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91.
Source identification of polycyclic aromatic hydrocarbons in environmental samples has advanced greatly in the last 20 years and continues to advance. To realize potential benefits and avoid possible pitfalls, however, great care is needed as one applies published diagnostic tools to data sets. This commentary reflects some recent observations, concerns, and recommendations. 相似文献
92.
A method involving high resolution gas chromatography combined with ion trap (HRGC-MS/MS) and negative chemical ionisation
(NCI) was developed for the determination of nitrated or oxygenated polycyclic aromatic hydrocarbons (nitro-PAHs, oxy-PAHs)
and other electrophilic substitutes in soil samples. Efficient clean-up was achieved by a combination of methods for the determination
of PAHs in soil and nitro-PAHs in aerosol using solid phase extraction (SPE) and semipreparative high performance liquid chromatography
(HPLC). In samples of surface soil from the city of Basle (Switzerland), nitro-PAHs (mainly 3-nitrofluoranthene and 1-nitropyrene)
were found in concentrations between 30 and 800 ng/kg dry weight. Oxy-PAHs and parent PAHs revealed 102-104-fold higher levels. Nitro-PAHs which are up to 105 times more mutagenic seem to be less persistent in soil than the parent forms, although their entire mutagenic potential
has to be estimated as being on the same order of magnitude. In urban air particulate matter, the amounts of nitro-PAHs (2–62
pg/m3) were 10–100 times lower than oxyPAHs and parent PAHs which were both found in a similar range. 3-nitrobenzanthrone, a recently
described suspected human carcinogen has not yet been detected. Using multivariate statistical analysis, it was possible to
elucidate similarities or special characteristics of substances in a given matrix reflecting their chemical properties or
specific emission sources. 相似文献
93.
The application of a mulch biofilm barrier for surfactant enhanced polycyclic aromatic hydrocarbon bioremediation 总被引:1,自引:0,他引:1
Lab scale mulch biofilm barriers were constructed and tested to evaluate their performance for preventing the migration of aqueous and surfactant solubilized PAHs. The spatial distribution of viable PAH degrader populations and resultant biofilm formation were also monitored to evaluate the performance of the biobarrier and the prolonged surfactant effect on the PAH degrading microorganism consortia in the biobarrier. Sorption and biodegradation of PAHs resulted in stable operation of the system for dissolved phenanthrene and pyrene during 150 days of experimentation. The nonionic surfactant could increase the solubility of phenanthrene and pyrene significantly. However, the biobarrier itself couldn't totally prevent the migration of micellar solubilized phenanthrene and pyrene. The presence of surfactant and the resultant highly increased phenanthrene or pyrene concentration didn't appear to cause toxic effects on the attached biofilm in the biobarrier. However, the presence of surfactant did change the structural composition of the biofilm. 相似文献
94.
Application of positive matrix factorization to identify potential sources of PAHs in soil of Dalian, China 总被引:2,自引:0,他引:2
Degao Wang Fulin Tian Chenlin Liu 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1559-1564
Soil derived sources of polycyclic aromatic hydrocarbons (PAHs) in the region of Dalian, China were investigated using positive matrix factorization (PMF). Three factors were separated based on PMF for the statistical investigation of the datasets both in summer and winter. These factors were dominated by the pattern of single sources or groups of similar sources, showing seasonal and regional variations. The main sources of PAHs in Dalian soil in summer were the emissions from coal combustion average (46%), diesel engine (30%), and gasoline engine (24%). In winter, the main sources were the emissions from coal-fired boiler (72%), traffic average (20%), and gasoline engine (8%). These factors with strong seasonality indicated that coal combustion in winter and traffic exhaust in summer dominated the sources of PAHs in soil. These results suggested that PMF model was a proper approach to identify the sources of PAHs in soil. 相似文献
95.
M. Ianistcki C. Sauer J. da Silva 《Environmental pollution (Barking, Essex : 1987)》2009,157(7):2037-2042
The purpose of this study was to biomonitor metropolitan areas of Porto Alegre (Brazil) for PAHs associated with atmospheric particles and check their effects on the DNA of the land mollusk Helix aspersa. The sampling sites are located in an urban area with heavy traffic: (i) Canoas, (ii) Sapucaia do Sul, and (iii) FIERGS/Porto Alegre. The samples were collected during a continuous period of 24 hours during 15 days using Stacked Filter Units (SFU) on polycarbonate filters (two separated size fractions: PM10-2.5 and PM<2.5). The concentrations of 16 major PAHs were determined according to EPA. Comet assay on H. aspersa hemolymph cells was chosen for genotoxicity evaluation. This evaluation shows that, in general, the smaller PM-size fractions (PM<2.5) have the highest genotoxicity and contain higher concentrations of extractable organic matter. In addition, associations between chemical characteristics and PM carcinogenicity tend to be stronger for the smaller PM-size fractions. 相似文献
96.
Sex ratios were bimodally distributed in a population of the monogynous and monandrous ant Leptothorax nylanderi during each of 3 study years. The population-wide investment ratios suggested worker control of sex allocation. Nest-level
variation in the proportional investment in virgin queens was not affected by the presence or absence of a queen and only
slightly by collecting year, but was correlated with nest size, total sexual investment and, unexpectedly, with differences
in nestmate relatedness: small, low-investment nests and nests with several worker lineages produced male-biased sex ratios.
Colonies containing several worker lineages arise from usurpation of mature colonies by unrelated founding queens and the
fusion of unrelated colonies under strong nest site limitation. In contrast to facultatively polygynous and polyandrous species
of social insects, where workers can maximize their inclusive fitness by adjusting sex ratios according to the degree of relatedness
asymmetry, workers in mixed colonies of L. nylanderi do not benefit from manipulating sex allocation, as here relatedness asymmetries appear to be the same as in homogeneous
colonies.
Received: 7 December 1999 / Received in revised form: 29 February 2000 / Accepted: 13 March 2000 相似文献
97.
M. T. Henshaw J. E. Strassmann D. C. Queller 《Behavioral ecology and sociobiology》2000,48(6):478-483
When cooperation is based on shared genetic interests, as in most social insect colonies, mechanisms which increase the genetic
similarity of group members may help to maintain sociality. Such mechanisms can be especially important in colonies with many
queens because within-colony relatedness drops quickly as queen number increases. Using microsatellite markers, we examined
the Old World, multiple-queen, swarm-founding wasp Polybioides tabidus which belongs to the ropalidiine tribe, and found that relatedness among the workers was four times higher than what would
be expected based on queen number alone. Relatedness was elevated by a pattern of queen production known as cyclical oligogyny,
under which, queen number varies, and daughter queens are produced only after the number of old queens has reduced to one
or a very few. As a result, the queens are highly related, often as full sisters, elevating relatedness among their progeny,
the workers. This pattern of queen production is driven by collective worker control of the sex ratios. Workers are three
times more highly related to females than to males in colonies with a single queen while they are more equally related to
males and females in colonies with more queens. As a result of this difference, workers will prefer to produce new queens
in colonies with a single queen and males in colonies with many queens. Cyclical oligogyny has also evolved independently
in another group of swarm-founding wasps, the Neotropical epiponine wasps, suggesting that collective worker control of sex
ratios is widespread in polistine wasps.
Received: 22 May 2000 / Revised: 24 August 2000 / Accepted: 4 September 2000 相似文献
98.
A Pilot Study on Using Urinary 1-Hydroxypyrene Biomarker for Exposure to PAHs in Beijing 总被引:3,自引:0,他引:3
Zhang W Xu D Zhuang G Ding C Wang G Chang J Ren G 《Environmental monitoring and assessment》2007,131(1-3):387-394
To study whether the urinary 1-hydroxypyrene (1-OHP) could be the biomarker of atmospheric PAHs, a small-scale pilot study
was carried out on the relation of 1-OHP vs PAHs with the traffic policemen in Beijing of smokers and nonsmokers to be subgroups
in both the exposure and control groups. Both the PAHs and 1-OHP were analyzed with high performance liquid chromatography
(HPLC). The ambient concentrations of PAHs were different at the different sites (the average sum of PAHs (TPAH) were 12.36,
16.27, 18.37 ng/m3 at the suburban residential, police station and high traffic area, respectively.), but considerably lower than the personal-exposure
concentrations (the average TPAH were 65.84 and 47.28 ng/m3 for patrol cars and inspection station, respectively). Pyrene was correlated well with BaP and the summed PAHs (TPAH), with
the correlation coefficients (R) of 0.79, 0.87 for ambient level and 0.92, 0.96 for personal exposure, respectively. The average of 1-hydroxypyrene of smokers
and nonsmokers were 0.39, 0.15 μmol/mol creatinine in control group and 0.57, 0.33 μmol/mol creatinine in exposure group,
respectively. The better correlation of pyrene to BaP and TPAH especially for personal exposure samples indicated that the
probability of urinary 1-hydroxypyrene, the metabolite of pyrene, to be the biomarker of total PAH. Nonsmokers in the exposure
and control groups had indistinguishable levels of 1-OHP, presumably because the ambient levels of pyrene were so similar
(the average were 3.25, 3.20 ng/m3 at the police station and high traffic area, respectively.). Smokers in the control group had significantly higher 1-OHP
than that of the nonsmokers, but showed indistinguishable differences in the exposure group. These results suggested that
urinary 1-OHP could be a biomarker of PAHs only when the level of PAHs was at a relatively higher level. Smoking as an important
influencing factor need to be controlled carefully. 相似文献
99.
辽宁省大气可吸入颗粒物中重金属及多环芳烃污染特征研究 总被引:4,自引:0,他引:4
为全面了解辽宁省大气可吸入颗粒物污染状况,2004年在省内选取了5个城市进行分季节采样,并对颗粒物中重金属元素含量和美国优先控制的16种多环芳烃(PAHs)进行了定量研究。结果表明,大气PM10和PM2.5中重金属元素和PAHs污染较重,且冬季高于其它季节,重金属元素和PAHs主要富集在PM2.5及以下细小颗粒物中。 相似文献
100.
In order to improve and optimize phytoremediation of PAH we propose to focus on the rhizospheric processes controlling PAH
degradation. In this paper the effect of root exudates on PAH availability is studied. Model organic compounds (malic acid,
malonic acid and EDTA) representing root exudates have been tested for their effect on phenanthrene sorption on a reference
non polluted agricultural soil material. Phenanthrene adsorption isotherms were first obtained with batch experiments. Results
showed linear isotherms and phenanthrene sorption was enhanced as the concentration of organic compounds in the solution increased.
Column leaching experiments were then used to simulate the effect of root exudation following the soil pollution. Inlet solutions
containing the different organic acids used were flowed through the column containing the artificially polluted soil material.
Elution curves showed that the phenanthrene was less easily eluted when the solution injected contained the organic acids.
However, magnitude of the phenomena did not fit with adsorption constants obtained in batch experiments. Phenanthrene desorption
appeared limited by sequestration but organic acids seemed able to partially disturb the soil material structure to limit
the sequestration effect. 相似文献