全文获取类型
收费全文 | 202篇 |
免费 | 1篇 |
国内免费 | 29篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 3篇 |
环保管理 | 19篇 |
综合类 | 144篇 |
基础理论 | 19篇 |
污染及防治 | 38篇 |
评价与监测 | 6篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 4篇 |
2021年 | 9篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2018年 | 5篇 |
2017年 | 9篇 |
2016年 | 5篇 |
2015年 | 8篇 |
2014年 | 8篇 |
2013年 | 10篇 |
2012年 | 13篇 |
2011年 | 17篇 |
2010年 | 9篇 |
2009年 | 13篇 |
2008年 | 9篇 |
2007年 | 14篇 |
2006年 | 15篇 |
2005年 | 7篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 7篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 8篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有232条查询结果,搜索用时 15 毫秒
201.
202.
《环境科学学报(英文版)》2023,35(4):494-505
Single particle-inductively coupled plasma mass spectrometry (SP-ICP-MS) is a powerful tool for size-characterization of metal-containing nanoparticles (MCNs) at environmentally relevant concentrations, however, coexisting dissolved metal ions greatly interfere with the accuracy of particle size analysis. The purpose of this study is to develop an online technique that couples hollow fiber ultrafiltration (HFUF) with SP-ICP-MS to improve the accuracy and size detection limit of MCNs by removing metal ions from suspensions of MCNs. Through systematic optimization of conditions including the type and concentration of surfactant and complexing agent, carrier pH, and ion cleaning time, HFUF completely removes metal ions but retains the MCNs in suspension. The optimal conditions include using a mixture of 0.05 vol.% FL-70 and 0.5 mmol/L Na2S2O3 (pH = 8.0) as the carrier and 4 min as the ion cleaning time. At these conditions, HFUF-SP-ICP-MS accurately determines the sizes of MCNs, and the results agree with the size distribution determined by transmission electron microscopy, even when metal ions also are present in the sample. In addition, reducing the ionic background through HFUF also lowers the particle size detection limit with SP-ICP-MS (e.g., from 28.3 to 14.2 nm for gold nanoparticles). This size-based ion-removal principle provided by HFUF is suitable for both cations (e.g., Ag+) and anions (e.g., AuCl4−) and thus has good versatility compared to ion exchange purification and promising prospects for the removal of salts and macromolecules before single particle analysis. 相似文献
203.
204.
Yu Bon Man Ka Lai Chow Zhang Cheng Wing Yin Mo Yung Hau Chan James Chung Wah Lam Frankie Tat Kwong Lau Wing Cheong Fung Ming Hung Wong 《环境科学学报(英文版)》2017,29(3):196-206
Sewage discharge could be a major source of polycyclic aromatic hydrocarbons(PAHs) in the coastal waters. Stonecutters Island and Shatin Sewage Treatment Works(SCISTW and STSTW)in Hong Kong, adopted chemically enhanced primary treatment and biological treatment,respectively. This study aimed at(1) determining the removal efficiencies of PAHs,(2) comparing the capabilities in removing PAHs, and(3) characterizing the profile of each individual PAHs, in the two sewage treatment plants(STPs). Quantification of 16 PAHs was conducted by a Gas Chromatography. The concentrations of total PAHs decreased gradually along the treatment processes(from 301 ± 255 and 307 ± 217 ng/L to 14.9 ± 12.1 and 63.3 ± 54.1 ng/L in STSTW and SCISTW, respectively). It was noted that STSTW was more capable in removing total PAHs than SCISTW with average total removal efficiency 94.4% ± 4.12% vs. 79.2% ± 7.48%(p 0.05). The removal of PAHs was probably due to sorption in particular matter, confirmed by the higher distribution coefficient of individual and total PAHs in solid samples(dewatered sludge contained92.5% and 74.7% of total PAHs in SCISTW and STSTW, respectively) than liquid samples(final effluent-total contained 7.53% and 25.3% of total PAHs in STSTW and SCISTW, respectively).Despite the impressive capability of STSTW and SCISTW in removing PAHs, there was still a considerable amount of total PAHs(1.85 and 39.3 kg/year, respectively for the two STPs) being discharged into Hong Kong coastal waters, which would be an environmental concern. 相似文献
205.
针对溶解氧(DO)、气水比对水解酸化池与好氧MBR组合工艺处理污水效果的影响和能耗问题.从气水比对DO的影响,DO对COD与色度去除效果的影响等方面来讨论气水比,溶解氧以及污水处理效果之间的最佳运行点。试验结果表明。在P(MLSS)分别为5.81、4.25、2.19g/L的运行条件下,MBR的最佳气水比为39:1、28.1.18:1;DO变化速率随污泥浓度的下降而升高;DO的变化对COD、色度的去除效果影响并不显著。 相似文献
206.
207.
Shan Chen Jiayuan Li Wenbo Feng Mingzhe Yuan Wei Zhang Houtao Xu Xiaoyan Zheng Liqing Wang 《环境科学学报(英文版)》2020,32(11):141-148
Sulfonamides(SAs) are common antimicrobial drugs, which are frequently detected in surface water systems, and are difficult to degrade, posing a potential threat to the aquatic environment. However, little is known about the potential adverse effects of SAs on nontarget organisms(e.g., microalgae) in the aquatic ecosystem. In this study, the effect of SAs(sulfadiazine(SD), sulfamerazine(SM1), and sulfamethazine(SM2) at 1, 5, 20, and 50 mg/L concentrations, respectively) on the freshwater microal... 相似文献
208.
209.
城市景观水体中腐殖酸的臭氧氧化去除 总被引:1,自引:0,他引:1
以南京师范大学德风园池底泥中提取的腐殖酸(HA)为研究对象,采用臭氧氧化技术对其进行去除,对初始pH值、混合气体流量、腐殖酸(HA)初始浓度以及水中常见离子等因素对去除效果的影响进行了研究。实验结果表明:腐殖酸(HA)的去除率随初始pH值的升高而提高,随混合气体流量减少而提高;当腐殖酸(HA)初始浓度为5 mg/L时,反应过程中溶液的UV254升高,紫外扫描结果发现,溶液在200~220 nm内出现杂乱的吸收峰,表明有新物质生成;水中常见的无机阴离子(CO32-、HCO3-)和二价金属离子(Ca2+、Cu2+)的存在会降低臭氧对腐殖酸(HA)的去除率。 相似文献
210.
生物除铁、锰的需氧量试验研究 总被引:2,自引:0,他引:2
研究锰砂滤层去除铁、锰过程中溶解氧因素对去除效果的影响,为生物法除铁、锰的实际运行提供了参考依据。在其他运行条件相同的情况下,只改变其中DO一项,进行去除率试验对比。DO在一定范围内的变化对生物除铁除锰效率的提高无显著影响。从经济性和微生物角度考虑原水DO维持在3mg/L左右既可满足运行要求。 相似文献