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The adsorption behaviour of Basic Red 12, Acid Orange 7 and Acid Blue 1 on zinc oxide nanoparticles (ZNP) has been investigated to understand the physicochemical process involved and to explore the possible use of nanoparticles in the treatment and management of textile waste matter. The dye removal capacity of ZNP towards Basic Red 12, Acid Orange 7 and Acid Blue 1 was found to be 15.64, 6.78 and 6.38 mg g?1, respectively. The adsorption process was pH dependent and optimum pH values of 9.0, 2.0 and 4.0 were obtained for Basic Red 12, Acid Orange 7 and Acid Blue 1, respectively. Equilibrium was established after 1.0 h for all dyes. Langmuir, Freundlich and Temkin isotherm models were applied to the system. The adsorbent ZNP was characterised using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR) techniques. SEM analysis revealed the noticeable nanoporous morphology of the material. The results of FTIR spectroscopy showed that the process is driven by an electrostatic complexation mechanism. XRD studies revealed the nanocrystalline structure of ZNP. BET surface area measurement suggested a high pore volume and large surface area for the adsorbent. The kinetic measurements suggested pseudo-second-order kinetic processes with high regression coefficients and smaller standard error of estimate values and lower residual sum of squares. The thermodynamic measurements suggested that all processes were exothermic and accompanied by negative values for Δ G0, Δ S0 and Δ H0. 相似文献
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Steady performance of a zero valent iron packed anaerobic reactor for azo dye wastewater treatment under variable influent quality 总被引:1,自引:0,他引:1
Zero valent iron (ZVI) is expected to help create an enhanced anaerobic environment that might improve the performance of anaerobic treatment. Based on this idea, a novel ZVI packed upflow anaerobic sludge blanket (ZVI-UASB) reactor was developed to treat azo dye wastewater with variable influent quality. The results showed that the reactor was less influenced by increases of Reactive Brilliant Red X-3B concentration from 50 to 1000 mg/L and chemical oxygen demand (COD) from 1000 to 7000 mg/L in the feed than a reference UASB reactor without the ZVI. The ZVI decreased oxidation-reduction potential in the reactor by about 80 mV. Iron ion dissolution from the ZVI could buffer acidity in the reactor, the amount of which was related to the COD concentration. Fluorescence in situ hybridization test showed the abundance of methanogens in the sludge of the ZVI-UASB reactor was significantly greater than that of the reference one. Denaturing gradient gel electrophoresis showed that the ZVI increased the diversity of microbial strains responsible for high efficiency. 相似文献
35.
The pure decomposition behavior of 2,2′-azobis (isobutyronitrile) (AIBN) and its physical phase transformation were examined and discussed. The thermal decomposition of this self-reactive azo compound was explored using differential scanning calorimetry (DSC) to elucidate the stages in the progress of this chemical reaction. DSC was used to predict the kinetic and process safety parameters, such as self-accelerating decomposition temperature (SADT), time to maximum reaction rate under adiabatic conditions (TMRad), and apparent activation energy (Ea), under isothermal and adiabatic conditions with thermal analysis models. Moreover, vent sizing package 2 (VSP2) was applied to examine the runaway reaction combined with simulation and experiments for thermal hazard assessment of AIBN. A thorough understanding of this reaction process can identify AIBN as a hazardous and vulnerable chemical during upset situations. The sublimation and melting of AIBN near its apparent onset decomposition temperature contributed to the initial steps of the reaction and explained the exothermic attributes of the peaks observed in the calorimetric investigation. 相似文献
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以钛酸四丁酯为原料 ,膨胀珍珠岩为载体 ,用溶胶 -凝胶法制备可漂浮于水面的负载型TiO2 。利用该负载型TiO2 对罗丹明B(RB)进行光催化脱色实验 ,结果表明 ,浸渍 3次的负载型TiO2 光催化活性最高 ,催化剂最佳用量为 5 0 0mg/10 0mLRB ,经 5h光照 ,对 10 0mL浓度为 1mg/L和 2 .5mg/LRB脱色率分别为 76 .6 7%和 4 7.2 7% ;该催化剂使用寿命长 ,2 5h后催化剂脱色性能没有减弱 ,可重复使用 ;经 8h光照 ,染料废水脱色效果好。 相似文献
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The effects of various quinone compounds on the decolorization rates of sulfonated azo dyes by Sphingomonas xenophaga QYY were investigated. The results showed that anthraquinone-2-sulfonate (AQS) was the most effective redox mediator and AQS reduction was the rate-limited step of AQS-mediated decolorization of sulfonated azo dyes. Based on AQS biological toxicity tests, it was assumed that AQS might enter the cells to kill them. In the cytoplasmic extracts from strain QYY, AQS effectively increased decolorization rates of sulfonated azo dyes than other quinone compounds. In addition, we found a NADH/FMN-dependent AQS reductase using nondenaturing polyacrylamide gel electrophoresis (Native-PAGE). 相似文献
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偶氮染料酸性橙Ⅱ、吩嗪染料中性红和三苯甲烷染料碱性艳蓝BO是3种具有代表性的常用工业染料。通过气液两相滑动弧放电等离子体产处理这3种染料,对其脱色效果、反应动力学、降解效果及降解路径进行了分析。实验结果显示:当放电电压10 k V、频率50 Hz、载气(空气)流速0.8 m~3/h、液体流速60 m L/min、染料溶液体积500 m L、浓度200 mg/L,放电处理60 min时,滑动弧等离子体对染料溶液的具有较好的脱色效果,酸性橙II、中性红和碱性艳蓝BO的脱色率分别为84.1%、72.7%与89.7%。3种染料的脱色反应符合一级反应动力学规律,其中碱性艳蓝在前30 min的脱色速率最快,可达0.0631 min~(-1),远大于酸性橙II和中性红,而后30 min的反应速率均明显放慢,低于酸性橙II和中性红的同期脱色速率。滑动弧等离子体对3种染料的降解效果(COD去除率)不高,经过60 min的处理降解率分别仅为27.4%、37.3%和28.2%。最后,通过降解过程中的UV-Vis色谱变化对3种染料的降解路径作了初步推测,即等离子体先破坏染料的发色体系与共轭体系,随后发生开环反应,最后再降解为小分子结构。 相似文献