基于OPMSE的畜禽养殖行业排放限值仿真

通过对清河流域畜禽养殖行业产生污水的各指标(BOD5,COD,NH_3-N)浓度进行统计,得出了排放污水中各污染物指标的浓度值范围。通过OPMSE的仿真计算,得出了排放污水经过BAT处理后,污染物浓度正态分布均值在90%,95%,99%置信水平下的置信区间。在置信水平为99%时,畜禽养殖行业的COD置信区间为(42.00,48.19),BOD_5置信区间为(7.47,8.74),NH_3-N置信区间为(6.78,7.88)。同时,依据仿真计算结果还得出了处理后污染物浓度的极小值和极大值,畜禽养殖行业的最佳出水COD,BOD_5,NH3_-N指标质量浓度分别为22.0,2.1,3.09 mg/L,最差出水COD,BOD_5,NH_3-N指标质量浓度分别为84.4,14.2,13.29 mg/L。将仿真结果与现有排放标准对比,拟定畜禽养殖行业的COD,BOD_5,NH_3-N直接排放限值分别为50,9,8 mg/L。     

Field Application of a Renewable Constructed Wetland Substrate for Phosphorus Removal1

Rosenquist, Shawn E., W. Cully Hession, Matthew J. Eick, and David H. Vaughan, 2011. Field Application of a Renewable Constructed Wetland Substrate for Phosphorus Removal. Journal of the American Water Resources Association (JAWRA) 47(4):800‐812. DOI: 10.1111/j.1752‐1688.2011.00557.x Abstract: Phosphorus (P) is typically the best target to prevent eutrophication in freshwater, a biological process associated with water quality degradation. Constructed wetlands (CW) and other practices that include P removal by sorption processes in substrates can provide economical treatment of stormwater, but have limitations (e.g., large land requirements, loss of removal over time, lack of P recovery). Over the last three years, a multi‐study research program addressed these limitations with a new P management concept. This concept minimizes CW size with a rejuvenation cycle (or rejuvenation) that renews P‐sorption capacity in the CW substrates and enables P recovery for productive use. This study, conducted in Blacksburg, Virginia (July‐September 2009), tested the efficacy of rejuvenation in the field. Methods included replicate cells of two sand substrates monitored for P removal during prerejuvenation and postrejuvenation filtration runs. One substrate contained cast iron filings as a repository for sorption capacity. Results support the following conclusions: (1) P removal is likely dependent on multiple factors including influent P concentration, previous substrate/solution equilibrium, pH, and time; (2) rejuvenation is capable of releasing P adsorbed during stormwater filtration; (3) inclusion of cast iron in substrate promotes additional P removal and enables further removal after rejuvenation; but (4) inclusion of cast iron may limit release of P during rejuvenation.     

Development and Application of the 2010 Chesapeake Bay Watershed Total Maximum Daily Load Model

The Phase 5.3 Watershed Model simulates the Chesapeake watershed land use, river flows, and the associated transport and fate of nutrient and sediment loads to the Chesapeake Bay. The Phase 5.3 Model is the most recent of a series of increasingly refined versions of a model that have been operational for more than two decades. The Phase 5.3 Model, in conjunction with models of the Chesapeake airshed and estuary, provides estimates of management actions needed to protect water quality, achieve Chesapeake water quality standards, and restore living resources. The Phase 5.3 Watershed Model tracks nutrient and sediment load estimates of the entire 166,000 km² watershed, including loads from all six watershed states. The creation of software systems, input datasets, and calibration methods were important aspects of the model development process. A community model approach was taken with model development and application, and the model was developed by a broad coalition of model practitioners including environmental engineers, scientists, and environmental managers. Among the users of the Phase 5.3 Model are the Chesapeake watershed states and local governments, consultants, river basin commissions, and universities. Development and application of the model are described, as well as key scenarios ranging from high nutrient and sediment load conditions if no management actions were taken in the watershed, to low load estimates of an all‐forested condition.     

Optimization of "Serpa" cheese whey nanofiltration for effluent minimization and by-products recovery

Second cheese whey (SCW) is a by-product of cheese and curd cheese production that is usually not recovered and therefore substantially contributes to the negative environmental impact of the cheese manufacture plants. Membrane technology, namely nanofiltration (NF), is used in this work for the recovery of SCW organic nutrients, resulting from "Serpa" cheese and curd production. The SCW is processed by NF to recover a rich lactose fraction in the concentrate and a process water with a high salt content in the permeate. The permeation experiments were carried out in a plate & frame NF unit, where two NF membranes (NFT50 and HR-95-PP) were characterized and tested. The NF permeation experiments were performed accordingly with two different operation modes: total recirculation and concentration. In order to select the best membrane and operating pressure for the SCW fractionation, total recirculation experiments were carried out. The NF modeling was also performed, in terms of permeate fluxes and rejection coefficients using the resistances-in-series model and the solution-diffusion model, respectively. After the membrane selection, the concentration experiments showed that the selected membrane (NFT50) at 3.0MPa allows a water recovery of approximately 80%, concentrating the SCW nutrients approximately 5 times. Therefore, the NF operation can successfully reduce the wastewater organic load and simultaneously contributes to the valorization of the cheese and curd cheese manufacture by-products.     

Sociopolitical Conditions for Successful Water Quality Trading in the South Nation River Watershed,Ontario, Canada1

O’Grady, Dennis, 2011. Sociopolitical Conditions for Successful Water Quality Trading in the South Nation River Watershed, Ontario, Canada. Journal of the American Water Resources Association (JAWRA) 47(1):39‐51. DOI: 10.1111/j.1752‐1688.2010.00511.x Abstract: The South Nation River watershed has a regulated water quality trading program. Legally, wastewater dischargers must not discharge any increased loading of phosphorus (P) into receiving waters. New wastewater systems are now choosing trading instead of traditional P removal technology, and point source dischargers are buying P credits from rural landowners, primarily farmers. These credits are generated by constructing nonpoint source pollution control measures. Mathematical formulae are used to calculate the credits of P removed by each measure. A successful trading program requires several conditions, including community agreement, legislative backing, credit and cost certainty, simplified delivery and verification, written instruments, and legal liability protection. South Nation Conservation, a community‐based watershed organization, is the broker handling the transactions for these P credits. The program is run by a multi‐stakeholder committee, and all project field visits are done by farmers and not paid professionals. An independent evaluation showed higher opinions for the broker and regulatory agency, and most farmers were willing to, or had already, recommended the program to other farmers.     

Is there a double-dividend from anti-sprawl policies?

This paper examines the welfare effects of anti-sprawl policies, such as development tax, in a simple spatial explicit urban model with two market failures - urban decline at the city core and underprovision of open space amenities at the urban fringe - and pre-existing distortionary property tax, used to fund public services and improvements to mitigate urban decline. Consistent with prior double-dividend literature, there is a tax interaction effect that occurs between the development tax and the pre-existing property tax. However, there are two fundamental differences between the tax interaction effect identified here and that of prior literature. Ours one has two components: First, there is a cost-side tax interaction effect that is ‘spatially’ concentrated at the urban fringe, as only agents at the urban fringe alter their behavior in response to the development tax. Second, there is also a benefit-side tax interaction effect, as increases in open space at the urban fringe are capitalized into housing prices throughout the city. In contrast to prior literature, we find that the empirical importance of the combined tax interaction effect is of substantially less importance and, as a consequence, the likelihood of a ‘double-dividend’ is higher than in prior studies. Further, we show that the development tax should be part of the local tax system, even in the absence of open space benefits.     

Forestry best management practices for timber harvesting and site preparation in the eastern United States: An overview of water quality and productivity research during the past 20 years (1982–2002)

Forestry Best Management Practices (BMPs) were developed to protect water quality. In the eastern US, those BMPs were often expanded to include maintenance of site productivity. Generally, BMPs recommend the use of pre-harvest planning and careful design for construction of roads and other activities that expose bare soil, minimizing trafficking and areas of bare soil, maintaining streamside management zones, ensuring rapid revegetation following harvesting, minimizing soil disturbance, and ameliorating severe trafficking with site preparation. This review of peer-reviewed research from the past 20 years examined the effects of forest harvesting and site preparation on water quality and site productivity in the eastern US. The review was subdivided into areas having relatively similar physiography and land management (New England, Lake States, Appalachian Plateau, Ridge and Valley, Blue Ridge, Piedmont, Atlantic Coastal Plain, Gulf Coastal Plain, and Ouachitas-Ozarks). In general, data from steeper physiographic regions indicated that forest harvesting and site preparation can increase erosion, sediment and nutrient losses to streams. However, the quantities introduced into streams tended to be relatively low, generally below the values that are considered acceptable for alternative land uses. Also most research indicated that water quality recovers within two to five years following forest operation disturbances, particularly if BMPs are employed. Research from the less mountainous and often more poorly drained Lake States and Coastal Plain regions indicated that soil compaction and rutting may or may not cause site productivity effects, depending on soil types, natural ameliorative properties and site preparation. Overall, the research supports the forestry BMPs recommended in the eastern states.     

Improved performance in a prenatal screening programme for Down's syndrome incorporating serum-free hCG subunit analyses

A prenatal screening programme for Down's syndrome potentially detecting 76 per cent of affected pregnancies in the South Australian general population at an amniocentesis rate of 3.9 per cent was designed following analysis of mid-trimester serum samples from 57 women who carried an affected fetus. This equates to one affected pregnancy being detected for 41 chromosomal analyses performed. For the experimental series, 75.4 per cent of affected pregnancies were detected, while 4.1 per cent of control specimens produced estimated risk odds consistent with further action. A maternal risk odds of birth of a Down's syndrome fetus of 1:420 was taken as the decision value, which is the prevalence of Down's syndrome births to 35-year-old mothers in South Australia. This screening performance was achieved by investigating combinations of serum analytes not previously reported and by refining the calculation of maternal risk odds to include selective weighting of indicator analytes. Combination of the measurements of free α-subunits and β-subunits of chorionic gonadotrophin, α-fetoprotein, unconjugated oestriol, and placental lactogen was found to be most effective in indicating Down's syndrome fetuses. In all combinations of analytes tested, replacing the measurements of free α-subunits and free β-subunits of chorionic gonadotrophin with the measurement of intact chorionic gonadotropin produced a less effective screen.     

控制流域氮流失的最佳管理措施配置及效率评估

以潮河流域为研究对象,分别进行流域整体单一措施配置和氮流失分区综合措施配置,既采用负荷去除法从污染负荷削减率的角度对BMPs配置效率进行评价,也采用R-R-V （Reliability-Resilience-Vulnerability）指数法从可靠性、可修复性和脆弱性等角度对流域水质改善效果进行评价.结果表明,分区进行氮流失综合措施配置效果更为理想,研究年内流域出口总氮削减率为14.35%~31.65%,年平均削减率为24.98%,在地表水Ⅱ类评估标准下,年平均总氮R-R-V指数为0.37、0.24、95.78,而多项单一措施的年平均削减率为17.48%,月尺度平均总氮R-R-V指数为0.36、0.24、112.96.R-R-V指数法从可靠性、可修复性和脆弱性等角度反映消减效率,无论单一措施配置或分区综合措施配置,可靠性指数与脆弱性指数的改善效率较高（大于14%）,而可修复性指数的改善效率较低.多数情况下可靠性指数与脆弱性指数的改善效率高于总氮削减率,可修复性指数的改善效率低于总氮削减率,表明流域总氮负荷虽然得到一定程度的削减且短期低于标准负荷,但其生态修复难度依旧较大.营养物标准负荷所对应浓度的设定是评估流域R-R-V指数改善效果的关键,且评估标准越严格,待评估营养物的R-R-V指数越趋于稳定.     

Constructed Wetland Treatment of Nitrates: Removal Effectiveness and Cost Efficiency

A constructed wetland (CW) was strategically placed to treat nitrates in groundwater as part of a watershed‐based farmer engagement process. Using stream water quality data collected before and after installation, this CW was found to reduce stream concentrations of nitrogen from nitrate (NO₃‐N) during the growing season by about 0.14 mg/l at mean streamflow, a 17% reduction. Based upon realistic ecological and economic assumptions, about 80 kg of NO₃‐N were removed annually by the CW at a cost of around US$30/kg. This per unit cost is at the low range of small wastewater treatment plant costs for nitrates, but higher than the costs of reduced fertilizer application.