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541.
Pilot plant study on ozonation and biological activated carbon process for drinking water treatment 总被引:1,自引:0,他引:1
A study on advanced drinking water treatment was conducted in a pilot scale plant taking water from conventional treatment process. Ozonation-biological activated carbon process (O3-BAC) and granular activated carbon process (GAC) were evaluated based on the following parameters: CODMn, UV254, total organic carbon (TOC), assimilable organic carbon (AOC) and biodegradable dissolved organic carbon (BDOC). In this test, the average removal rates of CODMn, UV254 and TOC in O3-BAC were 18.2%, 9.0% and 10.2% higher on (AOC) than in GAC, respectively. Ozonation increased 19.3-57.6 μg Acetate-C/L in AOC-P17, 45.6-130.6 μg Acetate-C/L in AOC-NOX and 0.1-0.5 mg/L in BDOC with ozone doses of 2 8 mg/L. The optimum ozone dose for maximum AOC formation was 3 mgO3/L. BAC filtration was effective process to improve biostability. 相似文献
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544.
Pulp mill effluent was treated by different advanced oxidation processes (AOPs) consisting of UV, UV/H2O2, TiO2-assisted photo-catalysis (UV/TiO2) and UV/H2O2/TiO2 in lab-scale reactors for total organic carbon (TOC) and toxicity removals. Effects of some operating parameters such as the initial pH, oxidant and catalyst concentrations on TOC and toxicity removals were investigated. Almost every method resulted in some degree of TOC and toxicity removal from the pulp mill effluent. However, the TiO2-assisted photo-catalysis (UV/TiO2) resulted in the highest TOC and toxicity removals under alkaline conditions when compared with the other AOPs tested. Approximately, 79.6% TOC and 94% toxicity removals were obtained by the TiO2-assisted photo-catalysis (UV/TiO2) with a titanium dioxide concentration of 0.75gl(-1) at pH 11 within 60min. 相似文献
545.
Water is a resource that is essential for all life on Earth. An exponentially growing human population, in addition to unprecedented
industrial and technological development, threaten the availability and quality of this resource. Climate change and ozone
depletion are two major environmental problems facing mankind today. These problems have the potential to further strain currently
available freshwater resources. Recent research has shown that climate change and ozone depletion are linked phenomena and
their interaction exacerbates their impact. Changes in precipitation, surface runoff, solar UV radiation, temperatures, and
evaporation are some of the predicted outcomes of climate change and ozone depletion. They influence the biogeochemical cycles
and aquatic ecosystems in lakes and rivers, and alter the character of natural organic matter (NOM) and, consequently, they
have the potential to affect the quality, quantity and treatability of our water resources. Given these uncertainties, and
the need to mitigate the consequences of climate change and ozone depletion, the issues of changing water quality, quantity
and treatability cannot be ignored by Australian governments and water utilities. 相似文献
546.
In this paper, the oxidation of tert-butyl formate (TBF) in aqueous solution by an ozone/UV process was described. The oxidation process was investigated experimentally in a semibatch reactor. The results of the study indicated that the ozone/UV process was very effective in oxidizing TBF. tert-Butyl alcohol (TBA), hydroxy-iso-butyraldehyde (HiBA), acetone, formaldehyde, and formic acid were identified as major primary intermediates during the oxidation of TBF. About 90% organic carbon balance was obtained indicating that most reaction intermediates have been identified and quantified. Some of the primary intermediates were also oxidized in the ozone/UV system. Accordingly, HiBA, acetone, formaldehyde, and formic acid were the primary intermediates of TBA oxidation. The oxidation of acetone in the ozone/UV system generated formaldehyde, pyruvaldehyde, acetic acid, formic acid as primary intermediates. It was also observed that the reaction intermediates formed during the oxidation of TBF react well in the ozone/UV system and complete mineralization could be achieved by the process. 相似文献
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548.
光助Fenton氧化法降解水中六氯苯的研究 总被引:7,自引:2,他引:5
采用光助Fenton氧化法处理六氯苯模拟废水,考察了反应时间、Fe3 与H2O2摩尔比、Fenton试剂用量、初始pH、六氯苯初始浓度、光强对六氯苯降解效果的影响,并初步探讨了六氯苯的降解动力学规律.结果表明.光助Fenton法降解六氯苯的最佳工艺条件为:紫外灯功率为300 W、Fe3 投加量为1.0 mmol/L、H2O2投加量为5.0 mmol/L、反应时间为60 min、初始pH为3,在此条件下,浓度为500μg/L的HCB的去除率可达91.3%.UV辐射与Fenton氧化对HCB的降解具有协同效应.光助Fenton法对HCB的降解符合一级反应动力学方程,表观速率常数为0.04 min-1,与Fenton法相比,提高了近9倍. 相似文献
549.
紫外分光光度法测定水中丁基黄原酸 总被引:5,自引:0,他引:5
根据丁基黄原酸具有在301 nm紫外波长段有最大吸收峰,pH<2时1 min内能够完全被分解,同时该吸收峰消失的特性,采用紫外分光光度(UV)法测定待测水样中丁基黄原酸浓度,并用待测水样作为背景校正,可有效地消除干扰.该方法的检出限为0.006 mg/L、测定上限为12.00 mg/L,实际水样测定的相对标准偏差小于5.76%.利用不同方法对样品进行分析测试,无明显差异.该方法具有线性相关性好、线性范围宽、操作简单准确等特点. 相似文献
550.
天津市秋季臭氧浓度影响因素及相关关系研究 总被引:3,自引:1,他引:2
选择天津市秋季典型重污染时期2005年11月2~7日近地面大气O3、NO、NO2、CO、紫外线(UV)强度和温度等观测数据,研究O3浓度的时间变化特征及其与相关前体物、气象条件的相关关系.结果表明,在观测期间O3浓度存在明显的日变化周期,在13:00~14:00时浓度最大,夜间变化平缓;O3浓度与NO、NO2、NOx和CO等前体物呈较好的负相关关系;温度和UV与O3浓度密切相关,昼间O3与UV呈相同变化趋势,相关系数达0.71,O3浓度变化滞后于UV变化,将O3浓度与前1小时的UV对比分析,相关系数提高到0.81. 相似文献