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41.
Chromium compounds have received considerable attention because these are used extensively in such industrial applications as electroplating, steelmaking, tanning of leather goods, and corrosion inhibition. The use of supported liquid membranes (SLMs) to remove metals from wastewaters has actively been pursued by the scientific and industrial community. In the present work, the selective separation and preconcentration of Cr(VI) ions has been studied by using a commercial amine as the membrane liquid on the porous polypropylene support. Permeation experiments were conducted on a laboratory scale batch reactor made up of perspex, with a memberane fixed amid the two chambers. The flux of Cr(VI) ions was found to be maximum (3.15?×?10?5?mol?cm?2?s?1) around pH 1. Above and below this pH the flux decreases. Distribution studies show that an increase in the amine concentration leads to higher distribution coefficients at fixed pH values. At pH around unity, the distribution of Cr(VI) ions into the organic phase was found to be maximum, of the order of 56.3. The Cr(VI) transport through the membrane increases with rise in temperature. In order to check the long-term efficiency of the flat sheet SLM, an experiment was conducted with higher Cr(VI) concentration (5000?ppm) for 24?h, at optimised parameters. It was observed that in 24?h, about 1/5th of the feed Cr(VI) is left over while the rest is transported. However, minute organic droplets were also seen in the feed and strip compartments, after 1 day. This observation suggested the loss of membrane liquid. The feasibility of preconcentration of Cr(VI) by using the proposed SLM parameters, was also studied by using the hollow fibre (HF) system. Highest enrichment factor (E.F) value was obtained for 50?mg?L?1 whereby all of the metal was transported to the stripping phase and the resulting Cr concentration was 688?mg?L?1 (E.F?=?13.8). It was observed that while treating more diluted solutions, the enrichment factor decreases. The values of E.F equal to 8.9 and 11.3 were found for initial Cr concentration of 10 and 30?mg?L?1. 相似文献
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研究了聚酯化纤废水中有机污染物乙醛、乙酸、乙二醇含量与COD之间的相关性,确定了COD与上述特征污染物含量的比值,并测定了它们的氧化率,为企业的生产工艺管理和 保管理提供了基础数据。 相似文献
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根据全反射原理.菲涅尔公式及朗伯-比尔定律,证明了低浓度溶液与折射率和吸光度之间的线性关系,得到了光纤出射光强随液体包层浓度成负指数关系。根据上述结果,利用光的强度调制进行溶液浓度检测,即通过测量光强的变化,检测出待测溶液浓度。实验表明,强度调制光纤传感器可以实现溶液浓度检测。 相似文献
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介绍我国粘胶纤维生产废气治理研究的发展情况,说明普通活性炭不适合作为粘胶纤维生产废气的吸附剂、建议采用密封窗封闭操作、用TF法脱除H2S,再用改性活性炭脱除CS2,同时应重视研究开发新型溶剂代替CS2进行无害化清洁生产.关键词:粘胶纤维废气治理硫化氢二硫化炭 相似文献
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活性炭纤维对气体中醋酸丁酯吸附性能的研究 总被引:9,自引:0,他引:9
通过试验选择活性炭纤维作为吸附剂,吸气气体中醋酸丁酯。对影响其吸附性能的主要因素进行了研究。 相似文献
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1,1,1-三氯乙烷回收装置 总被引:3,自引:0,他引:3
介绍了已在彩色显像管生产线上配套应用的三氯乙烷回收装置的工艺流程、操作控制系统和应用效果。 相似文献