Removal of NAPLs from the unsaturated zone using steam: prevention of downward migration by injecting mixtures of steam and air

Steam injection for remediation of porous media contaminated by nonaqueous phase liquids has been shown to be a potentially efficient technology. There is, however, concern that the technique may lead to downward migration of separate phase contaminant. In this work, a modification of the steam injection technology is presented, where a mixture of steam and air was injected. In two-dimensional experiments with unsaturated porous medium contaminated with nonaqueous phase liquids, it was demonstrated how injection of pure steam lead to severe downward migration. Similar experiments, where steam and air were injected simultaneously, resulted in practically no downward migration and still rapid cleanup was achieved. The processes responsible for the prevention of downward migration when injecting steam-air mixtures were analyzed using a nonisothermal multiphase flow and transport model. Hereby, three mechanisms were identified and it was demonstrated how the effectiveness of these mechanisms depended on the air-to-steam mixing ratio.     

SIMULATING THE EFFECTS OF REDUCED PRECIPITATION ON GROUND WATER AND STREAMFLOW IN THE NEBRASKA SAND HILLS1

ABSTRACT: The Nebraska Sand Hills have a unique hydrologic system with very little runoff and thick aquifers that constantly supply water to rivers, lakes, and wetlands. A ground water flow model was developed to determine the interactions between ground water and streamflow and to simulate the changes in ground water systems by reduced precipitation. The numerical modeling method includes a water balance model for the vadose zone and MOD‐FLOW for the saturated zone. The modeling results indicated that, between 1979 and 1990, 13 percent of the annual precipitation recharged to the aquifer and annual ground water loss by evapotranspiration (ET) was only about one‐fourth of this recharge. Ground water discharge to rivers accounts for about 96 percent of the streamflow in the Dismal and Middle Loup rivers. When precipitation decreased by half the average amount of the 1979 to 1990 period, the average decline of water table over the study area was 0.89 m, and the streamflow was about 87 percent of the present rate. This decline of the water table results in significant reductions in ET directly from ground water and so a significant portion of the streamflow is maintained by capture of the salvaged ET.     

Response of Three Plant Communities to Trampling in a Sand Dune System in Brittany (France)

Dunes that are protected because of their very rich and diverse plant communities are often exposed to excessive visitor pressure. The effects of trampling on the habitat must be known from a conservation viewpoint but also are important for management. To determine the response of plant assemblages to trampling by people, an experimental study was conducted on the state-owned dunes at Quiberon (Brittany, France). Indices of resistance and resilience were used to compare three typical plant communities belonging to the various landscape units: mobile dune, semifixed dune, and fixed dune. The strong contrasts between communities belonging to different successional stages reflect their ecological functioning. The mobile dune and semifixed dune with their low resistance contrasted with the fixed dune. Only the vegetation cover of the semifixed dune benefited from long-term trampling and had a very high resilience (134%). This response could be explained by a good balance of two opposite factors: soil compaction increasing soil stability and moisture content, and vegetation destruction. Because of their low resilience, trampling seems to be harmful for fixed dunes in the long term. The tourist pressure seems easier to integrate in to the mobile dunes and the semifixed dunes if periods of recovery are included in the management.     

Effects of sand movement by wind on nematodes and soil-borne fungi in coastal foredunes

In stabilized dunesAmmophila arenaria (marram grass) degenerates due to a process involving soil-borne pathogens and parasites. This leads to exposure of the sand surface so that wind erosion may create blowouts.Ammophila rejuvenates on the edges of the blowouts, where the sand has accumulated. We tested the hypothesis that such rejuvenation of plants may be related to a reduction of the plant-parasitic nematodes and fungal propagules during the process of wind-driven transport. Field measurements in blowouts during storm events indicated that the drifted sand contained relatively low numbers of plant pathogenic fungi and plant-parasitic nematodes. A wind tunnel experiment showed that drifting sand may indeed reduce the numbers of fungi and nematodes. Although most fungi were attached to sand particles, they were also affected by the wind-borne sand movement. Sand that had been deposited by wind was made up of a larger proportion of large-sized particles. In our experiment the relatively small particles were lost during transport. Stirring the soil (part of the forces of natural winds) by mixing for 15 min. with a propeller mixer at 1500 rpm significantly reduced the number of nematodes and fungi. Both sand movement in the wind tunnel and intensive stirring of the sand enhanced the growth ofAmmophila test plants in a bioassay. It was concluded that in wind-blown sand the pathogen inoculum is reduced. Therefore, serious consideration should be given to allowing controlled reactivation of blowouts to rejuvenate decliningAmmophila in stabilized foredunes. Implications for dune management are briefly discussed. Nomenclature: van der Meijden (1990) for vascular plants. Nematodes were identified to the genus level according to Bongers (1988). The allocation of nematodes to feeding groups was according to Yeates et al. (1993). Nomenclature of fungi according to Domsch et al. (1980) was used throughout this study except forFusarium. Species of the latter genus were identified according to Nelson et al. (1983).     

场地液化危害的概率分析

为使场地液化危害程度的估计建立在以概率论为基础的可靠性分析之上,本文提出二种估计场地液化危害程度的概率方法,二种方法分别采用不同的途径处理地震和岩土的不确定性,不仅分析了一点液化的概率,而且提供了估计整个土层住状液化概率的方法,文中最后通过算例简要讨论了液化概率分析结果的工程应用。     

TCE recovery mechanisms using micellar and alcohol solutions: phase diagrams and sand column experiments

Forty-one phase diagrams and fifteen sand column experiments were conducted to evaluate the efficiency of three types of washing solutions to recover trichloroethylene (TCE) at residual saturation and to identify the recovery mechanisms involved. This study demonstrates that: (1) an alcohol and a surfactant combination is more efficient than an alcohol used alone in water; (2) the prediction of the dominant recovery mechanism from the tie line slopes in phase diagram is accurate and can be reproduced in sand column experiments; and (3) TCE recovery efficiency in sand column experiments is generally well represented by the position of the miscibility curve in phase diagrams in the low concentration range. However, the miscibility curve alone is not sufficient to exactly predict the TCE recovery mechanisms involved. Tie line slopes and the critical tie line have to be taken into consideration to select the active matter as well as its concentration and to predict the dominant recovery mechanism in sand column experiments. The sand column experiments quantified the recovery efficiency of each solution and identified the proportion of the recovery mechanisms (mobilisation vs. solubilisation). Washing solutions with an active matter concentration above the critical tie line caused dominating mobilisation. Mobilisation was also dominant when the active matter of the washing solution partitioned into the organic phase and the active matter concentration was below the critical tie line. Solubilisation and emulsification were dominant for washing solutions containing active matter, which principally partitioned into the aqueous phase and an active matter concentration below the critical tie line.     

Hydrogeomorphic Reference Condition and Its Relationship with Macroinvertebrate Assemblages in Southeastern U.S. Sand Hills Streams

Defining stream reference conditions is integral to providing benchmarks to ecological perturbation. We quantified channel geometry, hydrologic and environmental variables, and macroinvertebrates in 62 low‐gradient, SE United States (U.S.) Sand Hills (Level IV ecoregion) sand‐bed streams. To identify hydrogeomorphic reference condition (HGM), we clustered channel geometry deviation from expectations given watershed area (Aws), resulting in two HGM groups discriminated by area at the top of bank (Atob) residuals <0.6 m² and >0.6 m² predicted to be HGM reference/nonreference streams, respectively. Two independent partial least squares discriminate analyses used (1) hydrologic/environmental variables and (2) macroinvertebrate mean trait values (mT) on 10 reference/nonreference stream pairs of similar Aws for classification validation. Nonreference streams had flashier hydrographs and altered flow magnitudes, lower organic matter, coarser substrate, higher pH/specific conductivity compared with reference streams. Macroinvertebrate assemblages corresponded to HGM groupings, with mT indicative of multivoltinism, collector‐gatherer functional feeding groups, fast current‐preference taxa, and lower Ephemeroptera, Plecoptera, and Trichoptera richness and biotic integrity in nonreference streams. HGM classifications in Sand Hills, sand‐bed streams were determined from channel geometry. This easily implemented classification is indicative of contemporary hydrologic disturbance resulting in contrasting macroinvertebrate assemblages.     

GEOLOGICAL AND CLIMATIC CONTROLS ON STREAMFLOWS IN THE NEBRASKA SAND HILLS1

ABSTRACT: This paper presents hydrological characteristics of the streamflow of the Dismal, Middle Loup, North Loup, and Cedar Rivers in the Nebraska Sand Hills and their relation to climate and ground water variation. Time series of streamflow, precipitation, temperature, and ground water levels from 1976 to 1998 were used to analyze trends and fluctuations of streamflow and to determine relationships among streamflow, climate, and the ground water system. An increase of precipitation and a decrease of maximum temperature over the period resulted in higher ground water levels and increased streamflow in the region. The high permeability of the soil and the thick unsaturated zone enhance precipitation recharge, limit surface runoff, and prevent ground water losses through evapotranspiration. Thus, an abundance of ground water is stored, supplying more than 86 percent of streamflow in the four rivers. Streamflow is generally more constant in the Sand Hills than elsewhere in the region. The four rivers present different hydrologic characteristics because of the spatial heterogeneity in hydrogeologic conditions. Streamflow of the Dismal and Middle Rivers, which are less sensitive to climatic variation, is much steadier than that of the North Loup and Cedar Rivers.     

Estimation of fecal Coliform removal from domestic sewage in two sand filter column systems

The objective of the present research is to compare fecal coliform removal from two different sand column systems treating septic tank effluent over a range of hydraulic loading rates. Drain time measurements were performed to compare the hydraulic characteristic of the column systems at different hydraulic loading rates. Biochemical oxygen demand (BOD), total suspended solids (TSS), and pH were also measured for the septic tank effluent. A removal of the order of 99% for fecal coliform, TSS, and BOD in column effluent was achieved using the sand filter columns. The ‘break‐in’ period for determining the effectiveness of the sand filter columns is also discussed.     

采油废水资源化技术工艺研究

采用三种不同的工艺 (隔油 -破乳絮凝 -砂滤、隔油 -水解酸化 -SBR和隔油 -破乳絮凝 -SBR)对某油田采油废水进行了对比性试验研究。试验结果表明 :某油田采油废水经隔油 -破乳絮凝 -SBR处理后 ,COD、BOD去除率分别达到了 95 %和 90 %以上 ,出水指标达到了国家含油废水排放标准和回注水标准 ;经过隔油 -破乳絮凝 -砂滤处理后 ,COD和油去除率分别达到 85 %和 95 %以上 ,COD没有达到排放标准 ,油达到了排放标准 ;经隔油 -水解酸化 -SBR工艺处理后 ,COD、BOD去除率分别达到 85 %左右和 90 %以上 ,BOD达到了排放水标准 ,但 COD没有达到排放标准 ,仍需后续处理