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891.
采用十六烷基三甲基溴化铵(HDTMA)对粘土进行改性,通过X射线衍射、红外光谱、热分析技术对改性粘土进行表征,分析作用机理;并将改性粘土用于垃圾渗滤液中氨氮的处理,对处理过程的吸附热力学和动力学性能进行研究。研究表明:粘土经过改性后,改性粘土的层间间距增大了0.754 nm;在303.15 K,313.15 K,333.15 K不同温度下,粘土吸附渗滤液中氨氮的平衡的时间为50 min左右,改性后的粘土吸附效果比原土提高了大约2~3倍;改性粘土对氨氮的吸附符合Langmuir等温吸附模型和Freundlich等温吸附模型;吸附过程标准摩尔吉布斯自由能△G~θ在-0.127 kJ/mol^-0.080 kJ/mol范围内,标准摩尔焓变△H~θ<0,吸附反应过程均属自发的放热过程;吸附动力学数据符合准二级动力学方程和粒子内扩散方程。 相似文献
892.
Melanie D. Harrison Andrew J. Miller Peter M. Groffman Paul M. Mayer Sujay S. Kaushal 《Journal of the American Water Resources Association》2014,50(6):1365-1382
Although wetlands are known to be sinks for nitrogen (N) and phosphorus (P), their function in urban watersheds remains unclear. We analyzed water and nitrate (NO3?) and phosphate (PO43?) dynamics during precipitation events in two oxbow wetlands that were created during geomorphic stream restoration in Baltimore County, Maryland that varied in the nature and extent of connectivity to the adjacent stream. Oxbow 1 (Ox1) received 1.6‐4.2% and Oxbow 2 (Ox2) received 4.2‐7.4% of cumulative streamflow during storm events from subsurface seepage (Ox1) and surface flow (Ox2). The retention time of incoming stormwater ranged from 0.2 to 6.7 days in Ox1 and 1.8 to 4.3 days in Ox2. Retention rates in the wetlands ranged from 0.25 to 2.74 g N/m2/day in Ox1 and 0.29 to 1.94 g N/m2/day in Ox2. Percent retention of the NO3?‐N load that entered the wetlands during the storm events ranged from 64 to 87% and 23 to 26%, in Ox1 and Ox2, respectively. During all four storm events, Ox1 and Ox2 were a small net source of dissolved PO43? to the adjacent stream (i.e., more P exited than entered the wetland), releasing P at a rate of 0.23‐20.83 mg P/m2/day and 3.43‐24.84 mg P/m2/day, respectively. N and P removal efficiency of the oxbows were regulated by hydrologic connectivity, hydraulic loading, and retention time. Incidental oxbow wetlands have potential to receive urban stream and storm flow and to be significant N sinks, but they may be sources of P in urban watersheds. 相似文献
893.
Observations of Atmospheric Nitrogen and Phosphorus Deposition During the Period of Algal Bloom Formation in Northern Lake Taihu,China 总被引:4,自引:1,他引:4
Cyanobacterial blooms in Lake Taihu occurred at the end of April 2007 and had crucial impacts on the livelihood of millions
of people living there. Excessive nutrients may promote bloom formation. Atmospheric nitrogen (N) and phosphorus (P) deposition
appears to play an important role in algal bloom formation. Bulk deposition and rain water samples were collected respectively
from May 1 to November 30, 2007, the period of optimal algal growth, to measure the bulk atmospheric deposition rate, wet
deposition rate, and dry deposition rate for total nitrogen (TN; i.e., all species of nitrogen), and total phosphorus (TP;
i.e., all species of phosphorus), in northern Lake Taihu, China. The trends of the bulk atmospheric deposition rate for TN
and the wet deposition rate for TN showed double peaks during the observation period and distinct influence with plum rains
and typhoons. Meanwhile, monthly bulk atmospheric deposition rates for TP showed little influence of annual precipitation.
However, excessive rain may lead to high atmospheric N and P deposition rates. In bulk deposition samples, the average percentage
of total dissolved nitrogen accounting for TN was 91.2% and changed little with time. However, the average percentage of total
dissolved phosphorus accounting for TP was 65.6% and changed substantially with time. Annual bulk atmospheric deposition rates
of TN and TP during 2007 in Lake Taihu were estimated to be 2,976 and 84 kg km−2 a−1, respectively. The results showed decreases of 34.4% and 78.7%, respectively, compared to 2002–2003. Annual bulk deposition
load of TN for Lake Taihu was estimated at 6,958 t a−1 in 2007 including 4,642 t a−1 of wet deposition, lower than the values obtained in 2002–2003. This may be due to measures taken to save energy and emission
control regulations in the Yangtze River Delta. Nevertheless, high atmospheric N and P deposition loads helped support cyanobacterial
blooms in northern Lake Taihu during summer and autumn, the period of favorable algal growth. 相似文献
895.
896.
制药废水硝化-反硝化除氮研究 总被引:12,自引:0,他引:12
含高浓度氮的制药废水经好氧生化处理后,虽然出水的COD,BOD5均可达到行业排放标准,但TN仍高达约170mg/L。本研究在曝气池中设置填料,利用生物膜外层好氧,内层缺氧厌氧的条件,使硝化-反硝化脱氮在同一构筑物内进行,NH3-N和TN去除率分别可达约90%和70%。在本试验条件范围内,温度越高,负荷越低,硝化和反硝化作用越完全,NH3-N和TN去除率越高。 相似文献
897.
898.
David Fowler Rognvald Smith Jennifer Muller John Neil Cape Mark Sutton Jan Willem Erisman Hilde Fagerli 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):41-47
Emissions of sulphur and oxidized nitrogen compounds in Europe have been reduced following a series of control measures during
the last two decades. These changes have taken place during a period in which the primary gases and the wet deposition throughout
Europe were extensively monitored. Since the end of the 1970s, for example land based sulphur emissions declined by between
90 and 70% depending on the region. Over the same period the total deposition of sulphur and its partitioning into wet and
dry deposition have declined, but the spatial pattern in the reduction in deposition differs from that of emission and has
changed with time. Such non-linearities in the emission-deposition relationship are important to understand as they complicate
the process of assessing the effects of emission reduction strategies. Observed non-linearities in terrestrial sulphur emission-deposition
patterns have been identified in north west Europe due to increases in marine emissions, and are currently slowing the recovery
of freshwater ecosystems. Changes in the relative amounts of SO2 and NH3 in air over the last two decades have also changed the affinity of terrestrial surfaces for SO2 and have therefore changed the deposition velocity of SO2 over substantial areas. The consequence of this effect has been the very rapid reduction in ambient SO2 concentration in some of the major source areas of Europe, where NH3 did not change much. Interactions between the different pollutants, generating non-linearities are now being incorporated
in long-range transport models to simulate the effects of historical emission trends and to provide projections into the future.
This paper identifies non-linearities in emission deposition relationships for sulphur and nitrogen compounds in Europe using
data from the EMEP long-rang transport model and measured concentration fields of the major ions in precipitation and of SO2 and NO2 in surface air. 相似文献
899.
900.
生态工程综合治理系统对农业小流域氮磷污染的治理效应 总被引:1,自引:4,他引:1
以典型农业小流域——开慧河流域源区为研究对象,基于研究区农业面源污染的主要排放特征,建立以生态湿地为主的小流域面源污染生态工程综合治理系统,重点探讨其对水体氮磷污染物的去除效果.结果表明,畜禽养殖业是开慧河流域源区水体氮磷污染物的主要来源,需要重点防控.组合生态湿地处理工程对农村分散式生活与养殖混合废水总氮(TN)、总磷(TP)的平均去除率为87. 1%和90. 9%;多级人工湿地拦截工程对农田排水与分散式养殖混合废水TN、TP的平均去除率为85. 7%和84. 9%;景观型生态湿地净化工程对末端汇水区水体中TN、TP的去除率在27. 1%~67. 4%和13. 3%~81. 5%之间.整个生态工程综合治理系统对流域TN和TP污染物的总拦截量分别为5 292 kg·a~(-1)和1 054 kg·a~(-1),占研究区农业面源TN、TP总污染负荷的35. 3%和43. 6%.因此,构建的生态工程综合治理系统对流域农业面源氮磷污染具有较好的治理效应,适合在我国南方小流域水环境治理中推广应用. 相似文献