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101.
In this study, recalcitrant total phenol (TPh) and organic matter removal were investigated at olive mill wastewater (OMW) in sequential Coagulation and Fenton system. This study focused on different operational parameters such as pH, H2O2, and Fe2+ dosages, and [Fe2+]/[H2O2] ratios. The optimum conditions were determined as; pH = 3; [Fe2+] = 2.5 g/L; [Fe2+]/[H2O2] = 2.5. A higher treatment efficiency was achieved at sequential Coagulation and Fenton system (COD, 65.5%) and TPh, 87.2%), compared to coagulation process (COD, 51.4%; total organic carbon (TOC), 38.6% and total nitrogen (TN) 52.1%). This study demonstrated that the Coagulation and Fenton process has a potential for efficient removal of phenolic pollutants from wastewater. 相似文献
102.
Vahid Moradi Faysal Ahme Martin B.G. Jun Arthur Blackburn Rodney A. Herring 《环境科学学报(英文版)》2019,31(9):183-194
The photocatalytic activity of Fe-doped TiO2 nanoparticles is significantly increased by an acid-treatment process. The photocatalyst nanoparticles were prepared using sol–gel method with 0.5 mol% ratio of Fe:Ti in acidic pH of 3. The nanoparticles were structurally characterized by means of X-ray diffraction(XRD), high-resolution transmission electron microscope(HRTEM), energy-dispersive X-ray spectroscopy(EDX), X-ray photoelectron spectroscopy(XPS) and diffuse reflectance spectroscopy(DRS). It was observed that the photocatalytic activity suffered from an iron oxide contaminating layer deposited on the surface of the nanoparticles. This contamination layer was removed using an HCl acidtreatment process. The photocatalytic activity using 500 mg/L of Fe0.5-TiO2 in a 10 mg/L of phenol solution increased significantly from 33% to 57%(about 73% increase in the performance), within 90 min of reaction time under visible light irradiation. This significant improvement was achieved by removing the iron oxide contamination layer from the surface of the nanoparticles and adjusting p H to mild acidic and basic pHs. 相似文献
103.
酚在鲤鱼体内的积累,分布和释放试验研究 总被引:1,自引:0,他引:1
研究酚在鲤鱼体内积累,分布和释放规律。鲤鱼饲养于0.005mg/L,0.025mg/L和0.05mg/L酚液中,在32d内随时间延长积累量增加,肝,性腺是酚的主要蓄积器官。随酚浓度升高,鲤鱼体的浓缩系数下降。将受酚污染后的鲤鱼重返清水中饲养,42d后肌肉,鳃中酚释放率高,肝脏释放率低。 相似文献
104.
膨润土吸附剂对水中酚吸附性能研究 总被引:16,自引:1,他引:16
讨了用羟基铝、硫酸处理过的膨润土对水中酚的吸附性能.试验结果表明:酚径膨润土吸附剂吸附后,其去除率为73.88%,处理水再经活性炭吸附,酚去除率可达99.8%、降至0.5mg/L以下. 相似文献
105.
污水零排放可以最大限度地减少工业废水对环境的污染,减少水资源的浪费。企业通过环境论证和风险分析,不断完善工业废水的排水控制和污染物治理措施,制定科学实用的应急预案,实现废水零排放,从而使水资源充分得到利用,环境安全更可靠。 相似文献
106.
Microbiological analysis of multi-level borehole samples from a contaminated groundwater system 总被引:1,自引:0,他引:1
Pickup RW Rhodes G Alamillo ML Mallinson HE Thornton SF Lerner DN 《Journal of contaminant hydrology》2001,53(3-4):269-284
A range of bacteriological, geochemical process-related and molecular techniques have been used to assess the microbial biodegradative potential in groundwater contaminated with phenol and other tar acids. The contaminant plume has travelled 500 m from the pollutant source over several decades. Samples were obtained from the plume using a multi-level sampler (MLS) positioned in two boreholes (boreholes 59 and 60) which vertically transected two areas of the plume. Activity of the microbial community, as represented by phenol degradation potential and ability to utilise a range of substrates, was found to be influenced by the plume. Phenol degradation potential appeared to be influenced more by the concentration of the contaminants than the total bacterial cell numbers. However, in the areas of highest phenol concentration, the depression of cell numbers clearly had an effect. The types of bacteria present were assessed by culture and DNA amplification by polymerase chain reaction (PCR). Bacterial groups or processes associated with major geochemical processes, such as methanogenesis, sulphate reduction and denitrification, that have the potential to drive contaminant degradation, were detected at various borehole levels. A comparative molecular analysis of the microbial community between samples obtained from the MLS revealed the microbial community was diverse. The examination of microbial activity complemented those results obtained through chemical analysis, and when combined with hydrological data, showed that MLS samples provided a realistic profile of plume effects and could be related to the potential for natural attenuation of the site. 相似文献
107.
108.
本文就XH-1型大孔吸附树脂对含酚废水处理性能进行了研究,探索了吸附平衡时间,确立了吸附体系Freundlich等温式,找到了树脂在不同再生剂中最佳工艺条件,发现了吸附、脱附过程分别具有二级和一级反应动力学特征,并得到其表现活化能. 相似文献
109.
110.
This work is dedicated to an accurate evaluation of thermodynamic and kinetics aspects of phenol degradation using wet air oxidation process. Phenol is a well known polluting molecule and therefore it is important having data of its behaviour during this process. A view cell is used for the experimental study, with an internal volume of 150 mL, able to reach pressures up to 30 MPa and temperatures up to 350 °C. Concerning the thermodynamic phase equilibria, experimental and modelling results are obtained for different binary systems (water/nitrogen, water/air) and ternary system (water/nitrogen/phenol). The best model is the Predictive Soave Redlich Kwong one. This information is necessary to predict the composition of the gas phase during the process. It is also important for an implementation in a process simulation. The second part is dedicated to kinetics evaluation of the degradation of phenol. Different compounds have been detected using GC coupled with a MS. A kinetic scheme is deduced, taking into account the evolution of phenol, hydroquinones, catechol, resorcinol and acetic acid. The kinetic parameters are calculated for this scheme. These data are important to evaluate the evolution of the concentration of the different polluting molecules during the process. A simplified kinetic scheme, which can be easily implemented in a process simulation, is also determined for the direct degradation of phenol into H2O and CO2. The Arrhenius law data obtained for the phenol disappearance are the following: k = 1.8 × 106 ± 3.9 × 105 M−1 s−1 (pre-exponential factor) and Ea = 77 ± 8 kJ mol−1 (activation energy). 相似文献