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81.
Vat and sulfur dyes must be reduced to their leuco forms before application. Since this process is currently carried out using irreversible reducing chemicals, it involves high economic and environmental costs. Here we show that reduction can alternatively be performed in an alkaline bath at room temperature by using H2 activated by a Pd catalyst. Sulfur dyes are thus directly reduced, whereas vat dyes require an electron transfer mediator. This alternative reaction can also be driven using H2 at sub-atmospheric pressures. It further avoids all drawbacks raised by electrolytic reductions, so far suggested as alternative green processes. 相似文献
82.
研究了ph在3-5的范围内,大气浓度水平下、铁、锰和铁锰共存时的注相催化氧化的动力学,发现在不同的条件下反应级数,表观反应速率常数和活化能不同,证实了铁,锰对S(Ⅳ)的液相催化氧化有明显的协同作用,并给出了许多反应体系的经验速率表达式。 相似文献
83.
《环境科学学报(英文版)》2023,35(3):786-797
Microbial electrosynthesis system (MES) is a promising method that can use carbon dioxide, which is a greenhouse gas, to produce methane which acts as an energy source, without using organic substances. However, this bioelectrical reduction reaction can proceed at a certain high applied voltage when coupled with water oxidation in the anode coated with metallic catalyst. When coupled with the oxidation of HS– to SO42−, methane production is thermodynamically more feasible, thus implying its production at a considerably lower applied voltage. In this study, we demonstrated the possibility of electrotrophic methane production coupled with HS– oxidation in a cost-effective bioanode chamber in the MES without organic substrates at a low applied voltage of 0.2 V. In addition, microbial community analyses of biomass enriched in the bioanode and biocathode were used to reveal the most probable pathway for methane production from HS– oxidation. In the bioanode, electroautotrophic SO42− production accompanied with electron donation to the electrode is performed mainly by the following two steps: first, incomplete sulfide oxidation to sulfur cycle intermediates (SCI) is performed; then the produced SCI are disproportionated to HS– and SO42−. In the biocathode, methane is produced mainly via H2 and acetate by electron-accepting syntrophic bacteria, homoacetogens, and acetoclastic archaea. Here, a new eco-friendly MES with biological H2S removal is established. 相似文献
84.
Yanfeng Wang Wei Chen Xiao Chen Huajun Feng Dongsheng Shen Bin Huang Yufeng Ji Yuyang Zhou Yuxiang Liang 《环境科学学报(英文版)》2018,30(3):347-355
Cd S/Mo S_2,an extremely efficient photocatalyst,has been extensively used in hydrogen photoproduction and pollutant degradation.Cd S/Mo S_2can be synthesized by a facile one-step hydrothermal process.However,the effect of the sulfur source on the synthesis of Cd S/Mo S_2via one-step hydrothermal methods has seldom been investigated.We report herein a series of one-step hydrothermal preparations of Cd S/Mo S_2using three different sulfur sources:thioacetamide,L-cysteine,and thiourea.The results revealed that the sulfur source strongly affected the crystallization,morphology,elemental composition and ultraviolet(UV)–visible-light-absorption ability of the Cd S/Mo S_2.Among the investigated sulfur sources,thioacetamide provided the highest visible-light absorption ability for Cd S/Mo S_2,with the smallest average particle size and largest surface area,resulting in the highest efficiency in Methylene Blue(MB)degradation.The photocatalytic activity of Cd S/Mo S_2synthesized from the three sulfur sources can be arranged in the following order:thioacetamideL-cysteinethiourea.The reaction rate constants(k)for thioacetamide,L-cysteine,and thiourea were estimated to be 0.0197,0.0140,and 0.0084 min~(-1),respectively.However,thioacetamide may be limited in practical application in terms of its price and toxicity,while L-cysteine is relatively economical,less toxic and exhibited good photocatalytic degradation performance toward MB. 相似文献
85.
A.M. Tsatsakis A. Manousakis M. Anastasaki M. Tzatzarakis K. Katsanoulas C. Delaki 《Journal of environmental science and health. Part. B》2013,48(6):657-670
Abstract This study paper reports on two cases of poisoning with the organophosphorus insecticides, fenthion and omethoate. The two victims were admitted in the Intensive Care Unit (ICU) a few hours after ingestion of the two insecticides. They received appropriate treatment for organophosphorous poisoning (gastric lavage, activated charcoal, atropine and pralidoxime) and supportive care. Both patients survived. Organophosphate blood levels were determined on admission (fenthion 2.9 (ig/ml, omethoate 1.6 Hg/ml) and during the hospitalisation and proved to be considerably high. Slow elimination rate of the poison already distributed in the body was indicated for both pesticides. The patient with omethoate poisoning remained clinically well (Glasgow Coma Scale : 15) and was discharged three days later. The patient with fenthion poisoning, who had also ingested 30 mg of bromazepam and 720 mg of oxetoron, developed cholinergic crisis six hours after admission and was intubated for 24 days, with concomitant complications. 相似文献
86.
87.
The heterogeneous uptake processes of sulfur dioxide on two types of Chinese mineral dust(Inner Mongolia desert dust and Xinjiang sierozem) were investigated using both Knudsen cell and smog chamber system. The temperature dependence of the uptake coefficients was studied over a range from 253 to 313 K using the Knudsen cell reactor, the initial uptake coefficients decreased with the increasing of temperature for these two mineral dust samples, whereas the steady state uptake coefficients of the Xinjiang sierozem increased with the temperature increasing, and these temperature dependence functions were obtained for the first time. In the smog chamber experiments at room temperature, the steady state uptake coefficients of SO2 decreased evidently with the increasing of sulfur dioxide initial concentration from 1.72 × 1012 to 6.15 × 1012mol/cm3. Humid air had effect on the steady state uptake coefficients of SO2 onto Inner Mongolia desert dust.Consequences about the understanding of the uptake processes onto mineral dust samples and the environmental implication were also discussed. 相似文献
88.
企业突发职业中毒事故应急物资准备研究 总被引:1,自引:0,他引:1
姜秀慧 《中国安全生产科学技术》2010,6(3):225-227
应急物资准备是突发职业中毒事故应急救援成功的关键因素。而我国企业目前普遍存在应急物资和资源配备不足、应急救援装备落后、老化等现象,这严重影响了突发职业中毒事故应急救援工作的有效开展。为在突发事件发生时能快速响应,企业必须做好应急物资准备工作。国家也应根据应急工作的特点,结合法律法规方面有关问题进行规定,以便从制度化、标准化方面入手,指导和进一步规范企业进行应急资源的配备。该文根据企业应急物资准备中存在的主要问题,提出了企业在充分危险评估的基础上,科学合理进行应急物资准备。国家也应不断完善并制订相应的应急资源准备标准,以指导和加强企业突发职业中毒事故应急救援物资的准备。 相似文献
90.