全文获取类型
收费全文 | 115篇 |
免费 | 3篇 |
国内免费 | 26篇 |
专业分类
安全科学 | 16篇 |
废物处理 | 6篇 |
环保管理 | 8篇 |
综合类 | 42篇 |
基础理论 | 43篇 |
污染及防治 | 18篇 |
评价与监测 | 7篇 |
社会与环境 | 3篇 |
灾害及防治 | 1篇 |
出版年
2024年 | 1篇 |
2023年 | 6篇 |
2022年 | 1篇 |
2021年 | 6篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 10篇 |
2014年 | 1篇 |
2013年 | 14篇 |
2012年 | 11篇 |
2011年 | 10篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 9篇 |
2007年 | 6篇 |
2006年 | 6篇 |
2005年 | 3篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有144条查询结果,搜索用时 375 毫秒
41.
Zhizhuo Liu Zhemin Shen Shouyan Xiang Yang sun Jiahua Cui Jinping Jia 《Frontiers of Environmental Science & Engineering》2023,17(3):31
42.
43.
Sundström M Bogdanska J Pham HV Athanasios V Nobel S McAlees A Eriksson J DePierre JW Bergman Å 《Chemosphere》2012,87(8):865-871
Here, we describe for the first time the synthesis of [35S] PFOS and [35S] PFBS with sulfur-35 enriched sulfur dioxide as the radiolabelled reagent, resulting in 2.5 and 2.3 mCi of product, respectively. Basic information concerning the physicochemical properties of perfluorooctanesulfonate (PFOS), perfluorobutanesulfonate (PFBS) and perfluorooctanoic acid (PFOA) are still limited. Hence, we utilized these radiolabelled perfluoroalkanesulfonates (PFSAs), as well as carbon-14 labelled perfluorooctanoic acid ([14C] PFOA) to determine some basic characteristics of physiological and experimental significance.The solubility of PFOS in buffered aqueous solutions at pH 7.4 was found to be severely reduced in the presence of potassium and sodium ions, which, however, did not reduce the solubility of PFOA or PFBS. PFOS was found to adhere to a small extent to polypropylene and polystyrene, whereas no such adhesion of PFOA or PFBS was detected. The extents of adhesion of PFOS and PFOA to glass were found to be 20% and 10%, respectively. For the first time, the partition coefficients for PFOS, PFBS and PFOA between n-octanol and water were determined experimentally, to be −0.7, −0.3, and 1.4, respectively, reflecting the difference in the amphiphilic natures of these molecules. 相似文献
44.
Pragmatic estimation of a spatio-temporal air quality model with irregular monitoring data 总被引:2,自引:0,他引:2
Paul D. Sampson Adam A. Szpiro Lianne Sheppard Johan Lindström Joel D. Kaufman 《Atmospheric environment (Oxford, England : 1994)》2011,45(36):6593-6606
Statistical analyses of health effects of air pollution have increasingly used GIS-based covariates for prediction of ambient air quality in “land use” regression models. More recently these spatial regression models have accounted for spatial correlation structure in combining monitoring data with land use covariates. We present a flexible spatio-temporal modeling framework and pragmatic, multi-step estimation procedure that accommodates essentially arbitrary patterns of missing data with respect to an ideally complete space by time matrix of observations on a network of monitoring sites. The methodology incorporates a model for smooth temporal trends with coefficients varying in space according to Partial Least Squares regressions on a large set of geographic covariates and nonstationary modeling of spatio-temporal residuals from these regressions. This work was developed to provide spatial point predictions of PM2.5 concentrations for the Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air) using irregular monitoring data derived from the AQS regulatory monitoring network and supplemental short-time scale monitoring campaigns conducted to better predict intra-urban variation in air quality. We demonstrate the interpretation and accuracy of this methodology in modeling data from 2000 through 2006 in six U.S. metropolitan areas and establish a basis for likelihood-based estimation. 相似文献
45.
对3类适用于酚类物质的衍生方法进行比较。结果显示,3种衍生方法均具有改善峰形、提高检测灵敏度、降低检出限等优势。其中七氟丁酸酐衍生法具有较大的腐蚀性;TMS衍生体系对水分非常敏感,需确保衍生体系脱水充分;五氟苄基溴衍生相对更成熟和完善。 相似文献
46.
The study examined the adsorption of Pb(Ⅱ) ions from aqueous solution onto chitosan, chitosan-GLA and chitosan-alginate beads.Several important parameters influencing the adsorption of Pb(Ⅱ) ions such as initial pH, adsorbent dosage and different initial concentration of Pb(Ⅱ) ions were evaluated. The mechanism involved during the adsorption process was explored based on ion exchange study and using spectroscopic techniques. The adsorption capacities obtained based on non-linear Langmuir isotherm for chitosan, chitosan-GLA and chitosan-alginate beads in single metal system were 34.98, 14.24 and 60.27 mg/g, respectively. However,the adsorption capacity of Pb(Ⅱ) ions were reduced in the binary metal system due to the competitive adsorption between Pb(Ⅱ) and Cu(Ⅱ) ions. Based on the ion exchange study, the release of Ca~(2+), Mg~(2+), K~+ and Na~+ ions played an important role in the adsorption of Pb(Ⅱ) ions by all three adsorbents but only at lower concentrations of Pb(Ⅱ) ions. Infrared spectra showed that the binding between Pb(Ⅱ) ions and the adsorbents involved mostly the nitrogen and oxygen atoms. All three adsorbents showed satisfactory adsorption capacities and can be considered as an efficient adsorbent for the removal of Pb(Ⅱ) ions from aqueous solutions. 相似文献
47.
苯酚及其衍生物对氨氮生物硝化的抑制研究 总被引:1,自引:0,他引:1
利用富集培养的硝化污泥研究了苯酚及其衍生物2,4-二氯苯酚、对氨基酚、邻甲基酚和对硝基酚对氨氮生物硝化过程的抑制特性。结果表明,上述5种酚类化合物对硝化细菌的抑制类型均为非竞争性抑制,抑制常数KI和EC50值相等,分别为2.61、1.92、8.50、1.18和6.65 mg/L。上述5种酚类化合物对硝化细菌的抑制程度由大到小的顺序为:邻甲基酚〉2,4-二氯苯酚〉苯酚〉对硝基酚〉对氨基酚。酚类化合物对硝化细菌的抑制是可逆的,通过简单的抑制剂稀释或洗涤可以使硝化细菌恢复活性。在保证出水水质的前提下,抑制剂存在时硝化工艺的泥龄被迫延长,且抑制程度越大,泥龄延长的程度越大。当系统受到有毒物质冲击时,和调控泥龄相比,调节工艺的进水流量或改变容积负荷是缓冲冲击的更简捷、快速和有效的途径。 相似文献
48.
均匀设计用于研究硝基苯衍生物对青海弧菌Q67的联合毒性 总被引:2,自引:0,他引:2
实验设计在混合物毒性评估与预测中起着非常重要的作用. 应用微板毒性测试方法测定了7种硝基苯衍生物对青海弧菌Q67的发光抑制毒性,硝基苯、邻氯硝基苯、间氯硝基苯、对氯硝基苯、间硝基苯胺、对硝基苯胺和对硝基甲苯的-lg EC50值(EC50的单位为mol/L)分别为2.66,3.22,3.30,3.29,2.94,4.22和3.39;引入均匀实验设计方法,在单个硝基苯衍生物剂量-效应关系基础上构建不同效应浓度下的10个混合物,同样应用微板毒性测试方法测定其对Q67的毒性,应用剂量加和(DA)与独立作用(IA)原理建立了混合物毒性的评估与预测模型. 结果表明:与等效应浓度比法相比,均匀实验设计构建的混合物浓度配比,具有三维浓度分布特征,可在更大范围内考察各种可能的混合物类型,更加接近于实际环境体系. 相似文献
49.
多糖及其衍生物抗病毒作用研究进展 总被引:44,自引:1,他引:44
近年来,多糖及其衍生物的抗病毒作用已得到充分证实,有的已用于临床作为抗病毒药物使用.本文综述了多糖及其衍生物的抗病毒活性、构效关系、作用机理和临床运用. 相似文献
50.