Visible light sensitive activated carbon-metal oxide (TiO2, WO3, NiO,and SnO) nano-catalysts for photo-degradation of methylene blue: a comparative study

Four composites of metal oxide doped with activated carbon with a metal oxide weight of 20% were prepared using mechano-mixing method. The nano-catalysts were characterized by N₂-adsorption–desorption, X-ray diffraction analysis, transmission electron microscopy, Fourier-transform infrared spectroscopy, UV-diffuse reflectance, and photoluminescence spectroscopy. Photo-catalytic degradation of methylene blue dye under UV 254 nm and visible light was examined. In general, prepared catalysts are more active for degradation of dye under visible light than UV, reaching 96% within 180?min irradiation using the SnO catalyst. Photo-degradation of methylene blue followed pseudo first order reaction mechanism with a rate constant of 14.8?×?10^?3?min^?1, and the time required for removal of 50% of dye was 47?min.     

Participatory scenario planning to facilitate human–wildlife coexistence

Fostering human–wildlife coexistence requires transdisciplinary approaches that integrate multiple sectors, account for complexity and uncertainty, and ensure stakeholder participation. One such approach is participatory scenario planning, but to date, this approach has not been used in human–wildlife contexts. We devised a template for how participatory scenario planning can be applied to identify potential avenues for improving human–wildlife coexistence. We drew on 3 conceptual building blocks, namely the SEEDS framework, the notion of critical uncertainties, and the three-horizons technique. To illustrate the application of the proposed template, we conducted a case study in the Zambezi region of Namibia. We held 5 multistakeholder workshops that involved local people as well as numerous nongovernment and government stakeholders. We identified 14 important wildlife species that generated multiple services and disservices. The subsequent benefits and burdens, in turn, were inequitably distributed among stakeholders. Government actors played particularly influential roles in shaping social-ecological outcomes. We identified 2 critical uncertainties for the future: the nature of governance (fragmented vs. collaborative) and the type of wildlife economy (hunting vs. photography based). Considering these uncertainties resulted in 4 plausible scenarios describing future human–wildlife coexistence. Stakeholders did not agree on a single preferred scenario, but nevertheless agreed on several high-priority strategies. Bridging the remaining gaps among actors will require ongoing deliberation among stakeholders. Navigating the complex challenges posed by living with wildlife requires moving beyond disciplinary approaches. To that end, our template could prove useful in many landscapes around the world.     

Does Oil and Goodwill Mix?: Examining the Oil and Gas Industry’s Impact on Stakeholder Engagement on Facebook

The present study explores how oil and gas companies use Facebook to communicate about community-supporting initiatives and engage stakeholders. Drawing from the company–cause fit and social interactivity literature, we examined the type of message and the language used in company Facebook posts to elicit stakeholder engagement, as measured by the number of likes, shares, and comments. We content analyzed 953 Facebook posts from 12 companies featured on Oil & Gas Journal’s top 50-company list. The results showed that, although oil and gas companies are posting about their CSR-related efforts on Facebook, their lack of two-way messaging and interactive language use are not effectively engaging stakeholders. In terms of theory, this study advances company–cause fit and interactive studies by applying them to the oil and gas industry. In terms of practice, the results highlight the importance of using diverse messaging and interactive language when utilizing Facebook to engage stakeholders.     

Honge oil methyl ester and producer gas-fuelled dual-fuel engine operated with varying compression ratios

Alternative and renewable fuels have numerous advantages compared with fossil fuels as they are renewable and biodegradable, besides providing food and energy security and foreign exchange savings and addressing environmental and socio-economic issues. Therefore, these renewable fuels can be used predominantly in compression ignition (CI) engines for transportation purposes and power generation applications. Today, the use of biomass-derived producer gas is more relevant for addressing rural power generation and is also a promising technique for controlling both NO_x and soot emission levels. Although a producer gas–biodiesel-operated dual-fuel diesel engine exhibits lower performance, they are independent from the use of fossil fuels. The lower performance of the engine could be due to the slow-burning and lower calorific value of producer gas. For this purpose, exhaustive experiments on the use of Honge oil methyl ester (HOME)–producer gas in a dual-fuel CI engine were carried out for the improvement of its fuel efficiency. This paper presents the effect of the compression ratio (CR) on the performance, combustion and exhaust emission characteristics of a single-cylinder, four-stroke, direct injection stationary diesel engine operated using HOME and producer gas in a dual-fuel mode. The results indicated that the HOME–producer gas combination exhibited lower brake thermal efficiency (BTE) with comparable emission levels with the diesel–producer gas combination at different CRs. Comparative measures of BTE, peak pressure, pressure–crank angle variation, heat release rate, smoke opacity, and hydrocarbon (HC), carbon monoxide (CO) and nitric oxide (NO_x) emission levels are presented and analysed.     

Energy conservation and waste utilization in the cement industry serve the green technology and environment

The cement industry is one of the most energy-intensive industries consuming 4 GJ/ton of cement, i.e. 12–15% of the energy use in total industry. Energy cost accounts for 30% of the total cost of cement production. Seventy-five per cent of this energy is due to the thermal energy for clinker production. It is also found that 35% of this supplied thermal energy is lost in flue gas streams. Most modern kilns use pet coke or coal as their primary fuel. Instead, the municipal waste in landfills offer a cheap source of energy and reduce the environmental effects of dumping solid waste. The calcination and drying processes and the kiln need large quantities of thermal energy. About 40% of the total energy input is lost in the hot flue gases and cooling the stack plus the kiln shell. Hence, it is suitable to use an organic Rankine cycle (ORC) to recover the exhaust energy from the kiln. Alternatively, a 15 MW gas turbine engine combined with a steam turbine could be utilized. It was found that ORC produces 5 MW with a capital cost recovery period of 1.26 years. However, the gas turbine combined system produces 21.45 MW with a maximum recovery period of 2.66 years.     

Optimizing a two-echelon serial supply chain with different carbon policies

In recent years, organizations are becoming environment conscious due to stringent laws, competitive advantages and increasing awareness of customers. They are integrating environmental practices into their operations to curb carbon emissions. Regulatory bodies are also imposing carbon policies to check emission. In this paper, we developed three models considering three carbon policies (I. carbon tax, II. strict cap and III. cap-and-trade) and have determined the optimal order quantity and number of shipments for a two-echelon supply chain. The objective is to minimize the total supply chain cost which comprises the ordering, setup, production, inventory holding and transportation costs. In Model I tax on carbon emissions has been included in the cost function; in Model II we have considered a strict carbon cap on the total carbon emission; and in Model III trading price of carbon is included in the cost function. A numerical study is given to illustrate the solution procedure. Further, sensitivity analyses are performed to examine the impact of the various parameters on the total cost and total emission.     

1000 kV交流输电线路噪声的计算模式和减缓措施

介绍了几家国内外研究机构建立的用来计算预测输电线路电晕可听噪声的模式,针对皖电东送淮南至上海1000 kV特高压交流示范工程输电线路的实际参数,建立了相应的计算公式,可以较为准确的预测该类型输电线路可听噪声的大小;交流输电线路电晕产生可听噪声的影响因素众多,根据是否可控将这些因素分为两大类,并分析了单个因素对可听噪声预测值的影响程度,针对输电电路导线参数、杆塔型式和附加材料三个方面的内容,提出了几类切实可行的输电线路可听噪声减缓措施,为后续1000 kV交流输电线路的设计和建设提供参考。     

On the amount of counterpart assistance to be provided after natural disasters: from the perspective of indirect economic loss assessment

China’s counterpart assistance policy is of vital importance in providing guidance for emergency management and post-disaster reconstruction. However, the amount of assistance that partner provinces should provide as well as the criteria that partners should abide by in offering counterpart assistance remain a main challenge. The goal of this research is to fill this gap by proposing a new framework consisting of an interregional input–output (IRIO) model and a resilience index. Subsequently, the indirect economic loss is obtained by utilizing the index system of provincial economic resilience assessments, with measures of indirect economic loss developed from the IRIO. Furthermore, to examine the internal validity and systematic error, the reliability of the adopted models, the calculation methods, and the index systems are investigated. To assess the external validity of the proposed measures and resilience index of the framework, data from the 2008 Wenchuan Earthquake are applied for estimating parameter values of the framework, and a follow-up investigation was conducted for examining the fairness and enhanced effectiveness of the new counterpart assistance criteria. In summary, this paper attempts to present some new ideas about the analysis of economic motivations of mutual aid and the improvement of the counterpart assistance policy.     

Effect of Ca(II), Fe(II), and Fe(III) on Cu(II) adsorption by a polyvinylidene fluoride-based chelating membrane from Cu(II)–EDTA complex solution

A polyvinylidene fluoride-based membrane bearing the diethylenetriaminepentaacetic acid chelating group was employed to recover Cu(II) from the Cu(II)-ethylenediaminetetraacetic acid complex aqueous solution. Effects of Ca(II), Fe(II), and Fe(III) on Cu(II) uptake were investigated by static batch adsorption tests and dynamic adsorption filtration. Isotherms, kinetics, and breakthrough curves of Cu(II) uptakes in the presence of the three cations at concentrations of 1 mmol L^?1 were elucidated. The three cations showed a positive effect on the Cu(II) uptake; the stimulative roles were in the order of Fe(III) > Fe(II) > Ca(II). They did not alter the adsorption behavior of the membrane; adsorption isotherms and kinetics could be described by Langmuir and Lagergren second-order models, and Cu(II) adsorption was a spontaneous and exothermic process. The presence of Ca(II), Fe(II), and Fe(III) increased the sorption capacity of the membrane stack by 1.3, 1.9, and 3 times. Breakthrough time and the exhaustion time of membrane stacks were also extended.     

QSAR models for predicting the toxicity of halogenated phenols to Tetrahymena

Halogenated phenols are industrial pollutants which may cause serious damage to the environment. In this work, a two-dimensional (2D) and two three-dimensional (3D) quantitative structure–activity relationship models for the toxicity prediction of halogenated phenols in Tetrahymena were developed. The structural factors that mainly influence toxicity were explored, agreeing with previously reported data. The results obtained with the 3D model were in agreement with those obtained with the 2D model. According to our findings, several new molecules with different predicted activities were designed.