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121.
Wichmann H Sprenger R Ehlers N Bahadir MA 《Environmental science and pollution research international》2005,12(4):227-232
Background, Aims and Scope Releasing agents, applied in the aluminium diecasting process, usually consist of water, oils, waxes, polysiloxanes, as well
as of a set of additives like emulsifiers, corrosion inhibitors, and biocides. During spray application and part release,
gases and aerosols are emitted into workplace air. The chemical compositions of these emissions are determined by the components
of the releasing agents and their reaction products formed during thermal stress of more than 700 °C. In the frame of the
joint project, the analytical tasks were to develop an appropriate sampling strategy for this production environment, to draw
conclusions about the occurrence of hazardous chemicals from production plant studies and from laboratory-scale thermolysis
experiments, and to determine the biodegradability of customary releasing agents.
Methods During realistic test production, active air sampling was performed in a production hall using different adsorption materials.
Cotton fabric sheets were positioned in the production area as passive samplers. Thermolysis experiments were performed at
600 °C with sealed quartz ampoules. The biodegradability of different releasing agents was determined according to German
industry standard DIN 51828 (2000). For analyses, GC/MS (headspace), FTIR, HPLC, IC, and ICP-OES techniques were applied.
Results and Discussion The substance spectrum, which was found in workplace air, was dominated by saturated and non-saturated aliphatic hydrocarbons.
Besides these, alcohols, alkyl phenols, xylenes and other benzene derivatives, aldehydes, glycols, carboxylic acid esters,
and amides were present. The German limiting value of 40 mg/m3 of complex hydrocarbon mixtures in a diecasting workplace atmosphere
was clearly under-run. Total hydrocarbon contents ranged between 2.7 and 6.3 mg/m3. Five different PAH were found in the air
close to the diecasting machine, with maximum concentrations between 0.05 and 3.06 μg/m3. Concentrations of nonylphenols ranged
from 10 to 200 μg/m3, and those of triethanolamine from 20 to 30 μg/m3. From 17 elements analyzed, only B, Fe, P, S, Si, and
Ti were emitted in small amounts. It was striking that the PAH patterns resulting from thermolysis experiments were quite
the same compared to those determined during the diecasting process. An influence of water and of Fe/Al on the composition
of the thermolysis products could mostly be shown. The degrees of biodegradation of three releasing agent extracts after 21
days were 21%, 29%, and 55%, respectively.
Conclusion A sampling strategy was developed, which allows an emission assessment for the industrial process of aluminium diecasting.
It enabled one to control limiting values, to characterise a wide variety of compounds emitted, and to identify and quantify
relevant pollutants. Only a few hazardous substances could be detected during the exemplary use of one releasing agent within
the compounds emitted into workplace air. Indications were found, that the prediction of the formation of harmful substances
from releasing agent components should be possible via thermolysis experiments. The biodegradability test can serve to assess
the expenditure of disposal of the usual leakage run-off of excess agent during production.
Recommendation and Outlook Investigations on further differently composed releasing agents, e.g. powders, would be desirable. A substitution of nonylphenol
ethoxylates by less harmful components would surely be an improvement of a releasing agent with regard to work safety and
health care, because of avoiding the emission of toxic and endocrine active nonylphenols. The surprisingly wide range of biodegradability
of the investigated releasing agents points to an optimization potential, that has obviously not yet been considered. 相似文献
122.
123.
本文分析了我国废铝回收处理现状,论述了废铝回收与现代技术的关系,指出废铝的回收分类标准和废铝的直接改制利用应引起人们的重视。 相似文献
124.
125.
薄液膜下铝合金与不锈钢电偶腐蚀研究 总被引:3,自引:3,他引:0
目的研究与不锈钢偶接时铝合金的腐蚀行为与机理。方法依据ASTM G149标准制备电偶试样,在循环盐雾箱中模拟薄液膜下2024铝合金与316L不锈钢之间的电偶腐蚀过程,分别在腐蚀6,12,18,24,30 d后取出试样,进行质量损失分析、截面与点蚀坑形貌分析、以及电化学阻抗谱测试。结果偶接之后2024铝合金的质量损失量是非偶接条件下的将近10倍。偶接后2024铝合金在腐蚀6 d后就形成了约20μm厚的腐蚀产物层,且随着腐蚀时间的增加,腐蚀产物层越来越致密,越来越厚。偶接后点蚀坑则主要在横向扩展,在纵深方向扩展较小。结论电偶作用不仅加速了铝合金的腐蚀,还改变了其腐蚀过程,而且这种作用在腐蚀的初期不明显,在腐蚀后期较为显著。 相似文献
126.
127.
以Na2SiO3·9H2O,Al2(SO4)3·18H2O为原料,加入一定量稳定剂,采用复合法制备出高铝含量且稳定的聚硅硫酸铝(PASS)。研究结果表明:采用磷酸氢二钠与烷基糖苷(质量比为1:1)作为复合稳定剂,在碱化度为1.5~1.8、Ⅳ(A1):Ⅳ(Si)=1.0~3.0的条件下,合成的PASS絮凝效果最佳;复合稳定剂对废水的COD去除率及浊度去除率影响不大,但能显著改善絮凝产品的稳定性;PASS可用于处理pH范围较宽(pH为6.0—11.0)的工业废水,且处理前后废水pH变化不大;PASS对低温低浊度废水有较好的絮凝效果;在加入量相同的情况下,PASS的絮凝性能明显优于聚合硫酸铝、硫酸铝、聚合硫酸铁,当PASS加入量为40~100恤L/L时,废水浊度去除率达98%以上。 相似文献
128.
129.
以废铝易拉罐为原料,通过除漆、研磨等制得废铝易拉罐粉末(SAlCP)。利用SAlCP处理含U(VI)废水,优化处理工艺条件,采用SEM和XPS技术对SAlCP进行表征,并探讨了SAlCP去除U(Ⅵ)的机理。实验结果表明:在反应温度为30℃、溶液初始pH为5.0、U(Ⅵ)初始质量浓度为10 mg/L、SAlCP投加量为4 g/L、反应时间为120 min的优选条件下,U(Ⅵ)的去除率达98.2%。SAlCP去除U(Ⅵ)的反应过程可用拟一级动力学模型和Langmuir-Hinshelwood模型能较好地拟合。SAlCP的作用机理是还原沉淀-吸附共沉,且还原作用是SAlCP去除U(Ⅵ)的主要途径。 相似文献
130.
絮凝沉淀-Fenton试剂氧化法处理含高浓度硫酸盐的洗涤剂生产废水 总被引:3,自引:1,他引:2
采用絮凝沉淀-Fenton试剂氧化法处理含高浓度硫酸盐的洗涤剂生产废水(简称废水),考察了各种因素对COD去除率的影响。实验结果表明:根据实际废水的水质情况,选用聚合氯化铝(PAC)为絮凝剂,PAC最佳加入量为0.3g/L,经絮凝处理后COD去除率为42.3%;Fenton试剂氧化的最佳操作条件为:n(H2O2):n(Fe^2+)=0.5、H2O2加入量为7mmol/L、反应时间为2h,不调节废水初始pH,经Fenton试剂氧化处理后COD去除率为70%以上。经絮凝沉淀-Fenton试剂氧化法处理后,废水COD由1950mg/L降至240mg/L,总的COD去除率为87.7%,废水处理效果良好。 相似文献