全文获取类型
收费全文 | 790篇 |
免费 | 15篇 |
国内免费 | 91篇 |
专业分类
安全科学 | 36篇 |
废物处理 | 30篇 |
环保管理 | 76篇 |
综合类 | 351篇 |
基础理论 | 80篇 |
污染及防治 | 224篇 |
评价与监测 | 83篇 |
社会与环境 | 14篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 10篇 |
2022年 | 11篇 |
2021年 | 29篇 |
2020年 | 22篇 |
2019年 | 15篇 |
2018年 | 13篇 |
2017年 | 16篇 |
2016年 | 20篇 |
2015年 | 25篇 |
2014年 | 32篇 |
2013年 | 43篇 |
2012年 | 43篇 |
2011年 | 74篇 |
2010年 | 37篇 |
2009年 | 53篇 |
2008年 | 51篇 |
2007年 | 45篇 |
2006年 | 44篇 |
2005年 | 34篇 |
2004年 | 27篇 |
2003年 | 38篇 |
2002年 | 26篇 |
2001年 | 24篇 |
2000年 | 31篇 |
1999年 | 20篇 |
1998年 | 21篇 |
1997年 | 21篇 |
1996年 | 12篇 |
1995年 | 7篇 |
1994年 | 17篇 |
1993年 | 18篇 |
1992年 | 12篇 |
1991年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有896条查询结果,搜索用时 31 毫秒
141.
有机化合物的生物降解性能和生物毒性 总被引:6,自引:0,他引:6
有机化合物在环境中的出现是当今世界的重大挑战之一,80年代以来,对于有机化合物在生化处理系统中的归宿和对生物的影响已引起普遍的关注。迄今为止,有关这个课题的研究和资料仍然很少。文章对有机化合物的生物降解性能和生物毒性作一综述,以供同行参考。 相似文献
142.
化学修饰电极在环境微量及痕量有机物分析中的应用 总被引:1,自引:0,他引:1
根据实验研究及国内外文献,从伏安及电位溶出分析,流动注射/液相色谱电化学检测,化学修饰电极生物传感器及化学修饰电极预富集—石墨炉原子吸收法联用等方面,重点综述了化学修饰电极在环境微量及痕量有机物分析中的应用。 相似文献
143.
Edward Heyse Dongping Dai P. Suresh C. Rao Joseph J. Delfino 《Journal of contaminant hydrology》1997,25(3-4)
This paper introduces a new reversible-flow design for a continuously stirred reactor used to study sorption mass transfer in soil and solvent systems. The stirred reactor has potential advantages over conventional packed column or batch reactors because it isolates intraparticle sorption rate limitations from advective-dispersive transport, yet allows changes to flux through the reactor for analysis of sorption kinetics under dynamic conditions. Previously, stirred reactors have often failed due to clogging of sediment on the effluent frit. The reverse-flow backwashing design allows longer life and higher confidence in maintaining mixed conditions than previous designs. Mass transfer 'rate coefficients estimated from stirred and column experiments are compared; both techniques produced results consistent with a published correlation. The data also show that fitted sorption mass transfer coefficients can be strongly dependent on the choice of equilibrium partition coefficient (i.e. batch or first-moment derived values), and that the conventional two-site sorption kinetics model fails to accurately predict sorption mass transfer in the presence of changing solvent velocity through the reactor. 相似文献
144.
利用西湖淤泥进行低成本有机型基质栽培试验 总被引:6,自引:0,他引:6
以西湖淤泥为主要原料,配以砻糠灰、干鸡粪、菜籽饼等,组配低成本有机型基质,旨在合理开发利用西湖淤泥。处理Ⅰ(西湖淤泥 砻糠灰 干鸡粪)与处理Ⅱ(西湖淤泥 砻糠灰 菜籽饼)均有良好的理化性质,其孔隙度、有机质含量及N、P、K含量适宜樱桃番茄的生长。处理Ⅰ樱桃番茄早期营养生长及前期产量、总产量等方面与对照(泥炭 珍珠岩 泡沫粒)无显著性差异,果实中Vc含量显著高于对照。处理Ⅱ早期营养生长不如对照,但前期产量、总产量与对照无显著性差异,干物质、Vc含量与糖度显著高于对照。处理Ⅰ、处理Ⅱ的成本约为对照的1/2左右。 相似文献
145.
研究了操作参数对活性炭固定床处理有机废气的影响。温度升高,吸附容量下降。湿度的存在会减少活性炭对有机物的吸附容量。适当的操作气速为0.1-0.5m/s,在此范围内,气速与压降在对数坐标上呈线性关系。 相似文献
146.
Miscible-displacement experiments were conducted to examine the impact of microbial lag and bacterial cell growth on the transport of salicylate, a model hydrocarbon compound. The impacts of these processes were examined separately, as well as jointly, to determine their relative effects on biodegradation dynamics. For each experiment, a column was packed with porous medium that was first inoculated with bacteria that contained the NAH plasmid encoding genes for the degradation of naphthalene and salicylate, and then subjected to a step input of salicylate solution. The transport behavior of salicylate was non-steady for all cases examined, and was clearly influenced by a delay (lag) in the onset of biodegradation. This microbial lag, which was consistent with the results of batch experiments, is attributed to the induction and synthesis of the enzymes required for biodegradation of salicylate. The effect of microbial lag on salicylate transport was eliminated by exposing the column to two successive pulses of salicylate, thereby allowing the cells to acclimate to the carbon source during the first pulse. Elimination of microbial lag effects allowed the impact of bacterial growth on salicylate transport to be quantified, which was accomplished by determining a cell mass balance. Conversely, the impact of microbial lag was further investigated by performing a similar double-pulse experiment under no-growth conditions. Significant cell elution was observed and quantified for all conditions/systems. The results of these experiments allowed us to differentiate the effects associated with microbial lag and growth, two coupled processes whose impacts on the biodegradation and transport of contaminants can be difficult to distinguish. 相似文献
147.
A Triassic sandstone aquifer polluted with a mixture of phenolic hydrocarbons has been investigated by means of high-resolution groundwater sampling. Samples taken at depth intervals of 1 m have revealed the presence of a diving pollutant plume with a sharply defined upper margin. Concentrations of pollutant phenols exceed 4 g/l in the plume core, rendering it sterile but towards the diluted upper margin evidence for bacterial sulphate reduction (BSR) has been obtained. Groundwaters have been analysed for both delta34S-SO4 and delta18O-SO4. Two reservoirs have been identified with distinct sulphate oxygen isotope ratios. Groundwater sulphate (delta18O-SO4 = 3-5/1000) outside the plume shows a simple linear mixing trend with an isotopically uniform pollutant sulphate reservoir (delta18O-SO4 = 10-12/1000) across the plume margin. The sulphur isotope ratios do not always obey a simple mixing relation, however, at one multilevel borehole, enrichment in 34SO4 at the plume margin is inversely correlated with sulphate concentration. This and the presence of 34S-depleted dissolved sulphide indicate that enrichment in 34SO4 is the result of bacterial sulphate reduction. Delta34S analysis of trace hydrogen sulphide within the plume yielded an isotope enrichment factor (epsilon) of -9.4/1000 for present-day bacterial sulphate reduction. This value agrees with a long-term estimate (-9.9/1000) obtained from a Rayleigh model of the sulphate reduction process. The model was also used to obtain an estimate of the pre-reduction sulphate concentration profile with depth. The difference between this and the present-day profiles then gave a mass balance for sulphate consumption. The organic carbon mineralisation that would account for this sulphate loss is shown to represent only 0.1/1000 of the phenol concentration in this region of the plume. Hence, the contribution of bacterial sulphate reduction to biodegradation has thus far been small. The highest total phenolic concentration (TPC) at which there is sulphur isotope evidence of bacterial sulphate reduction is 2000 mg/l. We suggest that above this concentration, the bactericidal properties of phenol render sulphate-reducing bacteria inactive. Dissolved sulphate trapped in the concentrated plume core will only be utilised by sulphate reducers when toxic phenols in the plume are diluted by dispersion during migration. 相似文献
148.
利用有机基质厌氧生物产氢的试验研究 总被引:7,自引:0,他引:7
对利用有机基质厌氧生物产氢过程进行了试验研究 ,结果表明 ,污泥种类、基质种类、基质浓度和起始 p H对厌氧产氢反应有显著影响。当校河底泥在以 2 0 g COD/L的果糖为基质 ,起始 p H为 6.5时 ,产氢效果最佳 ,停滞期仅为 5 h,产气速率高达5 0 .1m L/g VSS·h,且可持续 12 h,累积产气量高达 60 4.9m L/g VSS,其中氢气含量约为 5 0 %。半连续试验的结果表明 ,若及时更换和补充基质 ,适当调节 p H,就可实现持续产氢 ,在 16h内平均产气速率可达 60 .0 m L /g VSS· h,氢气含量约为 45 %。 相似文献
149.
Peng Xu Junke Zhang Dongsheng Ji Zirui Liu Guiqian Tang Changsheng Jiang Yuesi Wang 《环境科学学报(英文版)》2018,30(1):16-27
In this study, we performed a highly time-resolved chemical characterization of nonrefractory submicron particles(NR-PM_1) in Beijing by using an Aerodyne high-resolution time-of-flight aerosol mass spectrometer(HR-ToF-AMS). The results showed the average NR-PM_1 mass concentration to be 56.4 ± 58.0 μg/m~3, with a peak at 307.4 μg/m~3. Due to the high frequency of biomass burning in autumn, submicron particles significantly increased in organic content, which accounted for 51% of NR-PM_1 on average. Secondary inorganic aerosols(sulfate + nitrate + ammonium) accounted for 46% of NR-PM_1, of which sulfate,nitrate, and ammonium contributed 15%, 20%, and 11%, respectively. To determine the intrinsic relationships between the organic and inorganic species, we used the positive matrix factorization(PMF) model to merge the high-resolution mass spectra of the organic species and NO+and NO_2~+ions. The PMF analysis separated the mixed organic and nitrate(NO+and NO_2~+) spectra into four organic factors, including hydrocarbon-like organic aerosol(HOA), oxygenated organic aerosol(OOA), cooking organic aerosol(COA), and biomass burning organic aerosol(BBOA), as well as one nitrate inorganic aerosol(NIA) factor. COA(33%) and OOA(30%) contributed the most to the total organic aerosol(OA) mass, followed by BBOA(20%) and HOA(17%). We successfully quantified the mass concentrations of the organic and inorganic nitrates by the NO+and NO2+ions signal in the organic and NIA factors. The organic nitrate mass varied from 0.01-6.8 μg/m~3, with an average of 1.0 ±1.1 μg/m~3, and organic nitrate components accounted for 10% of the total nitrate mass in this observation. 相似文献
150.
测定了竹炭对微污染水源水中CODMn,UV254,UV410的去除效果,研究了竹炭粒径、竹炭用量、吸附时间、溶液pH值对竹炭吸附特性的影响,并由正交试验确定出竹炭去除水中CODMn,UV254,UV410的最佳吸附条件。研究表明,粒径越小,竹炭的吸附效果越好;竹炭用量为100mg、吸附时间为1h时,竹炭对各指标去除率最高;弱酸条件对竹炭对各指标的吸附最有利,当pH值=4时竹炭对各指标的去除率最大;正交试验确定出动态吸附最佳操作条件为:竹炭粒径为100~200目,质量为100mg,振荡吸附1h,原水pH值为4。 相似文献