Fe2O3-CeO2-Bi2O3/γ-Al2O3 catalyst in the catalytic wet air oxidation (CWAO) of cationic red GTL under mild reaction conditions

Fe₂O₃-CeO₂-Bi₂O₃/γ-Al₂O₃, an environmental friendly material, was investigated. The catalyst exhibited good catalytic performance in the CWAO of cationic red GTL. The apparent activation energy for the reaction was 79 kJ·mol⁻¹. HO₂· and O₂·⁻ appeared as the main reactive species in the reaction. The Fe₂O₃-CeO₂-Bi₂O₃/γ-Al₂O₃ catalyst, a novel environmental-friendly material, was used to investigate the catalytic wet air oxidation (CWAO) of cationic red GTL under mild operating conditions in a batch reactor. The catalyst was prepared by wet impregnation, and characterized by special surface area (BET measurement), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The Fe₂O₃-CeO₂-Bi₂O₃/γ-Al₂O₃ catalyst exhibited good catalytic activity and stability in the CWAO under atmosphere pressure. The effect of the reaction conditions (catalyst loading, degradation temperature, solution concentration and initial solution pH value) was studied. The result showed that the decolorization efficiency of cationic red GTL was improved with increasing the initial solution pH value and the degradation temperature. The apparent activation energy for the reaction was 79 kJ·mol⁻¹. Hydroperoxy radicals (HO₂·) and superoxide radicals (O₂⁻·) appeared as the main reactive species upon the CWAO of cationic red GTL.     

区域循环工业发展评价指标体系的构建及应用

依据循环工业基本原理及Delphi方法,构建了包括资源利用效率、污染减量排放、资源循环利用、经济效益和科技水平在内的区域循环工业发展评价指标体系,并通过运用AHP(层次分析法)模型,测算了指标权重。据此,以南京市为例,评价了1996~2003年间南京市循环工业发展的状况,结果表明,自1996年以来,南京市循环工业发展水平不断提高,但是自2000年以来,在南京市工业经济效益不断增长的同时,资源利用效率、污染减量排放、资源循环利用、科技水平等指标增长缓慢,乃至出现波动性下降的状况,为此文章提出了相关政策建议。     

Effects of Forest Fragmentation and Habitat Degradation on West African Leaf-Litter Frogs

Abstract:  Habitat degradation alters the dynamics and composition of anuran assemblages in tropical forests. The effects of forest fragmentation on the composition of anuran assemblages are so far poorly known. We studied the joint influence of forest fragmentation and degradation on leaf-litter frogs. We specifically asked whether the processes structuring leaf-litter anuran assemblages in fragmented forests are the same as those in continuous forests. We analyzed anuran assemblages with respect to habitat characteristics, including fragmentation and degradation parameters. In comparison with continuous forests, species richness and diversity were lower and assemblage composition was altered in forest fragments. These changes seemed to be mainly caused by habitat degradation rather than forest fragmentation. Availability of aquatic sites for breeding, vegetation structure (including those variables indicating degradation), and leaf-litter cover had the most influence on the presence of single species. The comparatively small impact of fragmentation on anurans might be due to the location of the study area; it still possessed large tracts of continuous forest. These forest blocks may stabilize the regional rainforest climate and thus weaken the effects of fragmentation .     

Organic carbon and environmental quality of riverine and off-shore sediments from the Gulf of Cádiz,Spain

Here we show that heavy metal geoaccumulation is apparent in the Tinto and Odiel estuary and, at a lower magnitude, in off-shore sediments. Values above probable effects level (PEL) are recorded for As, Cu, Hg, Pb and Zn in the Tinto and Odiel estuary, for As and Hg in the associated off-shore sediments and for As in the Guadiana River. Significant correlations were found between total organic carbon (TOC) and Cr, Cu, Ni and Zn in the Tinto and Odiel estuary, and Cr, Cu, Ni, Pb, Hg and As in the Guadiana River. PCA analysis differentiated the three studied locations.     

风险评价在规划环境影响评价中的应用

规划环境影响评价(以下简称规划环评)是对规划实施后可能造成的影响进行分析、预测和评价的过程,属于战略影响评价范畴,需要解决区域内项目布局、规模等问题.规划环评中的风险评价应同规划环评的目标相对应,即从源头上对规划中涉及的风险源进行分析并提出预防或减缓风险的方案.比较了规划环评风险评价和建设项目风险评价后指出,规划环评中风险评价的目标主要在于通过对风险源的识别和分析,为整个区域内项目的布局、规模以及土地利用提供合理指导,并对原规划方案进行反馈.总结了风险评价用于规划环评中的特点及其与建设项目风险评价在步骤上的异同,并以平顶山化工城规划环境影响评价中风险评价的内容为例,对风险评价在规划环评中的应用进行了探讨.结果表明,平顶山的风险源对周围地区有一定影响,应考虑部分地区的搬迁工作.      

Pinelands national reserve: An intergovernmental approach to nature preservation

The Pinelands National Reserve was created in 1978 when private interests and federal, state, and local governments allied to protect 378,000 ha (935,000 acres) of New Jersey's Pine Barrens from encroaching development. An intergovernmental authority, the Pinelands Commission, manages the reserve by implementing a regional plan to guide development away from environmentally sensitive areas and into designated growth centers. Through transferable development rights, financial gains from development in growth centers are used to compensate owners and localities in the reserve who might otherwise have developed their lands. The national reserve strategy contrasts with other federal strategies for preserving unique environments in which the federal government exercises exclusive control (e.g., national parks, monuments, and recreation areas). This article describes the strategy applied in the Pinelands and discusses the conditions in which it may be more or less effective than other strategies used to protect unique or valued landscapes. It then compares the Pinelands model with the strategies and conditions of california's Redwood National Park and Point Reyes National Seashore to develop propositions about the circumstances in which one or another strategy is more likely to be viable. Finally, it applies these propositions to the possibilities for future forest preservation in New England.     

The Science of Politics/The Politics of Science: Examining the Snowmobile Controversy in Yellowstone National Park

The snowmobile controversy in Yellowstone National Park not only pits snowmobilers against environmentalists, but it also pits the Bush Administration against the Clinton Administration. Caught in the middle are the National Park Service, scores of natural and social scientists, and Yellowstones permanent residents—the flora and fauna. The controversys political aspects are the focus of this paper; specifically, the tenuous relationship among research scientists, whose job it is to inform management and policy decisions; politicians, whose job it is to formulate those same decisions in the public arena; and public land management agencies, whose job it is to implement the decisions. The crux of the paper concerns the politicization of natural resource policy and ways in which research scientists tend to get caught up in it. Lessons learned from this Yellowstone episode regarding the role of science in policy-making processes are also considered. Two recent federal court rulings shed additional light on the politics surrounding Yellowstones snowmobile controversy, as does the importance of governmental checks and balances in resolving natural resource management disputes.     

Enrichment of elements in industrial waste incineration bottom ashes obtained from three different types of incinerators,as studied by ICP-AES and ICP-MS

The elemental composition of the industrial waste incineration bottom ash (IWIBA) samples collected from three different types of incinerator with different kinds of wastes were compared. The major-to-ultratrace elements in the IWIBA samples were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). As a result, ca. 40 elements in the concentration range from milligrams per gram to submicrograms per gram could be determined with relative standard deviations of less than 5%. The IWIBA sample from petrochemical wastes contained lower concentrations of the elements, because fewer mineral constituents were contained in the input waste materials. On the contrary, the elemental concentrations in the IWIBA sample from industrial solid wastes provided the highest values for most elements, while the elemental compositions of the IWIBA sample from food wastes were similar to those of municipal solid waste incineration bottom ash. In addition, it was found from the analytical results that the levels of various heavy metals such as Cr, Mn, Fe, Ni, Cu, As, Zr, Mo, Sb, Ba, and Pb were higher in the IWIBA samples than in municipal solid waste incineration bottom ash. The enrichment factors of the elements in the IWIBA samples were estimated from the analytical results to compare the elemental distributions in incineration bottom ashes in relation to their mining influence factors, which are the indices for human use of the elements.     

Cross-Cultural Management of Pest Animal Damage: A Case Study of Feral Buffalo Control in Australia’s Kakadu National Park

Government agencies responsible for pest animal management often assume that their views and assumptions about the benefits of control are widely shared, especially if these pests are exotics. This was certainly the case when tens of thousands of feral Asian water buffalo (Bubalus bubalis) were to be culled in Australias Kakadu National Park as part of a national Brucellosis and Tuberculosis Eradication Campaign (BTEC). Implementation of the campaign sparked considerable dispute between officials and aboriginal and non-aboriginal interests about the risks posed by buffalo relative to their value as a potential resource. Drawing upon a variety of written and oral sources relating to the era of buffalo control in Kakadu, this paper critically analyzes the way in which detriment caused by buffalo was appraised and managed under the BTEC program. In particular, the paper focuses the ways in which the BTEC program affected aboriginal people in Kakadu, who view buffalo as a source of customary and economic benefit as well as a source of change on their lands. The paper then considers what lessons can be learned from the BTEC for the development of sensible feral management objectives and strategies. It is argued that effective management of feral animals such as buffalo will require environmental managers to engage with local people and involve them in the definition and management of pest animal damage and methods of control.     

中小型工业锅炉石灰湿式脱硫装置的试验研究

在１ｔ／ｈ的锅炉上进行了石灰湿式脱硫的冷、热态试验，阐述了气体参数和浆液参数对脱硫塔阻力和脱硫效率的影响规律，并分析了脱硫塔内的气体速度分布状况。结果表明脱硫塔阻力小于３００Ｐａ，脱硫效率大于５０％，是一种投资省、阻力低、占地少适合我国国情，具有开发前景的脱硫工艺。