Sorption and desorption of lindane by wood charcoal in fixed‐bed reactor

Abstract

Sorption and desorption of lindane (y‐HCH) by wood charcoal (WC) and wood charcoal treated by 1N HNO₃ (WCT) in fixed‐bed reactor (FBR) were investigated in this study. WCT revealed a better performance than WC, in removing lindane in FBR. The breakthrough of lindane was significantly affected by the size of WCT, flow rate to the FBR, and depth of WCT bed. The removal of lindane in the presence of mixture of other pesticides was considerably reduced. The design parameters for FBR were calculated based on the bed‐depth service time (BDST) approach. Many parameters Viz. depth of sorption zone, velocity of sorption, sorbent use rate, critical bed‐depth, bed efficiency, and service time, were determined for design of the fixed‐bed. Using the material balance principle, the characteristics of the wave‐front were evaluated and found that the wave‐front velocity is approximately equal to the sorption velocity determined from the BDST approach. Desorption studies were performed in dilute organic solvent media and they gave an excellent performance in regeneration process.     

最小数据方法在舟曲县生态补偿中的应用

弄清补偿标准和新增生态系统服务供给量之间的关系是生态补偿研究中的关键问题.舟曲县现有的补偿是静态补偿,补偿标准低,没有很好地达到改善生态环境的目的.本文基于最小数据方法,以耕地和林地提供的水土保持量的差异表征生态系统服务,通过提供单位水土保持服务的机会成本的空间分布,推导出舟曲县森林水土保持的供给曲线,从而将补偿标准和新增水土保持服务的供给联系起来.同时对比了3种补偿标准下的退耕比例、生态补偿总资金需求和新增水土保持量.研究表明生态补偿在理论上可以提供舟曲县的水土保持能力.随着补偿标准的提高,新增水土保持量也在增加.当补偿标准为250元/亩时,退耕比例仅为8.26%,生态补偿总资金需求为1 930.03万元,新增水土保持量为4.69×104t;当补偿标准提高到518.63 元/亩时,退耕比例增加到49.54%,总资金需求为23 184.26万元,新增水土保持量为2.83×105t;当补偿标准增加到995.65 元/亩时,退耕比例可达到98.79%,总资金需求为87 340.95万元,可新增水土保持量达到5.65×105t.     

Data driven modelling of vertical atmospheric radiation

In the Czech Hydrometeorological Institute (CHMI) there exists a unique set of meteorological measurements consisting of the values of vertical atmospheric levels of beta and gamma radiation. In this paper a stochastic data-driven model based on nonlinear regression and on nonhomogeneous Poisson process is suggested. In the first part of the paper, growth curves were used to establish an appropriate nonlinear regression model. For comparison we considered a nonhomogeneous Poisson process with its intensity based on growth curves. In the second part both approaches were applied to the real data and compared. Computational aspects are briefly discussed as well. The primary goal of this paper is to present an improved understanding of the distribution of environmental radiation as obtained from the measurements of the vertical radioactivity profiles by the radioactivity sonde system.     

Effects of land-use pattern change on rainfall-runoff and runoff-sediment relations: a case study in Zichang watershed of the Loess Plateau of China

The purpose of this article is to identify the effect of land-use pattern on rainfall-runoff and runoff-sediment relations in Zichang Watershed of the Loess Plateau. From 1986 to 1997, many farmlands changed into grassland or woodland, especially the farmland in steep slope positions or far away from the river. The change of land-use pattern altered the rainfall-runoff and runoff-sediment relationships, and led to higher slope of trend curves(STCs) of annual rainfall-runoff mass curve and runoff-sediment mass curve in 1990s than that in 1980s. It is implied that more soil and water loss yielded in 1990s. In order to reduce soil loss, more attentions should be paid to land-use pattern and some grass or other herbaceous filter strips should be built along rivers.     

PM2.5中典型水溶性离子在线观测标准曲线优化研究

为了研究在线离子色谱法测定大气PM2.5中NH4^+、NO3^-、SO4^2-的不确定性来源,探讨了标准曲线的浓度范围及浓度梯度设置对离子浓度结果的影响,并对标准曲线设定方案进行了优化。结果表明:不同浓度范围的标准曲线对于NH4+的浓度结果有较大的影响,存在1. 87%~14. 91%的偏差,对于NO3^-、SO4^2-的影响较小,相对偏差分别为2. 94%和2. 82%;非均匀布点和均匀布点标准曲线定量NH4+的结果存在4. 15%~4. 25%的偏差,对于NO3^-和SO4^2-,相对偏差分别为0. 10%和5. 99%。对于二次拟合的NH4^+,在样品浓度波动较大时,可以将样品划分为低浓度范围和高浓度范围,分别选用低浓度段标准曲线和高浓度段标准曲线,以期得到更合理的浓度结果。     

利用13X沸石分子筛净化含NH+4-N废水的实验研究

研究了13X沸石分子筛在静态和动态条件下对中低浓度含NH⁺₄-N废水的吸附性能,包括影响吸附的主要因素、沸石对NH⁺₄-N的吸附效果和沸石的再生等。静态实验结果表明,pH值为6.5～7.5,吸附时间35 min,吸附温度20～30℃的条件下,沸石对50 mL NH⁺₄-N初始浓度（C0）为80 mg/L的废水吸附效果最佳,吸附过程符合Langmuir型吸附等温式,饱和吸附量为8.61 mg/g。动态条件下,随水力停留时间增加,沸石对NH⁺₄-N的吸附量上升,最大饱和吸附量可达24.20 mg/g,吸附过程符合Thomas吸附模型。直接焙烧法对吸附后的沸石进行再生活化处理效果良好。实验证明,利用13X沸石净化中低浓度含NH⁺₄-N废水具有良好的工业化应用前景。     

考虑降雨入渗的非饱和边坡稳定分析

分析了降雨入渗的边坡稳定问题,通过正交实验确定饱和-非饱和渗流计算参数。采用SEEP/W计算饱和-非饱和渗流,利用SLOPE/W模块计算树坪滑坡在降雨入渗情况下的安全系数。     

有机/无机缓蚀剂在模拟混凝土孔隙液中对钢筋缓蚀作用对比研究

目的 检测和评价五种有机/无机缓蚀剂在含3.5％NaCl的模拟混凝土孔隙液(SCP)中对Q235碳钢的缓蚀效果.方法 采用动电位极化曲线和电化学交流阻抗谱(EIS)测试方法 .结果 综合评价后可知,0.0015 mol/L的D-葡萄糖酸钠具有最好的缓蚀效果,浸泡30 d后的Rct可达到282.74×104?·cm2,此...     

基于时空分布特征的煤层瓦斯测压准确性研究

为获得真实可靠的现场实测煤层瓦斯压力,实现煤层突出灾害等级科学评价和精准防治,通过理论分析、数值模拟和现场验证相结合的方法,以双重孔隙介质为基础,根据煤层瓦斯流动模型和瓦斯压力恢复曲线,分析煤层瓦斯压力测定的时空分布及准确性,并以桃园煤矿Ⅱ1采区10煤层为例,开展工程验证.研究结果表明:当基质瓦斯压力与裂隙瓦斯压力处于...     

Is there a Kuznets curve for cropland use? The evidence from international panel data

The environmental Kuznets curve (EKC) hypothesis assumes the nonlinear relationship between production and its environmental effects, suggesting that the negative effect of production on the natural environment is reversed at higher levels of development. In contrast to the majority of the studies, this paper considers the possibility of non-linear effects of per capita output on agricultural land use (cropland), as one of the natural resource stocks, and additionally examines the influence of demographic and productivity variables on the agricultural land use. The study draws on panel data from 143 economies over the 1990–2019 period and employs a series of panel econometrics techniques (including panel unit root and cointegration tests, panel ordinary least squares, generalized method of moments, and panel quantile models). The results unequivocally indicate the inverted U-shaped relationship between the GDP per capita and cropland use, as per EKC hypothesis. The results are robust with respect to employing different techniques, the identified turning points correspond to low and low-middle-income levels, and the effects of agricultural productivity and population density on land use are respectively negative and positive.