全文获取类型
收费全文 | 616篇 |
免费 | 26篇 |
国内免费 | 221篇 |
专业分类
安全科学 | 13篇 |
废物处理 | 9篇 |
环保管理 | 73篇 |
综合类 | 373篇 |
基础理论 | 178篇 |
污染及防治 | 166篇 |
评价与监测 | 24篇 |
社会与环境 | 24篇 |
灾害及防治 | 3篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 10篇 |
2021年 | 5篇 |
2020年 | 11篇 |
2019年 | 17篇 |
2018年 | 21篇 |
2017年 | 24篇 |
2016年 | 23篇 |
2015年 | 20篇 |
2014年 | 24篇 |
2013年 | 81篇 |
2012年 | 45篇 |
2011年 | 84篇 |
2010年 | 53篇 |
2009年 | 66篇 |
2008年 | 68篇 |
2007年 | 47篇 |
2006年 | 43篇 |
2005年 | 25篇 |
2004年 | 29篇 |
2003年 | 24篇 |
2002年 | 11篇 |
2001年 | 14篇 |
2000年 | 21篇 |
1999年 | 16篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 18篇 |
1995年 | 2篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1975年 | 1篇 |
排序方式: 共有863条查询结果,搜索用时 343 毫秒
181.
城市污水的渠内处理技术研究 总被引:4,自引:0,他引:4
利用研制的60L/h污水的渠式动态模拟装置,研究城市污水的渠内处理技术。结果表明,此法比传统的城市污水处理方法能提高CODcr的脱除率约4%~5%,而工程建设费和运行管理费分别降低30%~40%和25%~30%。渠内处理适宜与自然净化结合进行,出水经植物净化12~15h后,BOD5进一步降低18%以上。由此可见,城市污水渠内处理技术具有良好的应用前景。 相似文献
182.
183.
184.
185.
Bueno M Fillat MF Strasser RJ Maldonado-Rodriguez R Marina N Smienk H Gómez-Moreno C Barja F 《Environmental science and pollution research international》2004,11(2):98-106
INTENTION, GOAL, SCOPE, BACKGROUND: Cyanobacteria have the natural ability to degrade moderate amounts of organic pollutants. However, when pollutant concentration exceeds the level of tolerance, bleaching of the cells and death occur within 24 hours. Under stress conditions, cyanobacterial response includes the short-term adaptation of the photosynthetic apparatus to light quality, named state transitions. Moreover, prolonged stresses produce changes in the functional organization of phycobilisomes and in the core-complexes of both photosystems, which can result in large changes in the PS II fluorescence yield. The localization of ferredoxin-NADP+ reductase (FNR) at the ends of some peripheral rods of the cyanobacterial phycobilisomes, makes this protein a useful marker to check phycobilisome integrity. OBJECTIVE: The goal of this work is to improve the knowledge of the mechanism of action of a very potent pesticide, lindane (gamma-hexaclorociclohexane), in the cyanobacterium Anabaena sp., which can be considered a potential candidate for bioremediation of pesticides. We have studied the effect of lindane on the photosynthetic apparatus of Anabaena using fluorescence induction studies. As ferredoxin-NADP+ reductase plays a key role in the response to oxidative stress in several systems, changes in synthesis, degradation and activity of FNR were analyzed. Immunolocalization of this enzyme was used as a marker of phycobilisome integrity. The knowledge of the changes caused by lindane in the photosynthetic apparatus is essential for rational further design of genetically-modified cyanobacteria with improved biorremediation abilities. METHODS: Polyphasic chlorophyll a fluorescence rise measurements (OJIP) have been used to evaluate the vitality and stress adaptation of the nitrogen-fixing cyanobacterium Anabaena PCC 7119 in the presence of increasing concentrations of lindane. Effects of the pesticide on the ultrastructure have been investigated by electron microscopy, and FNR has been used as a marker of phycobilisome integrity. RESULTS AND DISCUSSION: Cultures of Anabaena sp. treated with moderate amounts of lindane showed a decrease in growth rate followed by a recovery after 72 hours of pesticide treatment. Concentrations of lindane below 5 ppm increased the photosynthetic performance and activity of the cells. Higher amounts of pesticide caused a decrease in these activities which seems to be due to a non-competitive inhibition of PS II. Active PS II units are converted into non-QA reducing, so called heat sink centers. Specific activity and amount of FNR in lindane-treated cells were similar to the values measured in control cultures. Release of FNR from the thylakoid after 48 hours of exposure to 5 ppm of lindane towards the cytoplasm was detected by immunogold labeling and electron microscopy. CONCLUSIONS: From these results, we conclude that the photosynthetic performance and activity of the cells are slightly increased in the presence of lindane up to 5 ppm. Moreover, in those conditions, lindane did not produce significant changes in the synthesis, degradation or activity of FNR. The high capability of Anabaena to tolerate lindane makes this cyanobacterium a good candidate for phytoremediation of polluted areas. RECOMMENDATION AND OUTLOOK: The results of this study show that cultures of Anabaena PCC 7119 tolerate lindane up to 5 ppm, without significant changes in the photosynthetic vitality index of the cells. However, a slight increase in phycobiliprotein synthesis is observed, which is related to total protein content. This change might be due to degradation of proteins less stable than phycobiliproteins. An identification of the proteins with altered expression pattern in the presence of the pesticide remains the subject of further work and will provide valuable information for the preparation of strains which are highly tolerant to lindane. 相似文献
186.
The fate of organic chemicals in the soil-plant-atmosphere environment and the governing processes were studied with a coupled dynamic soil transport and plant compartment model. Scenarios with applications of pesticides on sand and loam soils with chemical uptake in barley and wheat were used in the model calculations. Root uptake and concentrations in the plant compartments stem, leave and fruit were calculated for the pesticides terbuthylazine, isoproturon and carbofuran.
The effectivity of uptake from soils with different soil sorption coefficients had been shown for sand and loam soils. The processes degradation in plant and volatilization from leaves to atmosphere are especially effective for carbofuran and terbuthylazine. Although the concentrations in corn at harvest are lower than the maximum allowed concentrations, the peak concentrations in the course of the vegetation period are significantly higher (factor ≤ 200). 相似文献
187.
天然沸石具有较大的孔隙率和比表面积,对氨氮有较强的选择性离子交换能力.运用天然沸石曝气生物滤池处理城市污水厂二级生化出水,结果表明,曝气生物滤池有良好的去除效果.在气水比为3∶1,水力负荷为1 m/h,温度>20℃情况下,沸石曝气生物滤池对城市污水厂二级生化出水COD去除率为12.7%,NH3-N去除率为96.6%;试验系统沿程微生物活性和微生物量呈现逐渐下降趋势,而单位生物量的生物活性沿程分布则与此相反;曝气生物滤池对水中污染物的去除主要集中在底部进水端部分,当水流达到距进水端上方105 cm时,曝气生物滤池对水中NH3-N的去除率已达86.8%(占氨氮总去除率的90%),COD的去除率为13.3%(占COD总去除率的67%). 相似文献
188.
玉米自交系氮效率基因型差异的比较研究 总被引:20,自引:0,他引:20
采用溶液培养的方法。选用经田间,土壤试验对N反应有典型差异的玉米自交系478,H21,Wu312,Zong31,Baici,在4个供氮水平下(0.04,0.4,2和4nmol/L),研究了不同基因型玉米苗期氮素吸收,利用的差异及其原因,结果表明:极低N胁迫条件下(0.04mmol/L),总干重的基因型差异是由根系,地上部的共同作用的结果,高N下,总干重是由地上部的差异所决定的(表1),极低供N条件下,4578的总干重最大,且有较高的氮效率,Wu312,Zong31相对较低,478相对较高的氮效率主要来源于吸收效率的差异。该基因型在低N下总吸氮量最高,H21居中,Baici,Zong31相对较低,478相对较高的氮效率主要来源于吸收效率的差异。该基因型在低N下总吸氮量最高,H21居中,Baici,Zong31,Wu312相对较低(图1),吸收效率的差异主要是由于根系全N量的不同所致(图3),而根系全N量的差异主要是由于根系大小不同(表1),在极低氮水平下,不同基因型玉米根系全氮量的变幅比地上部高出28.1%,高N下(4mmol/L),全N量的变幅比地上部高出15.4%(图2,图3),在0.04mmol/L下,478与Wu312,Zong31的利用效率不存在显著差异(表2)。 相似文献
189.
Acid hydrolysis of estuarine water samples for the determination of amino acids (AAs) was tested and found to be effective
at high (250 μM) nitrate concentrations when the anti-oxidant, ascorbic acid, was added to the samples. Hydrolysable AA concentrations
were then determined in surface sediments collected from low and high salinity regions of the Tamar Estuary (UK) during winter
2003 and 2004, and in overlying water when simulated resuspension of sediment particles was performed. Concentrations of AAs
in sediment samples comprised <50% of particulate nitrogen, fitting the paradigm that most sedimentary nitrogen is preserved
within an organic matrix. When sediment samples were resuspended in overlying water (salinity 17.5), the rapid, measured increase
in dissolved AA concentrations almost equalled the reported nitrate concentration in the lower estuary, with the subsequent
decrease in the total dissolved AA levels suggested that bacterial uptake was occurring. Our data concur with previous studies
on nitrogen desorption from sediments and suggest that an understanding of organic nitrogen cycling will be an important aspect
of future effective estuarine management. 相似文献
190.
柠檬酸对土壤养分的活化及对作物吸收Fe、P的影响 总被引:5,自引:0,他引:5
土壤pH值是影响石灰性土壤Fe、Zn、Mn等微量元素有效性的重要因素,利用土壤培养法,研究了不同浓度柠檬酸溶液对石灰性土壤的pH值以及对P、Fe、Mn、Zn等元素的活化效应。结果表明,浓度高于0.001mol/L的柠檬酸溶液培养土壤,可降低土壤pH值,增加土壤有效P、Fe、Mn、Zn等元素的质量分数。培养24h后,P、Fe、Mn、Zn等有效养分质量分数最高,随着培养时间的延长,有效养分的质量分数下降,活化效果减弱,土壤表现出一定的钝化效应。利用盆栽模拟滴灌施肥条件,柠檬酸溶液处理可显著促进花生、菜豆植株的生长,叶片SPAD读数增加,并提高植株对P、Fe元素的吸收量,因此滴灌施肥条件下,可考虑使用柠檬酸增加石灰性土壤根区微量元素的有效性。 相似文献