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501.
Monitoring and assessment of toxic metals in Gulf War oil spill contaminated soil using laser-induced breakdown spectroscopy 总被引:1,自引:0,他引:1
Laser-induced breakdown spectroscopy (LIBS) was applied for the detection of toxic metals in oil spill contaminated soil (OSCS).
The OSCS samples were collected from Khursania Saudi Arabia along the coast of Persian Gulf exposed to oil spills in 1991
Gulf war. Environmentally important elements like Aluminum Magnesium, Calcium, Chromium, Titanium, Strontium, Iron, Barium,
Sodium, potassium, Zirconium and Vanadium from the contaminated soil have been detected. Optimal experimental conditions for
analysis were investigated. The LIBS system was calibrated using standard samples containing these trace elements. The results
obtained using Laser-Induced Breakdown Spectroscopy (LIBS) were compared with the results obtained using Inductively Coupled
Plasma Emission Spectroscopy (ICP). The concentrations of some elements (Ba and Cr) were found higher than permissible safe
limits. Health risks associated with exposure to such toxic elements are also discussed. 相似文献
502.
Ross A. Sutherland Filip M. G. Tack Christina A. Tolosa Marc G. Verloo 《Environmental monitoring and assessment》2001,71(3):221-242
Washoff of road deposited sediment into storm drainsystems is one of the major contributors to nonpoint sourcepollution in urban fluvial networks. These sediments contain avariety of potentially toxic organic and inorganic contaminants.Road sediment from 13 locations in an urban (non-industrialized)drainage basin, and soil from 10 background (control) locationswere collected to assess total and labile fractions of Al, Co,Cu, Fe, Mn, Ni, Pb and Zn. Four digestions, of varying strength,were used to assess contaminant levels, these included: a totalfour-acid digestion, a microwave-assisted digestion withconcentrated nitric acid (USEPA Method 3051), a 0.5 M `cold' HCl,and a 0.05 M EDTA (pH 7). Road sediment data indicate that Al,Co, Fe, Mn and Ni were primarily lithogenic in origin, while Cu,Pb and Zn showed very significant anthropogenic signals, mostprobably from vehicle-related sources. Median Pb concentrationenrichment ratios for the EDTA extraction were about 42,indicating an extreme anthropogenic signal. The weak extractants(HCl and EDTA) are considered in this study to be superior intheir ability to characterize the degree of anthropogeniccontamination and should be utilized more widely in environmentalcontaminant studies. 相似文献
503.
Due to the consumption of the herby cheese in south eastern Anatolia-Turkey is at high ratio, chemical parameters such as
dry matter, pH, acidity, aCl, protein, fat and trace metal contents in 50 different herby cheeses produced at this region
have been determined in the presented study. The content of lead, copper, cobalt, nickel, chromium, cadmium, and iron have
been analyzed by flame atomic absorption spectrometer in air/acetylene flame after combination ash digestion method and wet
digestion method. The mean concentration of lead, copper, cobalt, nickel, chromium and cadmium in our samples are higher than
literature values except iron. 相似文献
504.
505.
微波消解体系与聚四氟乙烯滤膜对PM2.5中重金属测定的影响 总被引:1,自引:0,他引:1
采用4种微波消解体系对聚四氟乙烯(PTFE)材质滤膜采集的PM2.5样品进行消解,利用电感耦合等离子体质谱(ICP-MS)测定样品中Cr、Mn、Cu、As、Cd 5种重金属元素含量,并计算其空白加标和样品加标回收率,建立了测定PTFE材质滤膜采集的PM2.5样品中重金属元素的最优微波消解体系。结果表明,4种消解体系下,空白加标回收率和样品加标回收率均处于合理范围,分别为95.3%~116.3%和93.3%~118.5%。其中,HNO3放置过夜+H2O2消解体系具有空白值低、测定稳定性强、操作简便、绿色环保、对人体健康危害小等优点,能够满足大批量PM2.5样品中重金属总量的快速、高效、准确分析的要求。 相似文献
506.
Triolo L Binazzi A Cagnetti P Carconi P Correnti A De Luca E Di Bonito R Grandoni G Mastrantonio M Rosa S Schimberni M Uccelli R Zappa G 《Environmental monitoring and assessment》2008,140(1-3):191-209
In order to evaluate the impact of atmospheric pollutants emitted by the industrial settlement of Milazzo (Italy) on agriculture,
sulphur dioxide and ozone levels in air were monitored and the data were used to estimate yield losses of the most widespread
cultures. Trace element concentrations in crops and soils were also detected and metabolic profiles of soil microbial communities
were considered. Vibrio fischeri test was used to appraise airborne pollutant ecotoxicity and epidemiological studies on causes of death distribution were
carried out to characterize health state of people living in the area. All the sampling points were selected in farms on the
basis of a theoretical meteo-diffusive model of industrial air pollutants. Experimental SO2 and O3 values mainly exceeded the threshold established by Italian and EU regulations to protect vegetation and they correspond
to estimated significant crop losses. Conversely toxic element residues in soils and in agroalimentary products were generally
lower than the fixed values. SO2 and O3 concentrations, toxic element contents and ecotoxicity levels of airborne pollutants were not related only to industrial
site emissions, while the fluctuations on metabolic profiles of soil microbial communities seem to agree with the predicted
deposition of xenobiotic compounds from the industrial plants. The epidemiological study evidenced a better health state of
populations living in the investigated area than in the Messina province and the Sicily region but, inside the area, males
living in the municipalities closest to the industrial settlement exhibited a worst health state than those in the very far
ones. 相似文献
507.
采用高分辨电感耦合等离子体质谱法测定地下水中14种稀土元素,并选择Rh作内标,可消除测定中的质谱干扰和非质谱干扰,使方法在0μg/L~100μg/L范围内线性良好。方法检出限为0.002μg/L~0.005μg/L,实际水样的加标回收率为80.0%~117%,RSD为2.1%~3.8%。 相似文献
508.
Impact of Coal Power Plant Emission on the Foliar Elemental Concentrations in Plants in a Low Rainfall Tropical Region 总被引:1,自引:0,他引:1
A field study was conducted around two thermal power plants of India to quantify the changes in foliar elemental concentrations due to emission in a low rainfall tropical area. Sulphur dioxide and particulates were at high levels which may cause serious ecological effects. Emission from the power plants has altered the elemental concentrations in the leaves of evergreen and deciduous plants. The foliar total-S and SO4
2–-S levels were significantly higher in all the plants growing at polluted sites. However, the organic-S content was more or less unaltered. In evergreen plants, the SO4
2–-S content increased gradually from summer through winter, whereas in the deciduous plants there was a higher magnitude of increase after onset of new leaves during summer. With the increasing pollution load, foliar Ca2+ and K+ contents increased, whereas N content decreased. The reduction in N content was greater during summer in evergreen plants and during winter in deciduous plants. The plants growing closer to the power plants accumulated more trace elements (Mn, Fe, Cd, Pb and Ni) as compared to those growing at distant sites. In deciduous plants the leaf fall during winter lowered down the trace element 相似文献
509.
采用微波消解-电感耦合等离子体质谱法测定水系沉积物中12种元素,通过优化试验相关条件消除质谱干扰和非质谱干扰对测定的影响,使方法在0μg/L~200μg/L范围内线性良好,当取样质量为0.25 g,定容体积为50 m L时,各元素的方法检出限为0.002 mg/kg~0.05 mg/kg。用该方法测定沉积物标准物质,6次测定结果均在标准值范围内,RSD为1.3%~6.1%,实际样品的加标回收率为83.0%~97.0%。 相似文献
510.