Analysis of dust distribution in silo during axial filling using computational fluid dynamics: Assessment on dust explosion likelihood

In this study, the dust distribution in a silo during axial filling was modelled using a commercial computational fluid dynamics (CFD) code. The work focused on the dust concentration distribution in the silo, for evaluating the likelihood of a dust explosion in the silo. The simulation was conducted using a combination of renormalized (RNG) k-epsilon and discrete phase models, with standard pressure interpolation and a second order upwind scheme. The predicted dust concentration distribution showed a good agreement with experimental data adopted from the literature. It was found that the dust concentration distribution was influenced by mean velocity and turbulence flow. The simulation results suggest that the cornstarch concentration inside the silo was always above the lower explosion limit (LEL), hence requiring a mitigating action or a control system to reduce the explosion risk.     

Enhanced styrene recovery from waste polystyrene pyrolysis using response surface methodology coupled with Box–Behnken design

A work applied response surface methodology coupled with Box–Behnken design (RSM-BBD) has been developed to enhance styrene recovery from waste polystyrene (WPS) through pyrolysis. The relationship between styrene yield and three selected operating parameters (i.e., temperature, heating rate, and carrier gas flow rate) was investigated. A second order polynomial equation was successfully built to describe the process and predict styrene yield under the study conditions. The factors identified as statistically significant to styrene production were: temperature, with a quadratic effect; heating rate, with a linear effect; carrier gas flow rate, with a quadratic effect; interaction between temperature and carrier gas flow rate; and interaction between heating rate and carrier gas flow rate. The optimum conditions for the current system were determined to be at a temperature range of 470–505 °C, a heating rate of 40 °C/min, and a carrier gas flow rate range of 115–140 mL/min. Under such conditions, 64.52% WPS was recovered as styrene, which was 12% more than the highest reported yield for reactors of similar size. It is concluded that RSM-BBD is an effective approach for yield optimization of styrene recovery from WPS pyrolysis.     

Photo- and electro-catalysis for solar disinfection of Escherichia coli-contaminated water using Ag–TiO2/graphite

A titanium dioxide film on a graphite substrate was synthesized by chemical bath deposition from TiCl₄ as precursor and with the surfactant cetyl trimethyl ammonium bromide as a linking and assembling agent. Silver was loaded on the TiO₂ film by electrodeposition at 0.025?A. Water contaminated with Escherichia coli was disinfected under sunlight irradiation by photolysis (Lys), photocatalysis (PC), photoelectrocatalysis (PEC), and electrocatalysis (EC). The highest rate constant, k, was achieved with EC; k was 5.1?×?10^?2 colony forming units (CFU) mL^?1?min^?1. However, auto-oxidation of Ag occurred during EC and PEC. Meanwhile, the rate constant of disinfection by means of PC was lower than EC and PEC, and k was 3.82?×?10^?2 CFU?mL^?1?min^?1. Nevertheless, the auto-oxidation of Ag in the Ag–TiO₂/graphite tablet did not occur during the disinfection process.     

Assessing the costs for adaptation of marine constructions to sea-level rise

Marine constructions are highly vulnerable to climate change and sea-level rise (SLR), leading to increased risk rates of destruction and the potential closure of ports, harbors, and marinas along the coast. We present a cost-adjustment analysis for such constructions along the south-eastern Mediterranean coast, which takes into account the physical characteristics of the constructions, and environmental uncertainty factors. At 0.5 m SLR, the estimated adjustment cost is USD 280 million, and at 1 m SLR, the estimated cost is USD 505 million. These costs are equivalent to 0.091% and 0.165% of the Israeli gross domestic production, respectively. Although high, these adjustment costs are lower than the costs of future damage that will accrue if we fail to act. This implies that the adaptation-policy approach to controlling for the risk of SLR will provide benefits to the economic marine sectors and the public at large.     

Seven years from the first application of polyaluminium chloride in the Czech Republic – effects on phytoplankton communities in three water bodies

This study determines the efficiency of polyaluminium chloride application on phytoplankton species as a consequence of five reservoir restorations in the Czech Republic during the years 2005 and 2008, including the first ever large-scale application. Although polyaluminium chloride has been used in water treatment plants across the world, information about its application toward cyanobacterial blooms in nature is poor. Although the application of polyaluminium chloride did not cause any fundamental long-term changes in the composition of phytoplankton species or phosphorus load, instead causing fast and acute removal of the phytoplankton community, it may act as an algicidal compound with fast removal efficiency. All treated water bodies described in our study remained unaffected by cyanobacterial blooms and the hygienic limit for the purposes of recreation was not exceeded in any particular season. This article should serve as notice of the advantages and disadvantages of polyaluminium chloride application, and also warn against the uniform usage of this chemical as a method of reducing phytoplankton species in all types of water bodies where cyanobacteria are present. Moreover, data about the effects on non-target (invertebrates) species and microcystin release from cyanobacterial cells are also mentioned.     

Mitigation translocation as a management tool

Mitigation translocation is a subgroup of conservation translocation, categorized by a crisis-responsive time frame and the immediate goal of relocating individuals threatened with death. However, the relative successes of conservation translocations with longer time frames and broader metapopulation- and ecosystem-level considerations have been used to justify the continued implementation of mitigation translocations without adequate post hoc monitoring to confirm their effectiveness as a conservation tool. Mitigation translocations now outnumber other conservation translocations, and understanding the effectiveness of mitigation translocations is critical given limited global conservation funding especially if the mitigation translocations undermine biodiversity conservation by failing to save individuals. We assessed the effectiveness of mitigation translocations by conducting a quantitative review of the global literature. A total of 59 mitigation translocations were reviewed for their adherence to the adaptive scientific approach expected of other conservation translocations and for the testing of management options to continue improving techniques for the future. We found that mitigation translocations have not achieved their potential as an effective applied science. Most translocations focused predominantly on population establishment- and persistence-level questions, as is often seen in translocations more broadly, and less on metapopulation and ecosystem outcomes. Questions regarding the long-term impacts to the recipient ecosystem (12% of articles) and the carrying capacity of translocation sites (24% of articles) were addressed least often, despite these factors being more likely to influence ultimate success. Less than half (47%) of studies included comparison of different management techniques to facilitate practitioners selecting the most effective management actions for the future. To align mitigation translocations with the relative success of other conservation translocations, it is critical that future mitigation translocations conform to an established experimental approach to improve their effectiveness. Effective mitigation translocations will require significantly greater investment of time, expertise, and resources in the future.     

Determination of propineb and its metabolites propylenethiourea and propylenediamine in banana and soil using gas chromatography with flame photometric detection and LC–MS/MS analysis

A sensitive and specific method for the determination of propineb and its metabolites, propylenethiourea (PTU) and propylenediamine (PDA), using gas chromatography with flame photometric detection (GC-FPD) and LC–MS/MS was developed and validated. Propineb and its metabolite residue dynamics in supervised field trials under Good Agricultural Practice (GAP) conditions in banana and soil were studied. Recovery of propineb (as CS₂), PDA and PTU ranged from 75.3 to 115.4% with RSD (n = 5) of 1.3–11.1%. The limit of quantification (LOQ) of CS₂, PDA and PTU ranged from 0.005 to 0.01 mg kg^?1, and the limit of detection (LOD) ranged from 0.0015 to 0.0033 mg kg^?1. Dissipation experiments showed that the half-life of propineb in banana and soil ranged from 4.4 to 13.3 days. PTU was found in banana with a half-life of 31.5–69.3 days, while levels of PDA were less than 0.01 mg kg^?1 in banana and soil. It has been suggested that PTU is the major metabolite of propineb in banana. The method was demonstrated to be reliable and sensitive for the routine monitoring of propineb and its metabolites in banana and soil. It also serves as a reference for the detection and monitoring of dithiocarbamates (DTCs) residues and the evaluation of their metabolic pathway.     

A Parallel Graded-Mesh FDTD Algorithm for Human–Antenna Interaction Problems

The finite difference time domain method (FDTD) is frequently used for the numerical solution of a wide variety of electromagnetic (EM) problems and, among them, those concerning human exposure to EM fields. In many practical cases related to the assessment of occupational EM exposure, large simulation domains are modeled and high space resolution adopted, so that strong memory and central processing unit power requirements have to be satisfied. To better afford the computational effort, the use of parallel computing is a winning approach; alternatively, subgridding techniques are often implemented. However, the simultaneous use of subgridding schemes and parallel algorithms is very new. In this paper, an easy-to-implement and highly-efficient parallel graded-mesh (GM) FDTD scheme is proposed and applied to human–antenna interaction problems, demonstrating its appropriateness in dealing with complex occupational tasks and showing its capability to guarantee the advantages of a traditional subgridding technique without affecting the parallel FDTD performance.     

Explosions of gasoline–air mixture in the tunnels containing branch configuration

In order to investigate the effects of branch tunnels on explosion propagation, experiments were performed in five different configuration tunnels (straight configuration and configurations with 1 branch, 2 branches, 3 branches and 4 branches). Pressure and flame transducers were used to record the history of the pressure development and track the velocity of the flame front. It was shown that the branch tunnels had ability to enhance the maximum overpressure, rate of overpressure rise, and deflagration index (K_G) of the gasoline–air mixture explosion due to the turbulence induced by the branch tunnels. The overpressure rise rate and K_G of the explosion increased as a function of the number of branch tunnels. Experiments also showed that the maximum flame speed increased as the branch number increasing from 0 to 3 due to the enlargement of turbulence induced by the branch tunnels. However, an increase of branch number did not always lead to an enhancement of flame speed because the heat loss was intensified resulting from the increase of flame surface caused by the branch tunnels. When the number of branch tunnels exceeded 3, the maximum flame speed dropped.