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521.
玻璃纤维负载P25光催化接触氧化活性艳红X-3B   总被引:14,自引:2,他引:12  
汤心虎  韦朝海  原炜明  张娜 《环境科学》2005,26(5):124-124-127
在玻璃纤维上焙烧P25制备了负载型TiO2光催化剂,探讨了焙烧温度对催化活性的影响,设计了光催化接触氧化反应器,并以活性艳红X-3B为模型污染物,考察溶液pH值、共存阴离子(CO32-、SO42-、Cl-)对光催化反应的影响.结果表明,焙烧温度直接影响负载后催化剂的活性,300℃负载时活性最高,SEM照片显示此时P25与载体结合牢固、负载颗粒均匀.酸性条件对活性艳红X-3B的降解有利,当溶液初始pH由2.0上升到10.0时,活性艳红X-3B的降解率从90.06%下降至42.71%.共存的CO32-、SO42-对活性艳红X-3B降解的影响不大,但Cl-对氧化过程有明显的抑制,使活性艳红X-3B的降解率下降17.03%.利用成熟的光催化剂P25,通过烧结的方法制备负载型催化剂是当前替代粉末催化剂的较为可行的方案.  相似文献   
522.
ABSTRACT. Establishment of seagrass‐based pollutant load reduction targets is a major aim of water quality management in the Indian River Lagoon (IRL) estuary. It is believed that light and water clarity are the limiting factors affecting seagrass abundance and distribution in the Lagoon. Thus, targeted reductions of nutrients, dissolved organic matter and for suspended sediments should achieve desired seagrass coverage goals. On an annual average, the Lagoon is receiving external loadings of 5,346, 771, and 54,408 metric tons per year of nitrogen (N), phosphorus (P), and total suspended solids (TSS), respectively. Most of the loadings are stormwater generated; thus, implementation of reduction targets will key in on major urban and agricultural stormwater systems. The process of developing targets requires the establishment of light requirements for seagrass. Two methods are being employed to develop such targets. One method is the application of a predictive, 3‐D model that accounts for the essential interactive processes of the Lagoon: hydrology, hydrodynamics, water quality, nutrient uptake/release, seagrass growth rates, and light attenuation. The other method is based simply on the comparison of loading rates between a developed sub‐basin with associated seagrass impacts and an undeveloped sub‐basin with adjacent healthy seagrass coverages. The latter method will provide the initial and preliminary targets that can be tested, confirmed, or modified by application of the 3‐D model.  相似文献   
523.
珠江三角洲稻田土壤砷及其向水稻籽粒迁移特征   总被引:2,自引:0,他引:2  
采集珠江三角洲区域水稻(Oryze sativa L.)植株的根系、秸秆、稻谷和对应的耕层土壤(0~15锄)样品,分析土壤和水稻植株中砷含量,初步研究土壤砷与土壤基本理化性质的关系及砷在土壤-水稻系统中的迁移规律.结果表明,土壤砷含量在1.83~18.14 mg·kg~(-1)之间,土壤砷与土壤有机质、砂粒含量呈显著负相关,与土壤粉粒含量呈显著正相关.糙米中的砷含量在0.21~0.43mg·kg~(-1)之间,均未超过国家食品卫生标准(0.7mg·kg~(-1)),砷在水稻植株中的分布规律为根>秸秆>颖壳>糙米.糙米砷含量与秸秆砷含量呈极显著正相关,与秸秆中P/As、Si/As摩尔比呈极显著负相关,因此,降低秸秆中As的积累、增加秸秆中P、Si的积累可降低水稻籽粒中的砷含量.  相似文献   
524.
The fatty acid rich fraction obtained from the petroleum ether extractable portion of Hydnocarpus laurifolia (PHL) seeds exhibited significant insecticidal action on rice bug, Leptocorisa acuta (LC50 8?mg/mL). Analysis of the fatty acid content of PHL by GC/MS showed that it contained chaulmoogric acid, hydnocarpic acid, gorlic acid, lignoceric acid, palmitic acid, oleic acid and stearic acid. Among these fatty acids chaulmoogric acid and hydnocarpic acid were present in highest amount. The PHL showed no genotoxic effect in bone marrow erythrocytes of Swiss mice as compared with methyl methane sulfonate. Metabolism of PHL was evaluated by monitoring the activities of xenobiotic metabolizing enzymes and on comparison with malathion (a synthetic pesticide) revealed that PHL was found to be metabolized and excreted from the body of Sprague-Dawley rats within 72?h of exposure.  相似文献   
525.
Many observations are reported that organic mercury compounds are involved in increasing intracellular Ca2+ levels. However, the issue of which substances on the cell membrane participate in the Ca2+ uptake that is induced by ethyl mercury is unclear. The findings of this study suggest that the P2X receptor participates in this process. The uptake of Ca2+ by C8-B4 cells was induced in the presence of ethyl mercury. Ca channels in the cell membrane were not affected in this process. In contrast, pretreatment with suramin, an antagonist of the P2X receptor, inhibited the Ca2+ uptake induced by ethyl mercury, and also brilliant blue G, a nonselective antagonist of P2×4, P2×5, and P2×7 receptors. In addition, A438079 and A740003, selective antagonists of P2×7 receptor, reduced Ca2+ uptake, while 5-BDBD, a selective antagonist of P2×4 receptor, did not. Furthermore, the mRNAs of both the P2×4 and P2×7 receptors were expressed in the presence of ethyl mercury, but the P2×5 receptor mRNA was not. These findings suggest that ethyl mercury may induce Ca2+ uptake through the P2×7 receptor of the cell membrane.  相似文献   
526.
N‐acetyltransferase (NAT) activity was determined in different ages of New Zealand White rabbit pineal gland using 2‐aminofluorene and p‐aminobenzoic acid as substrates and it was assayed by high pressure liquid chromatography. Rabbits of different ages were either sacrificed during the light phase, exposed to darkness or light for 1 min during the dark phase of the lighting cycle, returned to their cages in darkness for 30 min and then sacrificed. Pineal gland NAT activity in animal nocturnally exposed to 1 min of light was inhibited in animals 1 ‐day‐old of age. Nocturnal light exposure did not inhibit enzyme activity in 1‐day‐old rabbit, even though these animal displayed clear light : dark differences in pineal gland NAT activity. Nocturnal light exposure also did not inhibit night time levels of NAT activity in 1‐day‐old animals who had been bilaterally enucleated. The result suggested that this effect is retinally mediated. Pre‐treatment of 1‐day‐old and 60‐day‐old animals with the isoproterenol (beta‐noradrenoreceptor agonist drug), prevented the nocturnal light‐induced inhibition of NAT activity. The different sensitivity of 60‐day‐old and 1‐day‐old animals to different illuminances or durations of nocturnal light exposure, was that the duration or intensity of light exposure was enable to inhibit nocturnal NAT activity. The NAT activity was at least 3.2‐ to 4.6‐fold greater in 1‐day‐old rabbits compared to 60‐day‐old rabbits. Kinetic constants for arylamine NAT activity in pineal gland from rabbits were determined. Km and Fmax values for 2‐aminofluorene were 2.6‐fold higher for light exposure than for no light exposure rabbits. This is the first demonstration of the retina‐pineal gland pathway appears light‐induced changes in pineal glands of animals in 1‐day‐old of ages or older; but this pathway does not function in 60‐day‐old rabbits like manner in 1‐day‐old rabbits.  相似文献   
527.
通过工程实例介绍VAV系统在P3实验室环境控制过程中的应用,提出了影响环境压差变化的多方面的扰动因素,并针对外扰因素进行系统的分析,合理设计系统结构,并且准确地选取控制参数,来控制多台变频器工作,克服外扰对系统各区域压差的影响,实现环境指标的实时监控。  相似文献   
528.
The work reported compared the predictive ability of two theories of aesthetic behaviour, using normal, everyday objects. This involved utilizing simulated items of furniture in three experiments in which predictions deduced from the ‘collative-motivation’ model and what has been termed a ‘preference-for-prototypes’ model were made to compete empirically. For each of the five pairs of discrepant expectations formulated in the three experiments the outcomes were inconsistent with Berlyne's model, while supporting the prototypicality model. A number of theoretical implications are drawn from these findings.  相似文献   
529.
ABSTRACT: Data from seven diverse lakes with reasonably complete nutrient budgets and estimates of annual areal nitrogen fixation (AANF) were used to evaluate the proposition that nitrogen fixation (NF) declines as the ratio TN:TP in lake loadings increases. The results do not support the conclusion that the rate of AANF in lakes is related to the N:P ratio in externally generated influents, although low N:P nutrient loading ratios often favor blue-green algae capable of NF.  相似文献   
530.
分析了1972~1997年霍山窗小震的资料,研究了小震月频次、小震空间分布、P轴取向、P波初动等特征。认为当霍山窗小震月频次增高超过40次时应注意3个月内华东地区在佛子岭东北或西南方向500km内可能发生中强地震。未来地震的大小、距离和方位与震群中的最大震级及佛子岭台记录到的P波初动符号的一致性和空间特征有关。  相似文献   
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