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71.
四川省彭县银厂沟峡谷全长21公里,峡谷和原始森林保存完整。时隐时现的“彩虹”出现于峡谷两岸的瀑布上。区内自然景观丰富多彩。本文根据旅游地质调查工作成果,对自然景观的成因作了初步探讨。 相似文献
72.
73.
Chung-Ming Liu 《Chemistry and Ecology》1996,12(1):147-161
In this paper, three sensitivity studies are designed to analyze the effect of the NMHC (Non-Methane HydroCarbon) composition, the aerosol back-scattering and the high chimney NOx emission to the photochemical prodution of ozone by using a one-dimensional photochemistry-diffusion model under a favourable meteorological condition. Measurements of the NMHC composition in Taipei indicated that the percentage of iso-butene, cis-2-butene, trans-2-butene and benzene in a unit volume was much higher than of those observed in other major cities. the high ratio of benzene was directly linked to its high percentage in gasoline. As to the unusually high amount of iso-butene, cis-2-butene and trans-2-butene, more researches are needed to identify their source. Concerns are raised as to how productive is NMHC composition is to the photochemical production of the surface ozone. A rough estimate shows that the total reactivity of the Taipei NMHC composition is about 1.21 × 10-9 cm3 s-1 which is 1.6 times that of the Los Angeles (LA) NMHC composition, while the simulated noon peak will be different by 28 ppbv, i.e. 18% more than that simulated with a LA composition.
Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.
In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NOx from high chimneys cannot be ignored. in this study, NOx is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NOx emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated. 相似文献
Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.
In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NOx from high chimneys cannot be ignored. in this study, NOx is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NOx emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated. 相似文献
74.
Trichloroacetic acid (TCAA) is a member of the family of compounds known as chloroacetic acids, which includes mono-, di- and trichloroacetic acid. The significant property these compounds share is that they are all phytotoxic. TCAA once was widely used as a potent herbicide. However, long after TCAA's use as a herbicide was discontinued, its presence is still detected in the environment in various compartments. Methods for quantifying TCAA in aqueous and solid samples are summarized. Concentrations in various environmental compartments are presented, with a discussion of the possible formation of TCAA through natural processes. Concentrations of TCAA found to be toxic to aquatic and terrestrial organisms in laboratory and field studies were compiled and used to estimate risk quotients for soil and surface waters. TCAA levels in most water bodies not directly affected by point sources appear to be well below toxicity levels for the most sensitive aquatic organisms. Given the phytotoxicity of TCAA, aquatic plants and phytoplankton would be the aquatic species to monitor for potential effects. Given the concentrations of TCAA measured in various soils, there appears to be a risk to terrestrial organisms. Soil uptake of TCAA by plants has been shown to be rapid. Also, combined uptake of TCAA from soil and directly from the atmosphere has been shown. Therefore, risk quotients derived from soil exposure may underestimate the risk TCAA poses to plants. Moreover, TCE and TCA have been shown to be taken up by plants and converted to TCAA, thus leading to an additional exposure route. Mono- and di-chloroacetic acids can co-occur with TCAA in the atmosphere and soil and are more phytotoxic than TCAA. The cumulative effects of TCAA and compounds with similar toxic effects found in air and soil must be considered in subsequent terrestrial ecosystem risk assessments. 相似文献
75.
For biofilters treating waste gases containing volatile organic compounds(VOCs), biomass accumulation is a common problem which will induce bed clogging and significant decrease in VOCs removal efficiency during long-term operation. In this study, ozone injection was developed as a biomass control strategy, and its effects on the biofilter performance and the microbial community structure were investigated in long-term operation. Two biofilters,identified as BF1 and BF2, were operated continuously for 160 days treating gaseous toluene under the same conditions, except that 200 mg/m3 ozone was continuously injected into BF1 during days 45–160. During the operation period, ozone injection did not change the toluene removal efficiency, while the pressure drop of BF1 with ozone injection was significantly lowered compared with BF2. The wet biomass accumulation rate of BF1 was 11 g/m~3/hr, which was only46% of that in BF2. According to the carbon balance result, ozone injection also increased the toluene mineralization rate from 83% to 91%, which could be an important reason for the low biomass accumulation. The PMA-q PCR result indicated that ozone injection increased the microbial viability of the biofilm. The high-throughput sequencing result also revealed that the dominant phyla and genera were not changed significantly by ozone injection, but some ozonetolerant genera such as Rhodanobacter, Dokdonella and Rhodococcus were enhanced by ozone exposure. All the results verified that ozone injection is capable of sustaining the long-term performance of biofilters by lowering the biomass accumulation, increasing the microbial viability and changing the microbial community structure. 相似文献
76.
Ashok Kumar Pandey Shri Dhar Pandey Virendra Misra P. N. Viswanathan 《Chemistry and Ecology》1999,16(4):269-282
In order to investigate the role of functional groups present in humic acid(s) (HA) during complex formation, water soluble complexes between HA isolated from soil and metals (Pb, Ca, As, Ni, Cr, Co, Cu, Cd, Fe, Mn, Mg and Zn) were prepared and subjected to infrared (IR) spectroscopy. the IR data revealed the involvement of the - OH group of humic acid in complex formation with all metals except copper and arsenic, whereas the - COOH group of HA was found to be the preferred site of binding for all the metals. the significance of findings in relation to detoxification of environmental pollutants is discussed in this paper. 相似文献
77.
Jeffrey R. Brook Leiming Zhang Yifan Li David Johnson 《Atmospheric environment (Oxford, England : 1994)》1999,33(30):804
Numerical sensitivity tests and four months of complete model runs have been conducted for the Routine Deposition Model (RDM). The influence of individual model inputs on dry deposition velocity as a function of land-use category (LUC) and pollutant (SO2, O3, SO2−4 and HNO3) were examined over a realistic range of values for solar radiation, stability and wind speed. Spatial and temporal variations in RDM deposition velocity (Vd) during June – September 1996 time period generated using meteorological input from a mesoscale model run at 35 km resolution over north-eastern North America were also examined. Comparison of RDM Vd values to a variety of measurements of dry deposition velocities of SO2, O3, SO2−4 and NHO3 that have been reported in the literature demonstrated that RDM produces realistic results. Over northeastern NA RDM monthly averaged dry deposition velocities for SO2 vary from 0.2 to 3.0 cm s−1 with the highest deposition velocities over water surfaces. For O3, the monthly averaged dry deposition velocities are from 0.05 to 1.0 cm s−1 with the lowest values over water surfaces and the highest over forested areas. For HNO3, the monthly averaged dry deposition velocities have the range of 0.5 to 6 cm s−1, with the highest values for forested areas. For SO2−4, they range from 0.05–1.5 cm s−1, with the lowest values over water and the highest over forest. The monthly averaged dry deposition velocities for SO2 and O3 are higher in the growing season compared to the fall, but this behaviour is not apparent for HNO3 and sulphate. In the daytime, the hourly averaged dry deposition velocities for SO2, O3, SO2−4 and HNO3 are higher than that in the nighttime over most of the vegetated area. The diurnal variation is most evident for surfaces with large values for leaf area index (LAI), such as forests. Based on the results presented in this paper, it is concluded that RDM Vd values can be combined with measured air concentrations over hourly, daily or weekly periods to determine dry deposition amounts and with wet deposition measurements to provide seasonal estimates of total deposition and estimates of the relative importance of dry deposition. 相似文献
78.
Katja Riedel Rolf Weller Otto Schrems Gert Knig-Langlo 《Atmospheric environment (Oxford, England : 1994)》2000,34(29-30)
The annual cycles of hydrogen peroxide (H2O2) and methylhydroperoxide (MHP) have been investigated at a remote site in Antarctica in order to study seasonal variations as well as chemical processes in the troposphere. The measurements have been performed from March 1997 to January 1998 and in February 1999 at the German Antarctic research station Neumayer which is located at 70°39′S, 8°15′W. The obtained time series for hydrogen peroxide and methylhydroperoxide in near-surface air represents the first all-year measurements in Antarctica and indicates clearly the occurrence of seasonal variations. During polar night mean values of 0.054±0.046 ppbv (range<0.03–0.11 ppbv) for hydrogen peroxide and 0.089±0.052 ppbv (range<0.05–0.14 ppbv) for methylhydroperoxide were detected. At the sunlit period higher Mixing ratios were found, 0.20±0.13 ppbv (range<0.03–0.91 ppbv) for hydrogen peroxide and 0.19±0.10 ppbv (range<0.05–0.89 ppbv) for methylhydroperoxide. Occasional long-range transport of air masses from mid-latitudes caused enhanced peroxide concentrations at polar night. During the period of stratospheric ozone depletion we observed peroxide mixing ratios comparable to typical winter levels. 相似文献
79.
Ozone concentrations, flux and potential effect on yield during wheat growth in the Northwest-Shandong Plain of China 总被引:1,自引:0,他引:1
Ozone (O3) concentration and flux (Fo) were measured using the eddy covariance technique over a wheat field in the Northwest-Shandong Plain of China. The O3-induced wheat yield loss was estimated by utilizing O3 exposure-response models. The results showed that: (1) During the growing season (7 March to 7 June, 2012), the minimum (16.1 ppbV) and maximum (53.3 ppbV) mean O3 concentrations occurred at approximately 6:30 and 16:00, respectively. The mean and maximum of all measured O3 concentrations were 31.3 and 128.4 ppbV, respectively. The variation of O3 concentration was mainly affected by solar radiation and temperature. (2) The mean diurnal variation of deposition velocity (Vd) can be divided into four phases, and the maximum occurred at noon (12:00). Averaged Vd during daytime (6:00–18:00) and nighttime (18:00–6:00) were 0.42 and 0.14 cm/sec, respectively. The maximum of measured Vd was about 1.5 cm/sec. The magnitude of Vd was influenced by the wheat growing stage, and its variation was significantly correlated with both global radiation and friction velocity. (3) The maximum mean Fo appeared at 14:00, and the maximum measured Fo was − 33.5 nmol/(m2·sec). Averaged Fo during daytime and nighttime were − 6.9 and − 1.5 nmol/(m2·sec), respectively. (4) Using O3 exposure-response functions obtained from the USA, Europe, and China, the O3-induced wheat yield reduction in the district was estimated as 12.9% on average (5.5%–23.3%). Large uncertainties were related to the statistical methods and environmental conditions involved in deriving the exposure-response functions. 相似文献
80.
Ozone (O3) is an important atmospheric oxidant. Black carbon (BC) particles released into the atmosphere undergo an aging process via O3 oxidation. O3-aged BC particles may change their uptake ability toward trace reducing gases such as SO2 in the atmosphere, leading to different environmental and health effects. In this paper, the heterogeneous reaction process between O3-aged BC and SO2 was explored via in-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Combined with ion chromatography (IC), DRIFTS was used to qualitatively and quantitatively analyze the sulfate product. The results showed that O3-aged BC had stronger SO2 oxidation ability than fresh BC, and the reactive species/sites generated on the surface had an important role in the oxidation of SO2. Relative humidity or 254 nm UV (ultraviolet) light illumination enhanced the oxidation uptake of SO2 on O3-aged BC. The oxidation potentials of the BC particles were detected via dithiothreitol (DTT) assay. The DTT activity over BC was decreased in the process of SO2 reduction, with the consumption of oxidative active sites. 相似文献