全文获取类型
收费全文 | 1504篇 |
免费 | 371篇 |
国内免费 | 423篇 |
专业分类
安全科学 | 115篇 |
废物处理 | 64篇 |
环保管理 | 92篇 |
综合类 | 787篇 |
基础理论 | 895篇 |
污染及防治 | 235篇 |
评价与监测 | 76篇 |
社会与环境 | 14篇 |
灾害及防治 | 20篇 |
出版年
2024年 | 1篇 |
2023年 | 14篇 |
2022年 | 35篇 |
2021年 | 45篇 |
2020年 | 37篇 |
2019年 | 45篇 |
2018年 | 118篇 |
2017年 | 103篇 |
2016年 | 109篇 |
2015年 | 121篇 |
2014年 | 145篇 |
2013年 | 193篇 |
2012年 | 161篇 |
2011年 | 159篇 |
2010年 | 124篇 |
2009年 | 115篇 |
2008年 | 86篇 |
2007年 | 87篇 |
2006年 | 88篇 |
2005年 | 67篇 |
2004年 | 70篇 |
2003年 | 54篇 |
2002年 | 44篇 |
2001年 | 33篇 |
2000年 | 32篇 |
1999年 | 30篇 |
1998年 | 20篇 |
1997年 | 16篇 |
1996年 | 23篇 |
1995年 | 20篇 |
1994年 | 21篇 |
1993年 | 16篇 |
1992年 | 16篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 9篇 |
1987年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有2298条查询结果,搜索用时 437 毫秒
981.
Causes of Keshan–Beck disease (KBD) are still being probed and monitored in China. Relationships between trace elements from eco-environmental systems and KBD are poorly understood although relationships between environmental Se and human health have received extensive attention. In order to investigate relationships between eco-environmental geochemistry and KBD, we selected the Chousang KBD area in Yao County, Shaanxi Province, China, as an example of a prevailing KBD area applying I–Se-rich salts instead of utilizing Se-rich fertilisers on food crops to prevent local residents from developing KBD before 1995. Environmentally geochemical samples (rocks, soils, plants and children's hair) were collected from the Chousang KBD area. Soils in the study area contain 0.11±0.02 µg Se g–1, 0.75±0.11 µg Mo g–1, and 34.5±1.5 µg B g–1 on average, indicating that the study area is a deficient-Se–Mo–B area. Se (0.07±0.007 µg g–1), Mo (0.35±0.09 µg g–1) and B (3±0 µg g–1) contents are low in wheat and corn used as a daily main food staple of local inhabitants. It is indicated that the study area is deficient in environmental Se–Mo–B for the local residents. Se contents of children's hair from the Yangyuan Elementary School in the study area range from 0.09 to 0.26 µg Se g–1 with an average of 0.165±0.05 µg Se g–1 (n=10) in this KBD endemic area. Due to the low levels of Se, Mo and B available in soils and rocks, crops including wheat and corn are deficient in these elements, accordingly, the deficiency of Se, Mo and B in this area may be linked to the daily consumption of wheat and corn deficient in Se, Mo and B. Therefore, local inhabitants should be encouraged to fertilise mixtures of Se, Mo and B on crop plants in order to avoid development of KBD and guarantee a good harvest of crops. 相似文献
982.
983.
大同市空气中多环芳烃与人尿中1-羟基芘的分析 总被引:4,自引:0,他引:4
用GC~2/MS和HPLC鉴定出大同市空气中的多环芳烃化合物35种.对大同市不同功能区空气中苯并(a)芘(BaP)和人尿中1-羟基芘同步采样分析.结果表明,不同功能区BaP浓度有显著差别:采暖期浓度急剧增加,城区浓度为对照点的17倍,日均值达330ng/m~3.人尿中1-羟基芘的浓度与空气中BaP的浓度显著相关.采暖期城区尿中1-羟基芘的几何均值为1.86μmol/mol肌酐,非采暖期为1.14μmol/mol肌酐,均较北京市的均值高出五倍多.证明大同市由于直接燃煤,造成空气中多环芳烃的严重污染. 相似文献
984.
海栖热袍菌极耐高温木聚糖酶B的化学修饰和活性中心 总被引:5,自引:0,他引:5
分别用NBS、DTNB、Phenylgloxal、PMSF、WRK等对海栖热袍菌极耐高温木聚糖酶B进行化学修饰.结果表明,酶蛋白分子上的色氨酸和谷氨酸(或天冬氨酸)残基是维持酶活性的必需基团.半胱氨酸、精氨酸、丝氨酸及组氨酸残基均不处于酶活性中心.而修饰酶热稳定性测定结果是,羧基对稳定性起重要作用.通过测定修饰酶的假一级常数,得到一个色氨酸残基和一个谷氨酸(或天冬氨酸)残基为极耐高温木聚糖酶B所必需.在加入少量底物后,极耐高温木聚糖酶B的最大荧光发射峰从天然状态下的336am处红移至345am,且峰强度下降.这表明色氨酸残基位于酶蛋白表面.图7表2参18 相似文献
985.
金针菇中蛋白质含量的变化和其中一个蛋白质的生物活性 总被引:1,自引:0,他引:1
在对金针菇(Flammulinavelutipes)子实体活性蛋白质纯化过程中发现,金针菇在不同环境条件下不同蛋白质的表达量有差异.通过阴离子交换层析、凝胶层析和高压液相色谱,从金针菇中分离纯化获得了一种蛋白质Zb.经SDS-PAGE测定该蛋白分子量(Mr)为 30×103,等电聚焦电泳表明该蛋白质的等电点为 4. 7,且该蛋白质不含糖.N-端测序表明,该蛋白质N-端的 20个氨基酸为PQVKTSWEDLANLGWPIQQV.此外,在HepG2. 2. 2. 15细胞株上检测该蛋白质体外对肝炎病毒的抑制作用,发现对HBsAg抑制作用明显,抑制中浓度为 0. 117μg/mL,但对HBeAg几乎无作用.以胃癌细胞株MGC80-3为研究对象,检测表明,该蛋白质对MGC80-3抑制率在 50%时的蛋白质浓度约为 0. 75μg/mL.以起始浓度为 0. 296mg/mL的Zb检测它的血凝活性时发现,Zb对兔血红细胞和人A、B、O血红细胞的血凝滴度为 2-12.但同时观察到Zb处理后的兔血红细胞形态发生改变. 图 6表 1参 15 相似文献
986.
Protczak A Trzeszczynski J 《Environmental science and pollution research international》2002,9(6):377-380
In the last years, a continuous increase of the O3 concentration has been recorded in the lower atmospheric layers. Photochemical reactions with NO(x), CO and organic compounds are the main sources of O3 in the troposphere. In this work, an attempt was made to determine the impact of alkenes on the O3 concentration in the troposphere. A study on the gas-phase reactions of 03 with 1-hexene, 1-heptene and 1-nonene was made. The reactions were carried out at room temperature under atmospheric pressure. Ozone was formed by the ultraviolet radiation emitted by a mercury lamp, in order to simulate the atmospheric conditions. The changes with time in the concentration of O3, 1-alkenes and formed aldehydes were investigated. Qualitative and quantitative analyses were done by means of the gas chromatography and colorimetry. The following products were identified: pentanal from 1-hexene; hexanal from 1-heptene; oktanal from 1-nonene. For each of the reactions, HCHO was also determined as a product. The reaction rate constants were calculated and obtained in units of 10(-17) cm(-3) molecule(-1) s(-1): 1.94-0.99 for 1-hexene, 5.54-4.51 for 1-heptene and 1.54-0.76 for 1-nonene. Based on the results obtained, an explanation of O3 concentration variations in the planetary boundary layer can be given. Last year a considerable increase of O3 concentration on the roads of Western Europe was recorded. This increase could have resulted from the decrease of alkene concentration in the air due to common use of the catalytic converters in cars. The unsaturated hydrocarbons rapidly oxidize on the catalyst. In Eastern Europe, where the amount of cars equipped with catalytic converters is smaller than in Western Europe, the alkene content in the exhaust fumes results in a decrease of the O3 concentration in the troposphere. 相似文献
987.
无机/有机复合絮凝剂对碱性玫瑰精B的脱色研究 总被引:7,自引:0,他引:7
复配了一种无机 有机复合絮凝剂 ,并研究了它对碱性玫瑰精B模拟废水及广州某印染厂实际污水的处理效果。结果表明 ,该复合絮凝剂对碱性玫瑰精B模拟废水具有很好的脱色效果 ,当投加量为 650mg L时 ,脱色率达 98%以上 ,上清液近似无色 ,具有絮凝颗粒密实 ,污泥量小 ,沉淀速度快等优点 ,且在相同条件下比仅使用无机絮凝剂节省用量 57%。对实际污水 ,当投加量为 40 0mg L时 ,脱色率达到 92 % ,絮凝后污水基本无色。 相似文献
988.
989.
Professor D. J. H. Brock Lilias Barron Susan Holloway W. A. Liston S. G. Hillier M. Seppala 《黑龙江环境通报》1990,10(4):245-251
A set of 21 early maternal serum samples (19 first-trimester and two at 14 weeks) from pregnancies resulting in a child with Down syndrome was matched for gestation and length of storage with 63 samples from unaffected pregnancies. The concentrations of alpha-fetoprotein (AFP), unconjugated oestriol (uE3), human chorionic gonadotrophin (hCG), pregnancy-specific β1–glycoprotein (SP1), and placental alkaline phosphatase (PALP) were measured. The ratios of the medians for Down syndrome pregnancies compared with the medians for controls were AFP 0·71, uE3 0·67, hCG 1·43, SP1 0·79, and PALP 0·92. Although the differences between the medians for affected and unaffected pregnancies were not significant, the trends for AFP, uE3, and hCG confirm earlier findings on first-trimester samples. 相似文献
990.