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21.
环境升温过程对常温固化环氧树脂热力学性能的影响 总被引:2,自引:0,他引:2
目的提高常温固化环氧树脂体系的高温使用性能。方法采用常温固化剂T31、中温固化剂IPDA以及高温固化剂DDM作为混合固化剂,对E-44型和AG-80型混合环氧树脂体系进行常温固化反应,并分析环境升温过程对固化物热力学性能的影响。通过DMA分析、热变形测量、固化度测试,分别评价室温固化环氧树脂在环境升温过程前后的玻璃化转变温度、热变形量及体系内部的固化反应程度变化,并通过吸水率测试和弯曲强度测试对玻璃纤维布增强常温固化环氧树脂基复合材料的耐湿热性能以及高温条件下的力学性能进行分析。结果环氧树脂常温固化物的tg为85.21℃,经1.5℃/min的平均升温速率加热至90℃之后,该环境升温过程使固化物的固化度增大至92%以上,tg增长为132.06℃的同时热变形温度增大。其复合材料耐湿热性能提高,且100℃时弯曲强度的保持率为65%,对于加热至120℃的环境升温过程,固化物的固化度接近96%,tg增长为144.45℃的同时热变形温度进一步提高,其复合材料耐湿热性能改善程度更加明显,且130℃时弯曲强度保持率仍接近60%。结论常温、中温、高温混合固化剂的合理复配有助于环氧树脂体系在环境升温变化的诱导条件下发生梯度式固化反应,使体系内部的交联固化程度迅速升至较高水平,可以有效提高其玻璃化转变温度,显著改善常温固化环氧树脂体系在高温条件下的热力学性能。 相似文献
22.
大气环境质量综合评价加权灰色关联模型的建立与应用 总被引:1,自引:2,他引:1
利用灰色理论建立大气环境质量综合评价加权灰色关联模型 ,运用污染贡献率确定权重系数。与其它评价模型相比 ,加权灰色关联模型还具有排序功能 ,实例表明该模型是简便有效的 相似文献
23.
Analysis of pollutant levels in central Hong Kong applying neural network method with particle swarm optimization 总被引:6,自引:0,他引:6
Air pollution has emerged as an imminent issue in modernsociety. Prediction of pollutant levels is an importantresearch topic in atmospheric environment today. For fulfillingsuch prediction, the use of neural network (NN), and inparticular the multi-layer perceptrons, has presented to be acost-effective technique superior to traditional statisticalmethods. But their training, usually with back-propagation (BP)algorithm or other gradient algorithms, is often with certaindrawbacks, such as: 1) very slow convergence, and 2) easilygetting stuck in a local minimum. In this paper, a newlydeveloped method, particle swarm optimization (PSO) model, isadopted to train perceptrons, to predict pollutant levels, andas a result, a PSO-based neural network approach is presented. The approach is demonstrated to be feasible and effective bypredicting some real air-quality problems. 相似文献
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Fence for traffic noise control sometimes causes adverse effect on air pollution. Thus in this study, performance of porous fence as a tool for control of both air pollution and noise pollution was evaluated. A two-dimensional numerical model for flow and pollutant concentration and an analytical model for traffic noise were utilized in the analysis of a double-decked road structure with fences only at ground (Case 1) and at both ground and upper deck (Case 2). Porous fences were assumed only at the ground level since the solid fences at the upper deck usually leads to desirable result on air pollution. Effects of the variable porosity on air quality and noise level near road were evaluated. Obtained results showed: (1) flow pattern in leeward of fence was drastically changed at 40–50% porosity in Case 1 and 50% in Case 2. The porosity larger than 40% excluded presence of a circulation behind the fence. (2) Effect of porous fence on air pollution was different in Cases 1 and 2. In Case 1, the porous fence generally resulted in the reduction of air pollution at the ground level; on the other hand, in Case 2, it rather led to increase of the concentration. (3) Traffic noise level was also largely changed by the porosity of the fence; an example of simultaneous evaluation of the effects of porous fence on both air and noise pollution in Case 1 showed that the fence of 60% porosity leads to reduction of air pollution by 20% compared with solid fence case, and reduction of noise pollution by 4–6% in dB compared with no fence case, at l m high and 10 m from the road. 相似文献
28.
Atmospheric aerosols are an important contributing factor to turbidity in urban areas besides having impact on health. Aerosol characteristics show a high degree of variability in space and time as anthropogenic share of total aerosol loading is quite substantial and is essential to monitor the aerosol features over long time scales. In the present study extensive observations of columnar aerosol optical depth (AOD), total columnar ozone (TCO) and precipitable water content (PWC) have been carried over a tropical urban city of Hyderabad, India. Significant variations of AOD have been observed during course of the day with low values of AOD during morning and evening hours and high values during afternoon hours. Spectral variation of AOD exhibits high AOD at smaller wavelengths and vice versa except a slight enhancement in AOD at 500 nm. Anomalies in AOD, particulate matter and black carbon concentrations have been observed during May, 2003. Back trajectory analysis of air mass during these episodes suggested variation in air mass trajectories. Analysis of the results suggests that air trajectories from land region north of study area cause high loading of atmospheric aerosols. The results are discussed in the paper. 相似文献
29.
Hijano CF Domínguez MD Gimínez RG Sínchez PH García IS 《Environmental monitoring and assessment》2005,111(1-3):75-88
The evaluation of certain vascular plants that grow in the city of Madrid as biomonitors of SO2 air pollution in urban environments has been carried out. Total concentration of sulphur in leaves of the chosen higher plants
as well as other parameters in close relation to this contaminant (visible injury symptoms, chlorophyll a- and b-content and
peroxidase activity) have been determined in order to study the spatial distribution and temporal changes in SO2 deposition. Results obtained show that coniferous species such as Pinus pinea, were more sensitive to SO2 atmospheric concentration than leafy species as Quercux ilex subspecies ballota and, in the same way, bush species, such asPyracantha coccinea and Nerium oleander, were more sensitive than wooded species, such as Cedrus deodaraandPinus pinea, respectively. There is a higher accumulation of sulphur in vegetable species located near highways and dense traffic incidence
roads and near areas with high density of population. The minimum values for accumulation of SO2 were registered in winter and spring seasons (from January to April) due to the vegetative stop; while maximum values are
obtained during the summer season (from June to September), due to the stoma opening. The highest increments in sulphur concentration,
calculated as the difference between two consecutive months, are obtained in May and June for all considered species except
forCedrus deodara and Pyracantha coccinea, both species have few seasonal changes during the whole year. Some species are more sensitive to natural washing than others,
showing a decrease in sulphur concentration after rainfall periods. 相似文献
30.
土壤重金属污染的灰色模糊评价 总被引:14,自引:1,他引:14
以灰色聚类为基础,提出了灰色模糊聚类分析法,并将其应用于土壤环境质量评价中,经实例分析表明,这是一种较为简便,合理、有效的评价方法。 相似文献