the most intensive geomicrobiological activity probably responsible for magnetite formation. This finding could be relevant for developing methods for simply and quickly detecting oil spills. 相似文献
56.
5种吸附剂对水中离子液体的吸附性能 总被引:1,自引:0,他引:1
实验研究了蒙脱土、活性白土、人造沸石、活性炭和水滑石5种吸附材料在25℃和50℃下对[Bmim]Cl的吸附过程,结果表明,蒙脱土对离子液体的去除效果最好,温度对活性炭的吸附有一定的影响,而对其他吸附剂的影响不大,说明这些无机矿物发生了离子交换型吸附过程。实验进一步研究了蒙脱土在25℃下对[Bmim]Cl、[Bmim]BF4、[Bmim]PF6、[Bmim]DBP、[Hmim]Cl和[Omim]Cl 6种离子液体的吸附行为,结果表明,对于阳离子相同的离子液体,阴离子对吸附影响不大;对于阴离子相同的离子液体,其饱和吸附量随着阳离子链长的增加而减小。 相似文献
57.
58.
Biomagnetic monitoring of industry-derived particulate pollution 总被引:2,自引:0,他引:2
Hansard R Maher BA Kinnersley R 《Environmental pollution (Barking, Essex : 1987)》2011,159(6):1673-1681
Clear association exists between ambient PM10 concentrations and adverse health outcomes. However, determination of the strength of associations between exposure and illness is limited by low spatial-resolution of particulate concentration measurements. Conventional fixed monitoring stations provide high temporal-resolution data, but cannot capture fine-scale spatial variations. Here we examine the utility of biomagnetic monitoring for spatial mapping of PM10 concentrations around a major industrial site. We combine leaf magnetic measurements with co-located PM10 measurements to achieve inter-calibration. Comparison of the leaf-calculated and measured PM10 concentrations with PM10 predictions from a widely-used atmospheric dispersion model indicates that modelling of stack emissions alone substantially under-predicts ambient PM10 concentrations in parts of the study area. Some of this discrepancy might be attributable to fugitive emissions from the industrial site. The composition of the magnetic particulates from vehicle and industry-derived sources differ, indicating the potential of magnetic techniques for source attribution. 相似文献
59.
Yongpeng M Bailong Mu Xiaojing Zhang Hongzhong Zhang Haomiao Xu Zan Qu Li Gao 《环境科学学报(英文版)》2019,31(5):111-120
Hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites were selected for elemental mercury(Hg~0) removal from non-ferrous metal smelting flue gas in this study. Results showed that the hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites had favorable Hg~0 removal ability at low temperature. Moreover, the adsorption capacity of hierarchical magnetic composite is much larger than that of pure Fe_3O_4 and SiO_2@Fe_3O_4. The Hg~0 removal efficiency reached the highest value as approximately 92% under the reaction temperature of 150°C, while the removal efficiency sharply reduced in the absence of O_2. The characterization results indicated that Ag nanoparticles grew on the surface of SiO_2@Fe_3O_4 support. The large surface area of SiO_2 supplied efficient reaction room for Hg and Ag atoms. Ag–Hg amalgam is generated on the surface of the composites. In addition, this magnetic material could be easily separated from fly ashes when adopted for treating real flue gas, and the spent materials could be regenerated using a simple thermal-desorption method. 相似文献
60.
Dissolved organic matter removal using magnetic anion exchange resin treatment on biological effluent of textile dyeing wastewater 总被引:3,自引:0,他引:3
This study investigated the removal of dissolved organic matter(DOM) from real dyeing bio-treatment effluents(DBEs) with the use of a novel magnetic anion exchange resin(NDMP).DOMs in two typical DBEs were fractionized using DAX-8/XAD-4 resin and ultrafiltration membranes. The hydrophilic fractions and the low molecular weight(MW)(〈3 kDa) DOM fractions constituted a major portion(〉50%) of DOMs for the two effluents. The hydrophilic and low MW fractions of both effluents were the greatest contributors of specific UV254absorbance(SUVA254),and the SUVA254 of DOM fractions decreased with hydrophobicity and MW. Two DBEs exhibited acute and chronic biotoxicities. Both acute and chronic toxicities of DOM fractions increased linearly with the increase of SUVA254 value. Kinetics of dissolved organic carbon(DOC) removal via NDMP treatment was performed by comparing it with that of particle active carbon(PAC). Results indicated that the removal of DOC from DBEs via NDMP was 60%,whereas DOC removals by PAC were lower than 15%. Acidic organics could be significantly removed with the use of NDMP. DOM with large MW in DBE could be removed significantly by using the same means. Removal efficiency of NDMP for DOM decreased with the decrease of MW. Compared with PAC,NDMP could significantly reduce the acute and chronic bio-toxicities of DBEs. NaCl/NaOH mixture regenerants,with selected concentrations of 10% NaCl(m/m)/1%NaOH(m/m),could improve desorption efficiency. 相似文献