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71.
生态环境变化遥感评价指数的应用研究——以敖江流域为例 总被引:1,自引:0,他引:1
利用1994年5月12日与2009年6月6日的Landsat TM和2001年5月23日的Landsat ETM+卫星影像,选用遥感生态指数(RSEI),结合流域的植被覆盖度状况,定量评价了15年间敖江流域的生态环境变化与植被覆盖度变化情况,并对二者的关系进行了简要分析.结果表明:15年间,敖江流域生态等级为优所占的面积比例从13.48%上升到24.90%,增加了304.29 km2;植被覆盖度等级为极高的面积增加比例为29.31%.总体看来,敖江流域生态环境状况和植被覆盖状况均有明显的提高,两者具有较好的对应关系. 相似文献
72.
Reaction thermal runaway is one of the most important reasons leading to chemical accidents. With the rapid development of the chemical industry in the world, especially the fine chemical industry, various safety accidents also occur frequently. Therefore, it is necessary to study the exothermic behavior of the reaction process. In this study, reaction calorimeter was used to study the exothermic phenomena during the chlorination reaction and amination reaction. Differential scanning calorimetry was performed on the reactants, and thermogravimetric experiments were performed on the products. In addition, adiabatic experiment was performed to study the thermal runaway behavior of amination products under adiabatic conditions. The results showed that the target reactions generated a large amount of heat in the initial stage. The maximum temperature of amination reaction is higher than the initial decomposition temperature of the amination product under adiabatic condition. The pyrolysis of amination product was divided into three stages. The product had a high apparent activation energy at the beginning of decomposition, and the apparent activation energy decreased as the decomposition progressed. 相似文献
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Thermal runaway hazard assessment provides the basis for comparing the hazard levels of different chemical processes. To make an overall evaluation, hazard of materials and reactions should be considered. However, most existing methods didn't take the both into account simultaneously, which may lead the assessment to a deviation from the actual hazard. Therefore, an integrated approach called Inherent Thermal-runaway Hazard Index (ITHI) was developed in this paper. Similar to Dow Fire and Explosion Index(F&EI) function, thermal runaway hazard of chemical process in ITHI was the product of material factor (MF) and risk index (RI) of reaction. MF was an indicator of material thermal hazards, which can be determined by initial reaction temperature and maximum power density. RI, which was the product of probability and severity, indicated the risk of thermal runaway during the reaction stage. Time to maximum rate under adiabatic conditions and criticality classes of scenario were used to indicate the runaway probability of the chemical process. Adiabatic temperature rise and heat of the desired reaction and secondary reaction were used to determine the severity of runaway reaction. Finally, predefined hazard classification criteria was used to classify and interpret the results obtained by this method. Moreover, the method was validated by case studies. 相似文献
76.
The effect of pyrolysis and oxidation characteristics on the explosion sensitivity and severity parameters, including the minimum ignition energy MIE, minimum ignition temperature MIT, minimum explosion concentration MEC, maximum explosion pressure Pmax, maximum rate of pressure rise (dP/dt)max and deflagration index Kst, of lauric acid and stearic acid dust clouds was experimentally investigated. A synchronous thermal analyser was used to test the particle thermal characteristics. The functional test apparatuses including the 1.2 L Hartmann-tube apparatus, modified Godbert-Greenwald furnace, and 20 L explosion apparatus were used to test the explosion parameters. The results indicated that the rapid and slow weight loss processes of lauric acid dust followed a one-dimensional diffusion model (D1 model) and a 1.5 order chemical reaction model (F1.5 model), respectively. In addition, the rapid and slow weight loss processes of stearic acid followed a 1.5 order chemical reaction model (F1.5 model) and a three-dimensional diffusion model (D3 model), respectively, and the corresponding average apparent activation energy E and pre-exponential factor A were larger than those of lauric acid. The stearic acid dust explosion had higher values of MIE and MIT, which were mainly dependent on the higher pyrolysis and oxidation temperatures and the larger apparent activation energy E determining the slower rate of chemical bond breakage during pyrolysis and oxidation. In contrast, the lauric acid dust explosion had a higher MEC related to a smaller pre-exponential factor A with a lower amount of released reaction heat and a lower heat release rate during pyrolysis and oxidation. Additionally, due to the competition regime of the higher oxidation reaction heat release and greater consumption of oxygen during explosion, the explosion pressure Pm of the stearic acid dust was larger in low concentration ranges and decayed to an even smaller pressure than with lauric acid when the concentration exceeded 500 g/m3. The rate of explosion pressure rise (dP/dt)m of the stearic acid dust was always larger in the experimental concentration range. The stearic acid dust explosion possessed a higher Pmax, (dP/dt)max and Kst mainly because of a larger pre-exponential factor A related to more active sites participating in the pyrolysis and oxidation reaction. Consequently, the active chemical reaction occurred more violently, and the temperature and overpressure rose faster, indicating a higher explosion hazard class for stearic acid dust. 相似文献
77.
Lysine is widely used in the fields of food, medicine and feed, which generally appears in the form of lysine sulfate or lysine hydrochloride dust because of the high instability of the free L-lysine. The L-lysine Sulfate is in high risk of decomposition, spontaneous ignition and even the dust explosion, because the control temperature in its production process is high up to 90 °C. Thus, the thermal behaviors and its thermal stability of 65% lysine sulfate are experimentally explored in Air and Nitrogen using the simultaneous TG-DSC measurements. Results show: (1) the decomposition of 65% lysine sulfate can be divided into three stages both in the atmospheres of air and nitrogen, and most of the weight loss occurred in the first two stages, which are related with the decarboxylation and deamination process. (2) The effects of atmosphere on the decomposition of 65% lysine sulfate mainly occur at the third stage. In this stage, the weight loss in nitrogen is only 14.2%, which is much lower than that in air (34.3%), which is related to the oxidative degradation at high temperature. Besides, the active energy is slightly increased in nitrogen compared to that in air. (3) The initial temperatures of the decomposition of the 65% lysine sulfate are 145 °C and 155 °C, for the air and nitrogen atmosphere, respectively, which are much lower than that (260 °C) of the pure lysine. 相似文献
78.
For lack of an extinguishing agent with high-efficiency, non-toxic and environmentally friendly, a new type of extinguishing agent was fabricated to solve such an urgent problem. In this study, the zinc borate (ZB) and ferrocene (Fe(Cp)2) were utilized as two additives for extinguishants to suppress combustion reaction and the toxicity of the tail gas was detected. The mass fraction of ZB corresponding to the optimal inhibitory effect was determined to be 0.5–1.5%, by contrast, the optimum interval of Fe(Cp)2 was detected as 0.5–1.0%. Similarly, with the increasing proportion of the two additives, the homologous inhibitory action was gradually weakened. From the perspective of thermogravimetric analysis (TGA), it was indicated that the ZB accelerated the pyrolysis process of the extinguishant, making its thermal decomposition process more thoroughly. Meanwhile, the differential scanning calorimetry (DSC) demonstrated that the decomposition efficiency was markedly improved when the amount of ZB was maintained at 0.5–1.5%. Besides, the tail gas tests were implemented to assess the extent of toxic and harmful properties. In terms of the carbon monoxide (CO) and carbon dioxide (CO2) generated, once the mass fraction of ZB and Fe(Cp)2 was less than 1.5% and 1.0% respectively, the concentration of CO and CO2 was distinctly lower than that without additives. Moreover, the inhibitory ability on nitrogen oxides (NOx) was enhanced when the mass fraction of the two additives was kept below 1.0%. The results confirmed that a more practical extinguishant was proposed and it can provide guidance for the application and development of extinguishants. 相似文献
79.
现阶段,随着社会经济的不断发展,国家越来越重视河道整治工作。目前,依然存在着部分河道污染严重的问题。本文将对河道生态环境保护与治理工作进行分析研究,希望为相关工作人员提供参考。 相似文献
80.
Jim CY 《Environmental monitoring and assessment》2006,116(1-3):53-80
Urban trees serve important environmental, social and economic functions, but similar to other natural endowments they are
not customarily depicted in monetary terms. The needs to augment protection, funding and community support for urban greening
call for proper valuation. Heritage trees (HTs), the cream of urban-tree stock, deserve special attention. Existing assessment
methods do not give justice to outstanding trees in compact cities deficient in high-caliber greenery, and to their social-cultural-historical
importance. They artificially separate evaluation from valuation, which should be a natural progression from the former. Review
of tree valuation methods suggested the formula approach to be more suitable than contingent valuation and hedonic pricing,
and provided hints on their strengths and weaknesses. This study develops an alternative formulaic expert method (FEM) that
integrates evaluation and valuation, maximizes objectivity, broadly encompasses the key tree, tree-environment and tree-human
traits, and accords realistic monetary value to HTs. Six primary criteria (dimension, species, tree, condition, location,
and outstanding consideration) branched into 45 secondary criteria, each allocated numerical marks. Each primary criterion
was standardized to carry equal weight, and a tree's maximum aggregate score is capped at 100. A Monetary Assignment Factor
(MAF) to consign dollar value to each score unit was derived from three-year average per m2 sale price of medium-sized residential flats. The applicability of FEM was tested on selected HTs in compact Hong Kong. The
aggregate score of a tree multiplied by MAF yielded monetary value, which was on average 66 times higher than the result from
the commonly-adopted Council of Tree and Landscape Appraisers method. The computed tree values could be publicized together
with multiple tree benefits to raise understanding and awareness and rally support to protect HTs. The property-linked FEM
could be flexibly applied to other cities, especially to assess HTs in compact developing cities. 相似文献