石化行业炼油恶臭污染源治理技术评估

运用环保技术评估体系,提出石油炼制过程中典型恶臭污染源治理技术评价指标体系,并对已应用的治理技术进行全面评估,从而筛选出炼油污水处理场废气、酸性水罐罐顶气、冷焦水罐/油品中间罐/污油罐罐顶气、氧化脱硫醇尾气和油品装卸挥发气的最佳可行技术.     

Land Use and Climate Variability Amplify Carbon,Nutrient, and Contaminant Pulses: A Review with Management Implications

Nonpoint source pollution from agriculture and urbanization is increasing globally at the same time climate extremes have increased in frequency and intensity. We review >200 studies of hydrologic and gaseous fluxes and show how the interaction between land use and climate variability alters magnitude and frequency of carbon, nutrient, and greenhouse gas pulses in watersheds. Agricultural and urban watersheds respond similarly to climate variability due to headwater alteration and loss of ecosystem services to buffer runoff and temperature changes. Organic carbon concentrations/exports increase and organic carbon quality changes with runoff. Nitrogen and phosphorus exports increase during floods (sometimes by an order of magnitude) and decrease during droughts. Relationships between annual runoff and nitrogen and phosphorus exports differ across land use. CH₄ and N₂O pulses in riparian zones/floodplains predominantly increase with: flooding, warming, low oxygen, nutrient enrichment, and organic carbon. CH₄, N₂O, and CO₂ pulses in streams/rivers increase due to similar factors but effects of floods are less known compared to base flow/droughts. Emerging questions include: (1) What factors influence lag times of contaminant pulses in response to extreme events? (2) What drives resistance/resilience to hydrologic and gaseous pulses? We conclude with eight recommendations for managing watershed pulses in response to interactive effects of land use and climate change.     

Thermal Pollution Mitigation in Cold Water Stream Watersheds Using Bioretention

This study examines the use of bioretention as a strategy to reduce the thermal impact associated with urban stormwater runoff in developing cold water stream watersheds. Temperature and flow data were collected during 10 controlled runs at a bioretention facility located in Blacksburg, Virginia. It was determined that bioretention has the ability to reduce the temperature of thermally charged stormwater runoff received from an asphalt surface. Significant reductions in peak and average temperatures (p < 0.001) were observed. However, this facility was unable to consistently reduce the temperature below the threshold for natural trout waters in Virginia. The ability of bioretention to reduce runoff volume and peak flow rate also serves to reduce the hydrothermal impact. An average thermal pollution reduction of nearly 37 MJ/m³ was calculated using an adopted threshold temperature of 20°C. Based on the results of this study, it was concluded that properly designed bioretention systems have the capability to reduce the thermal impact of urban stormwater runoff on cold water stream ecosystems.     

Locating Existing Best Management Practices Within a Watershed: The Value of Multiple Methods

There is an increasing need to document the impacts of conservation‐related best management practices (BMPs) on water quality within a watershed. However, this impact analysis depends upon accurate geospatial locations of existing practices, which are difficult to obtain. This study demonstrates and evaluates three different methods for obtaining geospatial information for BMPs. This study was focused on the Eagle Creek Watershed, a mixed use watershed in central Indiana. We obtained geospatial information for BMPs through government records, producer interviews, and remote‐sensing aerial photo interpretation. Aerial photos were also used to validate the government records and producer interviews. This study shows the variation in results obtained from the three sources of information as well as the benefits and drawbacks of each method. Using only one method for obtaining BMP information can be incomplete, and this study demonstrates how multiple methods can be used for the most accurate picture.     

USING STREAM BIOASSESSMENT PROTOCOLS TO MONITOR IMPACTS OF A CONFINED SWINE OPERATION1

ABSTRACT: The processing of waste from confined animal feeding operations (CAFOs) presents a major environmental challenge. Treatment of waste and subsequent land application is a common best management practice (BMP) for these operations in Kentucky, USA, but there are few data assessing the effect of runoff from such operations on aquatic communities. The authors sampled a stream bordering a CAFO with a land application program to determine if runoff from the fertilized fields was adversely affecting stream communities. Water chemistry, periphyton, and macroinvertebrate samples from riffle habitats downstream of the CAFO were compared to samples collected from an upstream site and a control stream in 1999 and 2000. Riffle communities downstream of the fertilized fields had higher chlorophyll a levels than other sites, but there were no significant differences in macroinvertebrate numbers or in biometrics such as taxa richness among the sites. The BMP in place at this site may be effective in reducing this CAFO's impact on the stream; however, similar assessments at other CAFO sites should be done to assess their impacts. Functional measures such as nutrient retention and litter decomposition of streams impacted by CAFOs should also be investigated to ensure that these operations are not adversely affecting stream communities.     

LIVESTOCK GRAZING MANAGEMENT IMPACTS ON STREAM WATER QUALITY: A REVIEW1

ABSTRACT: Controlling agricultural nonpoint source pollution from livestock grazing is a necessary step to improving the water quality of the nation's streams. The goal of enhanced stream water quality will most likely result from the implementation of an integrated system of best management practices (BMPs) linked with stream hydraulic and geomorphic characteristics. However, a grazing BMP system is often developed with the concept that BMPs will function independently from interactions among controls, climatic regions, and the multifaceted functions exhibited by streams. This paper examines the peer reviewed literature pertaining to grazing BMPs commonly implemented in the southern humid region of the United States to ascertain effects of BMPs on stream water quality. Results indicate that the most extensive BMP research efforts occurred in the western and midwestern U.S. While numerous studies documented the negative impacts of grazing on stream health, few actually examined the success of BMPs for mitigating these effects. Even fewer studies provided the necessary information to enable the reader to determine the efficacy of a comprehensive systems approach integrating multiple BMPs with pre‐BMP and post‐BMP geomorphic conditions. Perhaps grazing BMP research should begin incorporating geomorphic information about the streams with the goal of achieving sustainable stream water quality.     

Two‐Stage Agricultural Ditch Sediments Act as Phosphorus Sinks in West Michigan

Phosphorus (P) and sediment inputs from agricultural drainage contribute to the development of hypereutrophic conditions in lakes across the world. Two‐stage (2‐S) ditches, an agricultural best management practice gaining acceptance in the Midwestern United States, increase floodplain area within drainage ditches to help capture nutrients and sediment. While denitrification has been shown to increase on 2‐S benches, less is known about their P retention ability. This study assessed the abiotic and biotic P retention of two separate 2‐S ditches compared to their corresponding traditional reaches directly upstream within the Macatawa watershed, located in West Michigan. Soluble reactive P export was significantly reduced in 2‐S baseflow of both ditch systems. Equilibrium P concentration values suggest retention of P within the 2‐S sediment. P was bound within stable fractions in both 2‐S and traditional reaches. An analysis of P stock within the ditches revealed sediment held over 96% of total P (TP) within each reach compared to <4% in bench vegetation and periphyton combined. Turbidity, but not TP, was reduced in one study ditch, whereas TP, but not turbidity, was reduced in the other study ditch. Geomorphic stability may have been responsible for differing P retention between ditches. Ability to retain P appears to be impacted by physical as well as biogeochemical characteristics; hence, structure and age of 2‐S reaches influence P retention.     

Water-Quality Performance of a Constructed Stormwater Wetland for All Flow Conditions1

Wadzuk, Bridget M., Matthew Rea, Gregg Woodruff, Kelly Flynn, and Robert G. Traver, 2010. Water-Quality Performance of a Constructed Stormwater Wetland for All Flow Conditions. Journal of the American Water Resources Association (JAWRA) 46(2):385-394. DOI: 10.1111/j.1752-1688.2009.00408.x Abstract: Results from a multiyear study demonstrate that a constructed stormwater wetland (CSW) improves urban stormwater runoff quality mitigating downstream impacts. Best management practices, such as CSWs, can comprehensively treat the various scales of stormwater runoff issues. Discrete sample analysis was used to investigate the CSW effect for storm events and base-flow periods on water-quality parameters [i.e., total suspended solids, total dissolved solids, total nitrogen, phosphorous (total and reactive), chloride, heavy metals (zinc, lead, and copper), and Escherichia coli]. The primary finding was that stormwater sediment load was removed through the CSW for all flow conditions during all seasons. The mechanisms responsible for the removal of suspended solids, including slower flow velocity, longer retention times, and vegetative contact, also reduced the mass of nutrients discharged downstream throughout the year. Exceedance probabilities were used to evaluate the expected pollutant reductions of nutrients and to incorporate the effect of natural flow variation on quality. Other findings included the observation that there was no significant difference in the performance of the CSW over two-year-long periods four years apart, indicating that a CSW is effective for an extended period.     

SPRING RUNOFF AND DRAINAGE N AND P LOSSES FROM HOG-MANURED CORN1

ABSTRACT: A two-year study was conducted to assess the effect of hog manure on the losses of nitrogen and phosphorus in runoff and drainage from grain-corn (Zea mays L.) plots, and the importance of spring versus annual loads. Treatments consisted of mineral N-P-K fertilizer applied at rates of 152 kg N ha^-1, 35 kg P ha^-1, and 86 kg K ha^-1; and hog (Sus scrofa domestica L.) manure applied preplant or post-emergence (six-to-eight leaf stage), at 152 kg N ha^-1, 39 kg P ha^-1, and 112 kg K ha^-1. The plots were rototilled (7 cm depth) in spring to incorporate fertilizer and preplant hog manure, and fall chisel-plowed (15 cm depth) to incorporate chopped corn residues. They were arranged in a completely randomized plot design. Flow volumes and nutrient levels in runoff and drainage waters were monitored year round but occurred mainly during the snowmelt (March 25-April 9), and post.snowmelt (April 10-May 13) periods. Of the total amount of water lost during snowmelt, 90 percent was in runoff, while 92 percent occurred as drainage in the post-snowmelt period. Sixty-five percent of the total annual volume of water lost was lost during these two periods as runoff and drainage. Treatments did not affect the annual snowmelt or post-snowmelt N and P loads. Total annual loads averaged 8.0 kg TKN ha^-1, 1.8 kg NH₄-N ha^-1, 43 kg NO₃-N ha^-1, 0.4 kg TP ha^-1, and 0.15 kg PO₄-P ha^-1. Spring (snowmelt and ost-snowmelt) runoff and drainage loads averaged 2.9 kg TKN ha^-1, 1.2 kg NH₄-N ha^-1, 18 kg NO₃-N ha^-1, 0.25 kg TP ha^-1, and 0.04 kg PO₄-P ha^-1, which were 40 percent to 70 percent of the yearly nutrient loads. Therefore, the hog manure management systems examined were of no greater threat to the environment than mineral fertilizers. However, spring N and P losses do represent an important part of the annual nutrient loss budget, even with conservation practices.     

BAT and BEP as instruments for reducing emissions of unintentionally produced POPs and development of guidelines under the stockholm convention

The 6th Intergovernmental Negotiating Committee (INC 6), under the Stockholm Convention on POPs, gave an expert group the mandate to develop guidelines for the application and implementation of best available techniques (BAT) and best environmental practices (BEP) for the prevention and reduction of unintentionally produced and emitted POPs, including polychlorinated dibenzodioxins/-furans (PCDD/Fs), polychlorinated biphenyls (PCBs) and hexachlorobenzene (HCB). Measures to reduce or eliminate the release of these POPs to the environment can be found in Article 5 of the Convention. BAT and BEP are already being applied as emission reduction instruments in a number of industrialised countries and are elements of other major international treaties, e.g. the UN ECE Protocol on POPs and the Marine Convention's OSPAR and HELCOM, and of the EU Directive for Integrated Pollution Prevention and Control (IPPC Directive). Existing concepts are presented and compared with the requirements of the Stockholm Convention. Consequences, perspectives and questions for the future intersessional work of the above-mentioned Expert Group are discussed.