全文获取类型
收费全文 | 721篇 |
免费 | 81篇 |
国内免费 | 332篇 |
专业分类
安全科学 | 46篇 |
废物处理 | 28篇 |
环保管理 | 52篇 |
综合类 | 654篇 |
基础理论 | 141篇 |
污染及防治 | 173篇 |
评价与监测 | 28篇 |
社会与环境 | 8篇 |
灾害及防治 | 4篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 20篇 |
2021年 | 34篇 |
2020年 | 27篇 |
2019年 | 26篇 |
2018年 | 35篇 |
2017年 | 43篇 |
2016年 | 50篇 |
2015年 | 55篇 |
2014年 | 46篇 |
2013年 | 98篇 |
2012年 | 79篇 |
2011年 | 83篇 |
2010年 | 51篇 |
2009年 | 68篇 |
2008年 | 48篇 |
2007年 | 53篇 |
2006年 | 48篇 |
2005年 | 33篇 |
2004年 | 23篇 |
2003年 | 23篇 |
2002年 | 21篇 |
2001年 | 16篇 |
2000年 | 47篇 |
1999年 | 5篇 |
1998年 | 12篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 9篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1990年 | 3篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有1134条查询结果,搜索用时 187 毫秒
181.
Kazuto Sazawa Yoshiki Furuhashi Noriko Hata Shigeru Taguchi Masami Fukushima 《毒物与环境化学》2013,95(3):472-482
A micro-scale algal growth inhibition (μ-AGI) test using a common micro-plate based fluorometric detection was used to demonstrate the effects of humic substances (HSs) on the toxicity of tetrabromobisphenol A (TBBPA) and its oxidative decomposition products 2,5-dibromo-1,4-benzoquinone (2,5-DBBQ), 2,5-dibromohydroquinone (2,5-DBHQ), 2,6-dibromobenzoquinone (2,6-DBBQ), and 2,6-dibromophenol (2,6-DBP) to Pseudokirchneriella subcapitata. The EC50 values were: EC50(TBBPA) = 7 mg L?1, EC50(2,5-DBHQ) = 7 mg L?1, EC50(2,5-DBBQ) = 19 mg L?1, EC50(2,6-DBP) = 49 mg L?1, and EC50(2,6-DBBQ) = 13 mg L?1. The toxicity of the chemicals was slightly lower in the presence of HA. The toxicity of TBBPA decomposed by a biomimetic catalytic system consisting of iron (III) 5,10,15,20-tetrakis (p-sulfonatophenyl) porphyrin (Fe(III)-TPPS) and KHSO5 was also evaluated using P. subcapitata and Chlamydomonas reinhardtii. 相似文献
182.
Shunitz Tanaka Masayuki Kawai Yosuke Nakata Motoki Terashima Hideki Kuramitz Masami Fukushima 《毒物与环境化学》2013,95(4-6):95-102
The photo-Fenton reactions, which could yield hydroxyl radicals via the catalytic degradation of H2O2 by Fe(II), were focused as one of the abiotic degradation processes of bisphenol A (BPA) in surface waters. At pH 6, in the presence of H2O2 only, 32% of BPA was degraded after 120?min of irradiation. However, 97% of BPA was degraded in the presence of both H2O2 and Fe(II). Without light irradiation, no BPA degradation was observed even in the presence of Fe(II) and H2O2. These results show that photo-Fenton processes are effective in the natural attenuation of BPA in surface water. In addition, the presence of humic acids (HAs), which were of more aliphatic nature, resulted in enhancing BPA degradation via the photo-Fenton processes. Therefore, HAs can be one of the important factors in enhancing the degradation of BPA in surface water via the photo-Fenton processes. 相似文献
183.
Liqin JI Xue BAI Lincheng ZHOU Hanchang SHI Wei CHEN Zulin HUA 《Frontiers of Environmental Science & Engineering》2013,7(3):442-450
A simple solvothermal method was used to prepare monodisperse magnetite (Fe3O4) nanoparticles attached onto graphene oxide (GO) sheets as adsorbents to remove tetrabromobisphenol A (TBBPA) from an aqueous solution. These Fe3O4/GO (MGO) nanocomposites were characterized by transmission electron microscopy. The adsorption capacity at different initial pH, contact duration, and temperature were evaluated. The kinetics of adsorption was found to fit the pseudo-second-order model perfectly. The adsorption isotherm well fitted the Langmuir model, and the theoretical maximum of adsorption capacity calculated by the Langmuir model was 27.26 mg?g-1. The adsorption thermodynamics of TBBPA on the MGO nanocomposites was determined at 303 K, 313 K, and 323 K, respectively. The results indicated that the adsorption was spontaneous and endothermic. The MGO nanocomposites were conveniently separated from the media by an external magnetic field within several seconds, and then regenerated in 0.2 M NaOH solution. Thus, the MGO nanocomposites are a promising candidate for TBBPA removal from wastewater. 相似文献
184.
Xue BAI Hanchang SHI Zhengfang YE Qiujin SUN Qing WANG Zhongyou WANG 《Frontiers of Environmental Science & Engineering》2013,7(6):844-850
In this study, microorganisms (named B111) were immobilized on polyvinyl alcohol microspheres prepared by the inverse suspension crosslinked method. The biodegradation of bisphenol A (BPA) and 4-hydro- xybenzaldehyde, a degradation product of BPA, by free and immobilized B lll was investigated. The BPA degradation studies were carried out at initial BPA concentrations ranging from 25 to 150 mg·L^-1. The affinity constant Ks and maximum degradation rate Rmax were 98.3 mg·L^-1 and 19.7mg·mg^-1VSS·d^-1 for free B111, as well as 87.2mg·L^-1 and 21.1mg·mg^-1VSS·d^-1 for immobilized B 111, respectively. 16S rDNA gene sequence analyses confirmed that the dominant genera were Pseudomonas and Brevundimonas for BPA biodegradation in microorganisms B 111. 相似文献
185.
186.
A/O法处理水产品加工废水 总被引:2,自引:2,他引:0
采用A/O工艺处理水产品加工废水,处理量为500 t/d,运行两年来,效果稳定,处理结果表明:对COD、BOD5和氨氮的去除率分别为94.7%、98.1%和86.4%,出水达到GB 8978—1996《污水综合排放标准》中的一级排放标准,且该工艺具有运行费用低、处理效果好、操作管理方便等一系列优点。 相似文献
187.
土壤和沉积物中有机质对双酚A和17α-乙炔基雌二醇的吸附行为 总被引:1,自引:0,他引:1
研究了土壤和沉积物原始样品bulk及其有机质组分(非水解性有机质NHC、碳黑BC和腐殖酸HA)对17α-乙炔基雌二醇(EE2)和双酚A(BPA)的吸附行为.所有的吸附等温线都很好地拟合了Freundlich模型,除HA和bulk外,所有的吸附等温线都为显著的非线性(n值为0.46—0.76).对于EE2和BPA的吸附非线性因子n值都存在这样的关系:HA>NHC>BC.EE2以有机碳归一化的Freundlich吸附能力(lgKOC)有BC>NHC>bulk>HA的关系,说明有机质成熟度越高,对EE2或者BPA的吸附能力越高.在土壤和沉积物有机质SOM(NHC、BC和HA)对吸附BPA和EE2的贡献上,NHC、BC和HA对沉积物和土壤对BPA总吸附贡献上要明显弱于它们对EE2的贡献.除了内分泌干扰物(EDCs)的疏水性影响EE2和BPA的吸附能力的差异外,分子大小和带电子苯环数也影响它们的吸附能力差异. 相似文献
188.
河源城南污水处理厂尾水深度处理效果的研究 总被引:2,自引:1,他引:1
河源市城南污水处理厂利用垂直流人工湿地对该厂A2-O工艺处理的尾水进行深度处理,研究了人工湿地对尾水中TN、NH4+-N、TP、COD、BOD5的去除效果。结果表明:人工湿地对污水处理厂尾水具有较好的深度处理效果,垂直流人工湿地处理系统对尾水中TN、NH4+-N、TP、COD和BOD5平均去除率分别达到97.4%、97.8%、95.06%、91.87%和95.87%以上,其出水水质基本达GB 18918—2002《城镇污水处理厂污染物排放标准》一级A标准,地表水Ⅲ类标准。 相似文献
189.
以聚合氯化铝(PAC)和氯化铁(FeCl3)为混凝剂,分析了双酚A(BPA)在1g/L高岭土溶液混凝过程中的特征.并借助循环错流过滤强化污染层累积的方法,评价产生滤饼层的微滤(MF)膜对BPA的截留效果.结果表明:清洁的微滤膜过滤BPA溶液在短时间内达到截留吸附饱和,之后其对BPA的吸附截留作用显著降低;混凝絮体混合液经膜过滤时产生的污染层有利于BPA的去除,且单独混凝对BPA去除率最高的混凝剂投加量下进行膜过滤时的阻力较小.PAC混凝—膜过滤后BPA去除率比单独混凝提高了34.30%;FeCl3混凝—膜过滤后BPA去除率比单独混凝提高了28.38%.初始BPA浓度对混凝-膜过滤去除率有一定影响,BPA浓度为100μg/L时,比BPA浓度为5mg/L时采用2种混凝-微滤膜过滤方式去除率均有提高. 相似文献
190.
Oxidative and genotoxic effects of bisphenol A on primary gill cell culture of Lake Van Fish (Alburnus tarichi Güldenstädt, 1814) 总被引:1,自引:0,他引:1
Lake Van is the largest lake in Turkey. The lake limits lifespan due to its high pH and brackish water. For this reason, only a single species of fish (Van Fish) is living in the lake that has been adapted to these conditions. In the present study, we investigated the total oxidant status (TOS), total antioxidant status (TAS), malondialdehyde (MDA) level and DNA damage effect of bisphenol A (BPA) (10?7, 10?6 and 10?5?M) on primary gill cell culture of Van Fish for 24 and 48?h of incubation periods. TAS levels were not changed when compared to those of the control group, but TOS levels were decreased in both 24 and 48?h. The MDA level increased only at the highest concentration (10?5) at the end of 12 and 24?h (p?.05). DNA damage increased only at the 10?5?M concentration after 48?h. At the end of the experiment, BPA exposure caused lipid peroxidation and genotoxic effect. These results indicate that high levels of BPA exposure induced oxidative stress and DNA damage by time- and concentration-dependent fashion in the gill cell culture of Van Fish. Gill cell culture is a useful model for the rapid identification of the harmful effects of chemicals in the aquatic environment. 相似文献