全文获取类型
收费全文 | 778篇 |
免费 | 30篇 |
国内免费 | 80篇 |
专业分类
安全科学 | 50篇 |
废物处理 | 22篇 |
环保管理 | 65篇 |
综合类 | 350篇 |
基础理论 | 179篇 |
污染及防治 | 55篇 |
评价与监测 | 160篇 |
社会与环境 | 2篇 |
灾害及防治 | 5篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 5篇 |
2021年 | 11篇 |
2020年 | 9篇 |
2019年 | 7篇 |
2018年 | 3篇 |
2017年 | 8篇 |
2016年 | 10篇 |
2015年 | 15篇 |
2014年 | 35篇 |
2013年 | 52篇 |
2012年 | 32篇 |
2011年 | 49篇 |
2010年 | 40篇 |
2009年 | 47篇 |
2008年 | 40篇 |
2007年 | 59篇 |
2006年 | 47篇 |
2005年 | 39篇 |
2004年 | 44篇 |
2003年 | 39篇 |
2002年 | 39篇 |
2001年 | 23篇 |
2000年 | 39篇 |
1999年 | 29篇 |
1998年 | 25篇 |
1997年 | 32篇 |
1996年 | 35篇 |
1995年 | 15篇 |
1994年 | 16篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1982年 | 2篇 |
排序方式: 共有888条查询结果,搜索用时 15 毫秒
51.
McGoldrick DJ Durham J Leknes H Kierkegaard A Gerhards R Powell DE McLachlan MS 《Chemosphere》2011,85(8):1241-1247
Cyclic volatile methyl siloxanes (cVMS) are high volume production chemicals used in a wide range of industrial and consumer products. Three cVMS compounds (D4, D5, and D6) have and are undergoing environmental risk evaluations in several countries and have been proposed for legal regulation in Canada. As interest in monitoring concentrations of these chemicals in the environment increase, there is a need to evaluate the analytical procedures for cVMS in biological matrices in order to assess the quality of data produced. The purpose of this study was to determine laboratory testing performance for measuring residues of D4, D5, and D6 in a standard set of fish homogenate samples and to estimate limits of determination for each substance. The samples sent to each laboratory consisted of homogenized whole body tissues of hatchery raised rainbow trout which were fed food fortified with D4, D5, and D6 (dosed) and trout that were fed standard food rations (control). The participants analyzed each sample using their analytical method of choice using their own standards and procedures for quantification and quality control. With a few exceptions, participating laboratories generated comparable results for D4, D5, and D6 in both the dosed and control samples having z-scores between 2 and −2. Method detection limits for the whole fish matrix were on average 2.4 ng g−1 ww for D4, 2.3 ng g−1 ww for D5, and 1.8 ng g−1 ww for D6. 相似文献
52.
53.
54.
利用微型滴定法测定白醋中的总酸度,并对常量实验和微型实验的测定结果进行了比较分析。结果两种方法无显著性差异,F检验、t检验均在允许范围内,微型实验的准确度和精密度均达到常量实验的测定水平,完全满足化学分析要求,并且有效地节省了实验试剂,大大降低了实验成本。 相似文献
55.
Abstract The acute toxicity of two organophosphorus (OP) insecticides, azinphosmethyl and acephate, was evaluated in the mummichog, Fundulus heteroclitus. In addition, the effects of certain intrinsic (sex) and extrinsic (salinity and multiple toxicant interraction) variables on the toxic response were also investigated. Azinphosmethyl was by far the most toxic of the two OP insecticides with a 96h LC50 ~ 100,000 x lower than that for acephate. Slight sex differences were observed in the sensitivity of mummichogs to each of the OP insecticides with male fish being marginally more sensitive. Significant effects of low salinity stress were observed only with acephate exposure and, in this case, low salinity appeared to be slightly protective. In general, all of the insecticide mixtures (azinphosmethyl/endosulfan, azinphosmethyl/fenvalerate and acephate/fenvalerate) tested exhibited simple additive toxicity. 相似文献
56.
57.
硼氢化钾吹气—分光光度法测定污水中硫化物 总被引:3,自引:0,他引:3
污水样品用硼氢化钾片剂酸性氢化反应,使硫化物同酸作用转化为H2S,并被氢气吹出,以NaOH溶液吸收,再用对氨基二甲基苯胺光度法测定。为了应急监测,研制了LS-1型硫化物快速测试预装置,配用DR/2000型便携式分光光度计,可在现场进行了水中硫化物的快速监测。. 相似文献
58.
Jay D. Evans 《Behavioral ecology and sociobiology》1998,44(1):35-42
Most social groups have the potential for reproductive conflict among group members. Within insect societies, reproduction
can be divided among multiple fertile individuals, leading to potential conflicts between these individuals over the parentage
of sexual offspring. Colonies of the facultatively polygynous ant Myrmicatahoensis contain from one to several mated queens. In this species, female sexuals were produced almost exclusively by one queen.
The parentage of male sexuals was more complex. In accordance with predictions based on worker sex-allocation preferences,
male-producing colonies tended to have low levels of genetic relatedness (i.e., high queen numbers). Correspondingly, males
were often reared from the eggs of two or more queens in the nest. Further, over half of the males produced appeared to be
the progeny of fertile workers, not of queens. Overall investment ratios were substantially more male biased than those predicted
by genetic relatedness, suggesting hidden costs associated with the production of female sexuals. These costs are likely to
include local resource competition among females, most notably when these individuals are adopted by their maternal nest.
Received: 3 March 1998 / Accepted after revision: 20 June 1998 相似文献
59.
聚苯乙烯基硫代磺酸钾树脂的合成及其与卤代烃的反应 总被引:2,自引:2,他引:0
由聚苯乙烯基磺酰氯树脂与硫化氢钾反应制备聚苯乙烯基硫代磺酸钾树脂(I),树脂I与亲电的卤代烃反应,生成聚苯乙烯基硫代磺酸酯树脂(Ⅱ),树脂Ⅱ经过乙硫醇处理,使卤代烃结构部分以不对称二硫醚的形式游离下来,用GC/MS对其结构进行鉴定。从不对称二硫醚的结构可推导出原卤代烃的结构,所制备的聚苯乙烯基硫代磺酸钾树脂的转化效率为1.11mmol·g^-1。 相似文献
60.
水中一氯胺和二氯胺的紫外连续流动测定 总被引:1,自引:0,他引:1
本文研究了二氯胺与溴化钾的反应及其产物。采用微孔渗透膜分离-紫外分光测定系统,测定水溶液中的一氯胺与二氯胺。本法的线性范围为2×10^-5mol·l^-1-1×^-2mol·l^-1,标准偏差在2×10^-4mol·l^-1时为4.3%。 相似文献