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31.
The polymerization reaction can lower the threshold of the required energy by the initiator to improve the efficiency of the overall process reaction. Emerging polymerization initiators are also a major focus of process improvement and technological progress. Azo compounds (azos), which used in dyeing applications, are subsequently used in polymerization reactions due to their highly exothermic reaction characteristics. Although higher heat release can promote polymerization and modify the product, heat generation may also cause process hazards.These thermal hazard parameters were studied by selecting dimethyl 2,2′-azobis(2,4-dimethylvaleronitrile) (ABVN), 2,2′-azobis(2-methyl propionate) (AIBME), 2,2′-azobis(2-methylpropionamide) dihydrochloride (AIBA), and 2,2′-azobis(isobutyronitrile) (AIBN), which are common azo initiators at present. Thermal hazards are closely related to the reaction kinetics of the substance itself. The form of the reaction, the apparent activation energy and the thermodynamic parameters of the exothermic mode were also obtained.Kinetic analysis of the actual process using the experimental data of the isothermal calorimetry model is rarely used in the evaluation of related thermal hazard characteristics. The simulation results revealed the kinetic azo models and were further applied to calculate the runaway situations of azo under specific boundary conditions. 相似文献
32.
镁渣配料煅烧硅酸盐水泥熟料的研究 总被引:8,自引:0,他引:8
研究了镁渣矿物组成和镁渣配料煅烧硅酸盐水泥熟料的反应动力在数和物理性能。结果表明:镁渣的主要矿物组成为γ-C2S、β-C2S、MgO、CF、C2F、FeO、CaF2等,并且镁渣可降低熟料形成反应表观活化能,加速熟料矿物的形成,提高熟料的强度。 相似文献
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35.
Wenjuan Liao Hao-Jie Cui Yaqi Ning Cong Wu Wei Peng Dong Cheng Lichu Yin Weijun Zhou 《环境科学学报(英文版)》2023,35(2):688-698
It has been documented that organic contaminants can be degraded by hydroxyl radicals ( • OH) produced by the activation of H2 O2 by Fe(II)-bearing clay. However, the interfacial electron transfer reactions between structural Fe(II) and H 2 O 2 for • OH generation and its effects on contaminant remediation are unclear. In this study, we first investigated the relation between • OH generation sites and sulfamethoxazole (SMX) degradation by activating H2O2 using nontronite with different reduction extents. SMX (5.2–16.9 μmol/L) degradation first increased and then decreased with an increase in the reduction extent of nontronite from 22% to 62%, while the • OH production increased continually. Passivization treatment of edge sites and structural variation results revealed that interfacial electron transfer reactions between Fe(II) and H 2 O 2 occur at both the edge and basal plane. The enhancement on basal plane interfacial electron transfer reactions in a high reduction extent rNAu-2 leads to the enhancement on utilization efficiencies of structural Fe(II) and H 2 O 2 for • OH generation.However, the • OH produced at the basal planes is less efficient in oxidizing SMX than that of at edge sites. Oxidation of SMX could be sustainable in the H 2 O 2 /rNAu-2 system through chemically reduction. The results of this study show the importance role of • OH generation sites on antibiotic degradation and provide guidance and potential strategies for antibiotic degradation by Fe(II)-bearing clay minerals in H 2 O 2 -based treatments. 相似文献
36.
The incessant demand and consumption of energy services among individuals’ is increasing throughout the world. Individuals’ electricity consumption in Northern Cyprus has risen considerably. However, the demand for electrical energy services on the island is heavily reliant on imported fossil fuels. Burning fossil fuels has adverse effects on its environment. Therefore, sustainable energy consumption is required and individuals are targeted for energy conservation to reduce electricity consumption. Against this background, using the Structural Equation Modeling approach, this research incorporates social‐psychological factors; personal norms, positive and negative emotions into the theory of planned behaviour (TPB) model to assess the relationships among the variables, explain their impact on consumers’ electricity conservation intentions and enhance the explanatory power of the model. Data was conveniently obtained from a quantitative sample of 400 electricity consumers. The results indicate that negative emotions have the strongest significant influence on intentions, but personal norms have the least effect on intentions to save electricity. Furthermore, the study revealed that our expanded TPB model can provide improved explanatory power more than the original TPB. Policy implications, limitations and future research are discussed. 相似文献
37.
The paper represents some results of comparative analysis of the methods used for processing and interpreting data of adiabatic calorimetry as well as applying it to practical situations. Specifically two approaches are compared – approximate method based on evaluation of simplified kinetics and a more comprehensive, simulation-based method that utilizes the evaluation of more detailed kinetic models.The analysis is focused on two important types of data processing – correction of experimental results on thermal inertia (phi-factor correction) and estimation of adiabatic time to maximum rate (TMR).The most widely cited method for phi-factor correction is considered and its improvement is proposed to enable more precise prediction of the adiabatic time scale. A procedure for phi-factor correction of pressure response is also proposed. The limitations of this enhanced Fisher's method are discussed by comparison with simulation-based method. All the illustrative materials are based on real examples.As an example of application, the simplified method will be used to predict TMR and its limitations will be discussed. 相似文献
38.
叙述了执行《中国学术期刊(光盘版)检索与评价数据规范》的重要性,并对在执行过程中发现的《规范》的某些条目,如作者简介和参考文献等的规定不够确切以及模拟样本不够准确严密等一些问题提出了看法和相应的建议。 相似文献
39.
水环境承载力约束下区域城镇化发展合理速度分析 总被引:1,自引:0,他引:1
城镇化发展在促进区域社会经济快速发展的同时也导致水环境问题日益严峻。基于区域水环境承载力探讨了城镇化发展合理速度的计量方法:①构建城镇化进程中水环境承载力评价系统,分析城镇化子系统及水环境承载力子系统的基本要素,建立评价指标体系;基于评价指标,利用向量模法测算水环境承载力综合评价值。②构建水环境承载力约束下的区域城镇化发展合理速度分析模型。③根据不同城镇化发展速度、政府不同管制力度设置9种组合情境,在对相关评价指标进行预测的基础上,分别测算不同情境下的水环境承载力综合评价值;通过“阈值”门槛筛选出合理情境,确定区域城镇化发展速度的合理范围。以经济实力强、城镇化水平高、水环境压力大、制度相对健全的江苏省作为研究区域进行实证分析,测算了2006—2017年江苏省水环境承载力综合评价值,以及2030年9种组合情境下的江苏省水环境承载力综合评价值。获得如下研究结论:①2006—2017年间江苏省水环境承载力虽呈现一定的波动,但2013年以后随着政府管制力度的加强,总体上呈现良好的上升态势,但水环境承载力下滑的压力已开始显现。②2030年9种组合情境中,只有“中/强”“低/强”“低/保持”满足水环境承载力阈值标准。结果表明:到2030年,政府对水环境管制力度“强”的情形下,江苏省城镇化发展可以维持1.0%~1.2%的年增长率;政府对水环境管制力度“保持”的情形下,江苏省城镇化发展只能维持1.0%的年增长率,并据此提出了政策建议。 相似文献
40.
Nicoletta Cavazza Author Vitae 《Journal of Safety Research》2009,40(4):277-283