Aerobic N2O emission for activated sludge acclimated under different aeration rates in the multiple anoxic and aerobic process

Nitrous oxide (N₂O) is a potent greenhouse gas that can be emitted during biological nitrogen removal. N₂O emission was examined in a multiple anoxic and aerobic process at the aeration rates of 600 mL/min sequencing batch reactor (SBR_L) and 1200 mL/min (SBR_H). The nitrogen removal percentage was 89% in SBR_L and 71% in SBR_H, respectively. N₂O emission mainly occurred during the aerobic phase, and the N₂O emission factor was 10.1% in SBR_L and 2.3% in SBR_H, respectively. In all batch experiments, the N₂O emission potential was high in SBR_L compared with SBR_H. In SBR_L, with increasing aeration rates, the N₂O emission factor decreased during nitrification, while it increased during denitrification and simultaneous nitrification and denitrification (SND). By contrast, in SBR_H the N₂O emission factor during nitrification, denitrification and SND was relatively low and changed little with increasing aeration rates. The microbial competition affected the N₂O emission during biological nitrogen removal.     

Predictors of specialist avifaunal decline in coastal marshes

Coastal marshes are one of the world's most productive ecosystems. Consequently, they have been heavily used by humans for centuries, resulting in ecosystem loss. Direct human modifications such as road crossings and ditches and climatic stressors such as sea‐level rise and extreme storm events have the potential to further degrade the quantity and quality of marsh along coastlines. We used an 18‐year marsh‐bird database to generate population trends for 5 avian species (Rallus crepitans, Tringa semipalmata semipalmata, Ammodramus nelsonii subvirgatus, Ammodramus caudacutus, and Ammodramus maritimus) that breed almost exclusively in tidal marshes, and are potentially vulnerable to marsh degradation and loss as a result of anthropogenic change. We generated community and species trends across 3 spatial scales and explored possible drivers of the changes we observed, including marsh ditching, tidal restriction through road crossings, local rates of sea‐level rise, and potential for extreme flooding events. The specialist community showed negative trends in tidally restricted marshes (?2.4% annually from 1998 to 2012) but was stable in unrestricted marshes across the same period. At the species level, we found negative population trends in 3 of the 5 specialist species, ranging from ?4.2% to 9.0% annually. We suggest that tidal restriction may accelerate degradation of tidal marsh resilience to sea‐level rise by limiting sediment supply necessary for marsh accretion, resulting in specialist habitat loss in tidally restricted marshes. Based on our findings, we predict a collapse of the global population of Saltmarsh Sparrows (A. caudacutus) within the next 50 years and suggest that immediate conservation action is needed to prevent extinction of this species. We also suggest mitigation actions to restore sediment supply to coastal marshes to help sustain this ecosystem into the future.     

A double‐edged sword: The moderating role of conscientiousness in the relationships between work stressors,psychological strain,and job performance

Although conscientiousness was commonly viewed as a type of personal resource to help individuals reduce strain or mitigate the impacts of stressors, empirical research demonstrated mixed results. Based on the personal resource allocation perspective, we posited that rather than functioning as personal resource per se, conscientiousness may act as a key factor influencing how individuals allocate their personal resources. The current study examined the moderating roles of conscientiousness in the relationships that work stressors (i.e., challenge stressors and hindrance stressors) have with employee psychological strain and job performance by using multi‐source, time‐lagged data collected from 250 employees working at two companies. The results showed that both challenge stressors and hindrance stressors were positively related to psychological strain. Conscientiousness moderated the relationships between both stressors and psychological strain, such that the positive relationships were stronger for individuals with high conscientiousness. Conscientiousness also moderated the relationship between challenge stressors and performance, such that the relationship was positive for individuals with high conscientiousness but negative for those with low conscientiousness. Altogether, the findings suggest that conscientiousness acts as a double‐edged sword that both promotes performance and exacerbates the stress reaction of employees when they are confronted with stressful situations. Copyright © 2014 John Wiley & Sons, Ltd.     

Characterization and prediction of highway runoff constituent event mean concentration

Highway stormwater runoff quality data were collected from throughout California during 2000-2003. Samples were analyzed for conventional pollutants (pH, conductivity, hardness, and temperature); aggregates (TSS, TDS, TOC, DOC); total and dissolved metals (As, Cd, Cr, Cu, Ni, Pb, and Zn); and nutrients (NO(3)-N, TKN, total P, and ortho-P). Storm event and site characteristics for each sampling site were recorded. A statistical summary for chemical characteristics of highway runoff is provided based on statewide urban and non-urban highways. Constituent event mean concentrations (EMCs) were generally higher in urban highways than in non-urban highways. The chemical characteristics of highway runoff in California were compared with national highway runoff chemical characterization data. The results obtained in California were generally similar to those found in other states. The median EMC for Pb measured in studies conducted in previous decades was much higher than the current median Pb EMC in California. The lower Pb EMC in California compared to previous highway runoff monitoring is believed to be due to the elimination of leaded gasoline. An attempt was also made to identify surrogate constituents within a general family of water quality categories using Spearman correlations and selected pairs with Spearman coefficients greater than 0.8. The strongest correlations were observed among parameters associated with dissolved minerals (EC, TDS, and chloride); organic carbon (TOC and DOC); petroleum hydrocarbons (TPH and O & G); and particulate matter (TSS and turbidity). Within the metals category, total iron concentration was highly correlated with most total metal concentrations. The correlations between total and dissolved concentrations were all less than 0.8, even between total and dissolved concentrations of the same metals. Multiple linear regression (MLR) analyses were performed to evaluate the impact of various site and storm event variables on highway runoff constituent EMCs. Parameters found to have significant impacts on highway runoff constituent EMCs include: total event rainfall (TER); cumulative seasonal rainfall (CSR); antecedent dry period (ADP); contributing drainage area (DA); and annual average daily traffic (AADT). Surrounding land use and geographic regions were also determined to have a significant impact on runoff quality. The MLR model was also used to predict constituent EMCs. Model performance determined by comparing predicted and measured values showed good agreement for most constituents.     

Multiple regression models for the lower heating value of municipal solid waste in Taiwan

A multiple regression analysis was used to develop two predictive models of lower heating value (LHV) for municipal solid waste (MSW), using 180 samples gathered from cities and counties in Taiwan during 2001-2002. These models are referred to as the original proposed model (OPM) and the simplified model (SM). The coefficients of multiple determinations for the OPM and SM were 0.983 and 0.975, respectively. To verify the feasibility of the models, a demonstration program based on sampling of MSW in Kaohsiung City was conducted. As a result, the OPM showed superior precision in terms of relative percentage deviation (RPD) and mean absolute percentage error (MAPE), when compared to the conventional models based on the proximate analysis, physical composition and ultimate analysis. The SM was derived by neglecting the three minor physical components used in the OPM. The resulting SM was less precise when compared to the OPM, but it was still acceptable, with a precision level better than the conventional models. It was concluded that the predictability of empirical models could be improved significantly through selection of the appropriate physical components and multiple regression analysis.     

Relations between Conspecific Density and Effects of Ultraviolet‐B Radiation on Tadpole Size in the Striped Marsh Frog

Global increases in ultraviolet‐B radiation (UVBR) associated with stratospheric ozone depletion are potentially contributing to the decline of numerous amphibian species around the world. Exposure to UVBR alone reduces survival and induces a range of sublethal effects in embryonic and larval amphibians. When additional environmental stressors are present, UVBR can have compounding negative effects. Thus, examination of the effects of UVBR in the absence of other stressors may substantially underestimate its potential to affect amphibians in natural habitats. We examined the independent and interactive effects of increased UVBR and high conspecific density would have embryonic and larval striped marsh frogs (Limnodynastes peronii). We exposed individuals to a factorial combination of low and high UVBR levels and low, medium, and high densities of striped marsh frog tadpoles. The response variables were time to hatching, hatching success, posthatch survival, burst‐swimming performance of tadpoles (maximum instantaneous swim speed following an escape response), and size and morphology of tadpoles. Consistent with results of previous studies, we found that exposure to UVBR alone increased the time to hatching of embryos and reduced the burst‐swimming performance and size of tadpoles. Similarly, increasing conspecific density increased the time to hatching of embryos and reduced the size of tadpoles, but had no effect on burst‐swimming performance. The negative effect of UVBR on tadpole size was not apparent at high densities of tadpoles. This result suggests that tadpoles living at higher densities may invest relatively less energy in growth and thus have more energy to repair UVBR‐induced damage. Lower densities of conspecifics increased the negative effects of UVBR on developing amphibians. Thus, low‐density populations, which may include declining populations, may be particularly susceptible to the detrimental effects of increased UVBR and thus may be driven toward extinction faster than might be expected on the basis of results from single‐factor studies. Relaciones entre la Densidad Conespecífica y los Efectos de la Radiación Ultravioleta‐B sobre el Tamaño de Renacuajos de Limnodynastes peronei     

Use of bifurcation analysis for identification of a safe CSTR operability

Exothermic reactions are the most interesting systems for safety analysis because of their potential safety problems and the possibility of exotic behavior like multiple steady states. An operability and safety analysis of an exothermic reaction (hydrolysis of propylene oxide to tri-propylene glycol with consecutive reactions in a CSTR) with cooling is reported in this work. The information obtained from the bifurcation diagram is used to identify a set of unsafe operation points, which have been chosen on the base of requirement of maximal production of the process. An important information of safe reactor operation is the time in which the operator must handle a critical situation. For this reason, dynamics simulation of a failure in the cooling medium flow rate has been done and discussed for each of the selected operation points.     

机车司机行车安全监控系统应用研究

分析铁路行车安全监控系统的复杂性和现状;设计分局机车司机行车安全监控系统和数据流向;研制车载的机车司机工作状态实时监督系统;采用视频监控、图像处理技术以及人脸识别技术对机车司机工作状态进行识别并实时报警。经过实验证明:对司机长时间离开座位、睡眠和呆木状态有较高的识别率;同时对司机工作状态的图像信号进行压缩储存;管理人员可以回放检查。采用CDMA技术设计了地面对机车司机工作状态的视频监控子系统,可以把司机的工作状态图像及时传送到车站或调度中心。实际线路实验表明,该系统可以大大提高司机工作的安全性。     

Is love of nature in the US becoming love of electronic media? 16-year downtrend in national park visits explained by watching movies,playing video games,internet use,and oil prices

After 50 years of steady increase, per capita visits to US national parks have declined since 1988. This decline, coincident with the rise in electronic entertainment media, may represent a shift in recreation choices with broader implications for the value placed on biodiversity conservation and environmentally responsible behavior. We compared the decline in per capita visits with a set of indicators representing alternate recreation choices and constraints. The Spearman correlation analyses found this decline in NPV to be significantly negatively correlated with several electronic entertainment indicators: hours of television, (rs=-0.743, P<0.001), video games (rs=-0.773, P<0.001), home movies (rs=-0.788, P<0.001), theatre attendance (rs=-0.587, P<0.025) and internet use (rs=-0.783, P<0.001). There were also significant negative correlations with oil prices (rs=-0.547, P<0.025), foreign travel (rs=-0.452, P<0.05), and Appalachian Trail hikers (rs=-0.785, P<0.001). Income was significantly positively correlated with foreign travel (rs=0.621, P<0.005) but negatively correlated with national park visits (rs=-0.697, P<0.005). There was no significant correlation of mean number of vacation days, indicating available vacation time is probably not a factor. Federal funding actually increased during this period, and so was rejected as a probable factor. Park capacity was rejected as limiting since both total overnight stays and visits at the seven most popular parks rose well into the mid-1990s. Aging of baby boomers was also rejected as they are only now reaching retirement age, and thus during the period of visitation decline were still of prime family vacation age. Multiple linear regression of four of the entertainment media variables as well as oil prices explains 97.5% of this recent decline (r=0.975, multiple r2=0.950, adjusted multiple r2=0.925, SE=0.015, F=37.800, P<0.0001). We may be seeing evidence of a fundamental shift away from people's appreciation of nature (biophilia, Wilson 1984) to 'videophilia,' which we here define as "the new human tendency to focus on sedentary activities involving electronic media." Such a shift would not bode well for the future of biodiversity conservation.     

Implications of Atmospheric Change for Biodiversity of Aquatic Ecosystems in Canada

Overall, the greatest threats to Canadian and global biodiversity are associated with conversions of natural ecosystems to anthropogenic ones, and over-exploitation of biological resources. This circumstance does not, however, trivialize the importance of atmospheric influences. Although scientific understanding of the risks is incomplete, it is nevertheless clear that anthropogenic changes in atmospheric stressors are potentially damaging to biodiversity and other ecological values over medium- and longer-term scales. It is important that greater investments be made in support of longer-term monitoring and research designed to understand the effects of atmospheric and other environmental stressors on the biodiversity and structure and function of Canadian ecosystems.