全文获取类型
收费全文 | 1209篇 |
免费 | 106篇 |
国内免费 | 876篇 |
专业分类
安全科学 | 65篇 |
废物处理 | 17篇 |
环保管理 | 84篇 |
综合类 | 823篇 |
基础理论 | 798篇 |
污染及防治 | 291篇 |
评价与监测 | 97篇 |
社会与环境 | 14篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 9篇 |
2022年 | 34篇 |
2021年 | 37篇 |
2020年 | 38篇 |
2019年 | 59篇 |
2018年 | 65篇 |
2017年 | 94篇 |
2016年 | 86篇 |
2015年 | 121篇 |
2014年 | 103篇 |
2013年 | 283篇 |
2012年 | 143篇 |
2011年 | 130篇 |
2010年 | 86篇 |
2009年 | 111篇 |
2008年 | 70篇 |
2007年 | 93篇 |
2006年 | 92篇 |
2005年 | 71篇 |
2004年 | 56篇 |
2003年 | 63篇 |
2002年 | 38篇 |
2001年 | 41篇 |
2000年 | 34篇 |
1999年 | 22篇 |
1998年 | 54篇 |
1997年 | 33篇 |
1996年 | 19篇 |
1995年 | 24篇 |
1994年 | 28篇 |
1993年 | 14篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 4篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有2191条查询结果,搜索用时 31 毫秒
201.
介绍了前处理-水解-生物接触氧化工艺处理染料废水的工程实例.当进水COD≤8000 mg/L时,出水可达到国家〈污水综合排放标准〉(GB8978-1996)二级标准. 相似文献
202.
A Triassic sandstone aquifer polluted with a mixture of phenolic hydrocarbons has been investigated by means of high-resolution groundwater sampling. Samples taken at depth intervals of 1 m have revealed the presence of a diving pollutant plume with a sharply defined upper margin. Concentrations of pollutant phenols exceed 4 g/l in the plume core, rendering it sterile but towards the diluted upper margin evidence for bacterial sulphate reduction (BSR) has been obtained. Groundwaters have been analysed for both delta34S-SO4 and delta18O-SO4. Two reservoirs have been identified with distinct sulphate oxygen isotope ratios. Groundwater sulphate (delta18O-SO4 = 3-5/1000) outside the plume shows a simple linear mixing trend with an isotopically uniform pollutant sulphate reservoir (delta18O-SO4 = 10-12/1000) across the plume margin. The sulphur isotope ratios do not always obey a simple mixing relation, however, at one multilevel borehole, enrichment in 34SO4 at the plume margin is inversely correlated with sulphate concentration. This and the presence of 34S-depleted dissolved sulphide indicate that enrichment in 34SO4 is the result of bacterial sulphate reduction. Delta34S analysis of trace hydrogen sulphide within the plume yielded an isotope enrichment factor (epsilon) of -9.4/1000 for present-day bacterial sulphate reduction. This value agrees with a long-term estimate (-9.9/1000) obtained from a Rayleigh model of the sulphate reduction process. The model was also used to obtain an estimate of the pre-reduction sulphate concentration profile with depth. The difference between this and the present-day profiles then gave a mass balance for sulphate consumption. The organic carbon mineralisation that would account for this sulphate loss is shown to represent only 0.1/1000 of the phenol concentration in this region of the plume. Hence, the contribution of bacterial sulphate reduction to biodegradation has thus far been small. The highest total phenolic concentration (TPC) at which there is sulphur isotope evidence of bacterial sulphate reduction is 2000 mg/l. We suggest that above this concentration, the bactericidal properties of phenol render sulphate-reducing bacteria inactive. Dissolved sulphate trapped in the concentrated plume core will only be utilised by sulphate reducers when toxic phenols in the plume are diluted by dispersion during migration. 相似文献
203.
Feiler U Ahlf W Hoess S Hollert H Neumann-Hensel H Meller M Weber J Heininger P 《Environmental science and pollution research international》2005,12(5):257-258
- In current biotest approaches, intact organisms or in vitro systems are exposed to sediments using different exposure scenarios.
The most important issue in sediment toxicity testing protocols is the question which test phase (solid or liquid) should
be used. Whole-sediment exposure protocols represent the most realistic scenario to simulate in situ exposure conditions in
the laboratory. However, until now there is no agreement in how to acquire and to evaluate the data of the various available
sediment contact assays. The SeKT joint research project was initiated with the aim to compare recently developed sediment
contact assays by addressing reference conditions, control sediments and toxicity thresholds for limnic sediment contact tests. 相似文献
204.
Svecevicius G Syvokiene J Stasiŭnaite P Mickeniene L 《Environmental science and pollution research international》2005,12(5):302-305
Goal, Scope and Background Chlorite (ClO2ˉ) is a primary decomposition product when chlorine dioxide (ClO2) is added during water treatment; therefore
the toxic effects of both compounds on aquatic organisms are possible. Limited data are available concerning their toxicity
to fish. The aim of this study was to investigate sensitivity of rainbow trout to acute and chronic toxicity of chlorine dioxide
and chlorite, and to estimate the Maximum-Acceptable-Toxicant-Concentration (MATC) of those compounds in fish.
Methods The acute and chronic toxicity of chlorine dioxide and chlorite to larval and adult rainbow trout was investigated in 96-hour
to 20-day laboratory exposures evaluating the wide range spectrum of biological indices under semi-static conditions.
Results and Discussion Median lethal concentration (96-hour LC50) values derived from the tests were: 2.2 mg/l for larvae; 8.3 mg/l for adult fish
and 20-day LC50 for larvae was 1.6 mg/l of chlorine dioxide, respectively. Chlorite was found to be from 48 to 18 times less
acutely toxic to larvae and adult fish, correspondingly. Both chemical compounds induced similar toxic effects in rainbow
trout larvae during chronic tests (they affected cardio-respiratory and growth parameters), but chlorine dioxide had a higher
toxic potency than chlorite. A significant decrease in the heart rate and respiration frequency of larvae was established.
However, within an increase in exposure duration recovery of cardio-respiratory responses was seen to have occurred in larvae
exposed to chlorite. Meanwhile, in larvae exposed to chlorine dioxide, a significant decrease in cardio-respiratory responses
remained during all 20-day chronic bioassays. Chlorine dioxide also more strongly affected growth parameters of rainbow trout
larvae at much lower test concentrations. Decreased rate of yolk-sack resorption occurred only in the tests with chlorine
dioxide.
Conclusions Maximum-Acceptable-Toxicant-Concentration (MATC) of 0.21 mg/l for chlorine dioxide and of 3.3 mg/l for chlorite to fish was
derived from chronic tests based on the most sensitive parameter of rainbow trout larvae (growth rate). According to substance
toxicity classification accepted for Lithuanian inland waters, chlorine dioxide and chlorite can be referred to substances
of \moderate\ toxicity to fish.
Recommendations and Outlook Due to its very reactive nature, chlorine dioxide is rapidly (in a few hours) reduced to chlorite, which is persistent also
as a biocide but 16 times less toxic to fish, according to MATC. Therefore, it is much more likely that fish will be exposed
to chlorite than to chlorine dioxide in natural waters. Presently accepted, the Maximum-Permitted-Concentration of total residual
chlorine (TRC) in waste-water discharging into receiving waters is 0.6 mg/l. If this requirement will not be exceeded, it
is unlikely that fish would be exposed to lethal or even to sublethal concentrations of chlorine dioxide or chlorite. Furthermore,
chlorine dioxide does not generate toxic nitrogenous (chloramines) or carcinogenic organic residuals (trihalomethanes). All
these properties make chlorine dioxide a more promising biocide than chlorine. 相似文献
205.
对国内外饮用水中HANs类消毒副产物检测方法、生成的影响因素及毒理学试验的研究进展与现状进行了调查和分析,探讨了其存在于饮用水中可能导致的人体健康危害。结果表明,饮用水中HANs类消毒副产物普遍存在,而且HANs消毒副产物比常规消毒副产物(三卤甲烷、卤乙酸等)具有更强的三致效应、生殖发育毒性、基因和细胞毒性,通过饮水摄入人体,对健康造成潜在危害。HANs的检测、人体健康风险评价和控制是今后的研究重点。 相似文献
206.
改性粉煤灰在处理锑矿选矿废水中的应用 总被引:9,自引:1,他引:8
针对锑矿选矿废水中锑和丁基黄原酸钠严重超标的问题,用酸改性粉煤灰对其进行吸附处理.试验结果表明,当改性粉煤灰处理选矿废水的最佳质量体积比(g.mL-1)为1:100,pH值为3,静置时间为4h时,可以将选矿废水中的锑浓度从28.611mg.L-1降到0.05mg.L-1以下,去除率达99.8%以上;废水中的丁基黄原酸钠浓度可从0.373mg.L-1降到0.02mg.L-1以下,去除率达95.0%以上.处理废水后的改性粉煤灰用硫酸-硝酸浸提,浸出液中重金属离子浓度均低于国家浸出毒性标准,表明改性粉煤灰是一种很好的锑矿选矿废水处理剂. 相似文献
207.
氯酚类化合物对青鱼和细鳞斜颌鯝幼鱼的毒性 总被引:10,自引:1,他引:9
以我国特有青鱼和细鳞斜颌鯝为受试物种,利用其生命早期阶段的急性毒性LC50值和28d慢性生长抑制试验所获得的最大可接受浓度(MATC)评价了3种氯酚类化合物的毒性效应.实验结果显示,2,4-二氯酚(2,4-DCP),2,4,6-三氯酚(2,4,6-TCP)和五氯酚(PCP)对青鱼和细鳞斜颌鯝的的96hLC50值分别为4.01(3.61~4.68)、1.22(1.12~1.31)、0.10(0.08~0.11)mg·mL-1和2.48(1.94~2.89)、1.10(0.38~1.36)、0.09(0.08~0.10)mg·mL-1,且3种氯酚类化合物对青鱼的毒性和细鳞斜颌鲴的毒性存在良好的线性相关性.根据化学物质对鱼类毒性分级标准,PCP对青鱼和细鳞斜颌鲴均为剧毒,2,4-DCP和2,4,6-TCP对青鱼和细鳞斜颌鲴均为高毒.青鱼对2,4-DCP,2,4,6-TCP和PCP的MATC分别为0.05mg·mL-1、0.10mg·mL-1和0.015mg·mL-1,对应的急慢性毒性比(ACR)分别为80.2、12.2和6.67;细鳞斜颌鲴对2,4-DCP、2,4,6-TCP和PCP的MATC分别为0.30mg·mL-1、0.15mg·mL-1和0.01mg·mL-1,对应ACR分别为8.27、7.33和9.00. 相似文献
208.
氟虫腈对斑马鱼和小菜蛾毒性的手性选择性研究 总被引:3,自引:0,他引:3
手性农药分子的不同对映体在环境中的降解速率和对于生物的毒性可能存在很大的差异,因此拆分并使用对靶标生物毒性较高或对非靶标生物毒性较低的单一或浓缩的对映体配方可以有效地降低杀虫剂的环境风险.本文用手性柱拆分了一种广泛使用的手性农药,氟虫腈的两种对映体,研究了这两种对映体和消旋体对靶标生物小菜蛾和非靶标生物斑马鱼的急性毒性.结果表明氟虫腈对受试靶标和非靶标生物的毒性均无手性选择性,说明无法通过对氟虫腈进行手性拆分并使用单一对映体配方来降低氟虫腈的环境风险.这一结论间接支持了农业部新近出台的禁止氟虫腈用于防治农田害虫的政策. 相似文献
209.
210.
The test was designed to assess the toxicity of methyl tert-butyl ether (MTBE) to Chlorella ellipsoidea and Aphanizomenon flos-aquae during 15 d with concentrations of MTBE from high (2.00×104 mg/L) to low (2 mg/L). The results showed that the toxicity was low when the concentration of MTBE was 1.00×104-2.00×104 mg/L (the greatest inhibition of growth-rate was 70%-71%, occurring on day 1-5). Low concentrations (2-500 mg/L) stimulated algal growth up to the greatest effect of 85%-200% when the concentration of MTBE was 50-100 mg/L on day 3-5. The low concentrations may lead to an algal bloom owing to overabundance, which represents an aquatic ecological risk. However, the stimulatory effect occurred only during the day 1-5 and disappeared gradually during the day 13-15. The toxicity of MTBE (72-120 h EC50) is 6.65×103-9.58×103 mg/L for C. ellipsoidea and that is 1.14×104-2.00×104 mg/L for A. spiroides. We found that the toxicity and ecological risk of MTBE for the algal community structure were low. The toxicity was influenced by the duration of the test. We suggest that the duration of the test should not be shorter than half a life-cycle. 相似文献