Temporal change estimation of mercury concentrations in northern pike (Esox lucius L.) in Swedish lakes

Adequate temporal trend analysis of mercury (Hg) in freshwater ecosystems is critical to evaluate if actions from the human society have affected Hg concentrations ([Hg]) in fresh water biota. This study examined temporal change in [Hg] in Northern pike (Esox lucius L.) in Swedish freshwater lakes between 1994 and 2006. To achieve this were lake-specific, multiple-linear-regression models used to estimate pike [Hg], including indicator variables representing time and fish weight and their interactions. This approach permitted estimation of the direction and magnitude of temporal changes in 25 lakes selected from the Swedish national database on Hg in freshwater biota. A significant increase was found in 36% of the studied lakes with an average increase in pike [Hg] of 3.7 ± 6.7% per year that was found to be positively correlated with total organic carbon. For lakes with a significant temporal change the dataset was based on a mean of 30 fish, while for lakes with no temporal change it was based on a mean of 13 fish.     

植物病原细菌的BIOLOG系统鉴定及其多元统计初析

Ｂｉｏｌｏｇ细菌鉴定系统已广泛应用于细菌快速鉴定 ,通过比较菌株碳源利用的代谢指纹 ,还可用于细菌分类研究[1～ 4 \〗.该系统具有自动化和标准化程度高、结果快速准确和操作简便等优点 ,它主要根据细菌对 95种碳源的利用情况 ,以四唑紫 (Ｔｅｔｒａｚｏｌｉｕｍ)为指示剂 ,Ｂｉｏｌｏｇ代谢指纹经计算机处理并与数据库内已知细菌比较 ,实现对待测菌的快速鉴定 .Ｂｉｏｌｏｇ系统用于细菌分类研究中 ,除已广泛采用聚类分析并以树状图表示菌株间的相似关系外 ,近年来 ,国外许多学者已应用多元统计方法 (主成分分析、因子分析和方差分析 )…     

Landscape connectivity changes analysis for monitoring desertification of Minqin county, China

Landscape connectivity, as an important indicator of regional landscape functional pattern measured by cost–distances model, could both reveal evidence of, and act as an indicator, for desertification. Using Minqin county as a case study, this study was further to test cost–distance connectivity for indicating desertification, and to analyze temporal changes of connectivity in the county from 1977 to 1997. The results further indicate the connectivity interpreted as lower cost–distance and higher risk of desertification. The temporal change analysis of connectivity provides more detail supplement of desertification processes. Landscape connectivity changes in the county had three distinctive phases, the strongest decline of log cost–distance with overwhelming decrease area and decrease amount in the period 1977–1984, and its slight decline with the relative balance between the high decrease amount and high increase amount in the period 1984–1992, then its the slight decline with the relative balance between the low decrease amount and low increase amount in the period 1992–1997. The frequent temporal and spatial transition in source class, grassland, alkali–saline land and irrigated cultivated land caused negative effects on the oasis environment.     

Temporal trends and sources of PCDD/Fs, pentachlorophenol and chlornitrofen in paddy field soils along the Yoneshiro River basin, Japan

In order to understand the long-term behaviors of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), pentachlorophenol (PCP), and 2,4,6-trichlorophenyl-4′-nitrophenyl ether (chlornitrofen, CNP) in paddy soil, we measured their concentrations in paddy soil samples collected in 1982 and 1984 (1980s) and in 2000 and 2002 (2000s) from the Yoneshiro River basin, Japan. The concentrations of PCP and CNP decreased from the 1980s to the 2000s, whereas the concentrations of PCDD/Fs and their toxic equivalency (WHO2006-TEQ) remained. The major sources of PCDD/Fs in the paddy soil samples were attributed to impurities in PCP and CNP as a result of comparisons of homologue and congener profiles and principal component analysis. Based on the results of comparison of total input and remaining amount, it is estimated that more than 99% of PCP and CNP applied to the paddy fields had disappeared, whereas most of the applied PCDD/Fs and TEQ remained.     

Assessment of spatial-temporal patterns of surface and ground water qualities and factors influencing management strategy of groundwater system in an urban river corridor of Nepal

This study examined the spatial-temporal variations and factors influencing the management of groundwater along a section of the Bagmati river corridor in the Kathmandu valley (Nepal). The results showed that rural areas were less polluted than urban areas. In urban areas, the biochemical oxygen demand (BOD), total nitrogen (TN) and total phosphorus (TP) concentrations ranged from 8.41 to 29.74 mg/L, 6.7 to 128.96 mg/L and 0.06 to 1.5 mg/L, respectively. In rural areas, the BOD, TN and TP concentrations ranged from 0.78 to 18.25 mg/L, 4.8 to 11.56 mg/L and 0.07 to 0.65 mg/L, respectively. The level of organics was higher in the pre-monsoon season, while the level of nutrients was higher in post-monsoon season. A comparison of the groundwater and surface water in the upstream rural areas revealed that the TP concentration was higher in the groundwater than in the surface water, which was attributed to the sorption of phosphorus on iron, aluminum or calcium compounds contained in the surface water, which depends upon the temperature, pH and dissolved oxygen. In urban areas, a few wells were found at groundwater levels lower than the corresponding surface water levels and were subjected to a high risk of pollution. Overall, these findings reinforce the notion that the management of surface and ground waters in an integrated approach is essential for attaining sustainable development of groundwater systems.     

Monitoring the volume and lateral spread of disposed sediments by acoustic methods, Oslo Harbor, Norway

Acoustic equipment, including interferometric sonar and parametric sub-bottom profiler, have been used to determine the volume and lateral spread of dredged sediments disposed in the natural submarine depression in the Bekkelag Basin, inner Oslofjord since the beginning of the Oslo Harbor remediation project in 2006. This natural depression is used as a subaqueous confined disposal facility (CDF). Calculation of the volume of disposed sediments in the CDF is based on elevation change, derived from two high-resolution bathymetric datasets obtained in 2004, i.e. before the onset of the remediation project, and in April 2008. Seismic profiles across the CDF have been used to estimate the settlement of the original seabed, caused by loading-induced dewatering and compaction of the seabed sediments under the disposed masses.Detailed bathymetry and backscatter data demonstrate the lateral spread of disposed sediments within a well-confined area covering ca. 195,000 m². The sea bottom within this area is distinctly softer than the surrounding seabed as shown by very low acoustic backscatter amplitude, signifying a very loose surface character of the disposed sediments. The thickness of the disposed sediments reaches 6 m the deepest part of the original depression. The volume calculation of the disposed sediments in the CDF, based solely on bathymetry data, gives a value of ca. 310,000–320,000 m³. Settlement of the original seabed as a result of loading has been estimated to be 30 cm at 5 m thickness of the disposed sediments. Under the condition that the settlement rate is linearly correlated to the thickness of disposed sediments, the settlement corrected volume of disposed sediments is ca. 330,000–340,000 m³. Presented results demonstrate high accuracy and good reproducibility of acoustic seafloor data, and indicate a great potential of such methods as monitoring tools in environmental projects that involve dredging and subaqueous disposal.     

Effect of microbial activity, soil water content and added copper on the temporal distribution patterns of HCB and DDT among different soil organic matter fractions

Temporal changes in the distribution of exogenous HCB and DDT among different soil organic matter fractions were studied under sterile and non-sterile conditions, different soil water contents, and different concentrations of added Cu(2+). The residence time was 311days. Soil organic matter was fractionated into fulvic acid (FA), humic acid (HA), bound-humic acid (BHA), lipid, and insoluble residue (IR) fractions by a methyl isobutyl ketone (MIBK) method. Results revealed that there is a mass transfer tendency of DDT and HCB from FA, HA and BHA to IR and lipid fractions with increasing residence time. Microbial activity accelerated the mass transfer, while the addition of Cu(2+) slowed it down. The HCB and DDT transfer rate decreased as the soil moisture increased from 1.9% to 60%, but increased when soil moisture increased further to 90%. A two-compartment first order kinetic model was used to describe the mass transfer from FA, HA and BHA.     

Mobility of metals and metalloids in a multi-element contaminated soil 20 years after cessation of the pollution source activity

Knowledge of trace element concentrations and mobility is important in the ecotoxicological assessment of contaminated soils. We analysed soil pore water under field conditions to provide new insights into the mobility of residual contaminants in the surface 50cm of a highly contaminated woodland soil. Cadmium and Zn were highly mobile in the acidic soil, concentrations increasing with depth in soil pore water, showing considerable downward mobility. High levels of surface organic matter restricted the solubility of Cu, Pb and Sb, with highest concentrations being found close to the surface. Dissolved organic carbon in pore water had a strong influence on mobility of Cu, Zn, Pb and Sb. Elevated As had moved from the organic surface horizons but was largely immobilised in deeper layers and associated with Fe and Al oxides. The measured differential mobility of pollutants in the present study is highly relevant to protection of groundwater and other receptors.     

Levels and temporal trends (1983-2003) of persistent organic pollutants (POPs) and mercury (Hg) in seabird eggs from Northern Norway

The main objective of this study was to investigate possible temporal trends of persistent organic pollutants (POPs) and mercury in eggs of herring gulls (Larus argentatus), black-legged kittiwakes (Rissa tridactyla), common guillemots (Uria aalge) and Atlantic puffins (Fratercula arctica) in Northern Norway. Eggs were collected in 1983, 1993 and 2003. Egg concentrations of POPs (PCB congeners IUPAC numbers: CB-28, 74, 66, 101, 99, 110, 149, 118, 153, 105, 141, 138, 187, 128, 156, 157, 180, 170, 194, 206, HCB, alpha-HCH, beta-HCH, gamma-HCH, oxychlordane, trans-chlordane, cis-chlordane, trans-nonachlor, cis-nonachlor, p,p'-DDE, o,p'-DDD, p,p'-DDD, o,p'-DDT and p,p'-DDT) and mercury were quantified. Generally, POP levels decreased between 1983 and 2003 in all species. No significant temporal trend in mercury levels was found between 1983 and 2003.     

Declining levels of PCB, HCB and p,p′-DDE in adipose tissue from food producing bovines and swine in Sweden 1991–2004

The official control programme for organochlorine (OC) contaminants in food producing animals in Sweden was used to study temporal and spatial trends of the polychlorinated biphenyl CB 153, hexachlorobenzene (HCB) and p,p′-DDE in adipose tissue from bovines and swine 1991–2004. Our results show that efforts to decrease OC contamination of animal feed and the environment have had a positive impact on the contamination of the animal production. OC concentrations declined significantly in almost all studied regions of Sweden. OC temporal trends were slower in bovines (6–8% per year) than in swine (10–12%). Power analyses showed that data from more than 10 years of sampling were needed for a detection of an annual OC level change of 5% in both species in the control programme, due to large within- and between-year variation in OC levels. CB 153 and p,p′-DDE levels were higher in southern than in northern Sweden. Levels decreased with age in milk cows, but not in young nulliparous cows (heifers) and bulls. Moreover, milk cows and bulls had significantly lower OC levels than heifers. Levels were not age-dependent among swine, but castrated male swine (barrows) had significantly lower OC levels than young female swine (gilts). Levels of the studied OCs are now in many cases below the LOQ of the analytical method used. Future time trend studies of these OCs thus depend on lowered LOQs in the control programme.