DIN Retention‐Transport Through Four Hydrologically Connected Zones in a Headwater Catchment of the Upper Mississippi River1

Abstract: Dissolved inorganic nitrogen (DIN) retention‐transport through a headwater catchment was synthesized from studies encompassing four distinct hydrologic zones of the Shingobee River Headwaters near the origin of the Mississippi River. The hydrologic zones included: (1) hillslope ground water (ridge to bankside riparian); (2) alluvial riparian ground water; (3) ground water discharged through subchannel sediments (hyporheic zone); and (4) channel surface water. During subsurface hillslope transport through Zone 1, DIN, primarily nitrate, decreased from ～3 mg‐N/l to <0.1 mg‐N/l. Ambient seasonal nitrate:chloride ratios in hillslope flow paths indicated both dilution and biotic processing caused nitrate loss. Biologically available organic carbon controlled biotic nitrate retention during hillslope transport. In the alluvial riparian zone (Zone 2) biologically available organic carbon controlled nitrate depletion although processing of both ambient and amended nitrate was faster during the summer than winter. In the hyporheic zone (Zone 3) and stream surface water (Zone 4) DIN retention was primarily controlled by temperature. Perfusion core studies using hyporheic sediment indicated sufficient organic carbon in bed sediments to retain ground water DIN via coupled nitrification‐denitrification. Numerical simulations of seasonal hyporheic sediment nitrification‐denitrification rates from perfusion cores adequately predicted surface water ammonium but not nitrate when compared to 5 years of monthly field data (1989‐93). Mass balance studies in stream surface water indicated proportionally higher summer than winter N retention. Watershed DIN retention was effective during summer under the current land use of intermittently grazed pasture. However, more intensive land use such as row crop agriculture would decrease nitrate retention efficiency and increase loads to surface water. Understanding DIN retention capacity throughout the system, including special channel features such as sloughs, wetlands and floodplains that provide surface water‐ground water connectivity, will be required to develop effective nitrate management strategies.     

COMPARISON OF TWO AUTOREGRESSIVE MODELS FOR MONTHLY STREAM FLOW GENERATION1

ABSTRACT: Two autoregressive models for monthly stream flow generation are compared based on the reproduction of the historical record in terms of several important statistics such as the mean, standard deviation, skewness coefficient, correlation coefficient, and the reservoir storage components. In the comparison, both theoretical considerations and practical applications are employed to evaluate the performance of each model.     

Air quality assessment along Dhanbad - Jharia road

Road ambient air pollution status along Dhanbad – Jharia road isstudied and presented in this article. The selection of this areais made considering the importance of the road in Dhanbad district and the nature of activities taking place along the road, which reflect that the portion of road upto Dhansar can be considered as having commercial areas on both sides and that from Dhansar to Jharia as having industrial areas on both sides.For the assessment of the ambient air quality along the road monitoring is done at the following five locations: Indian Schoolof Mines (ISM), main gate; Bankmore; Dhansar police check post; Dhansar opencast project agent office and a residential house beside the Rajapur opencast project. The location of ISM, maingate is specially chosen as this represents a commercial shoppingcomplexes and the situation can be compared with that at Bankmore. Monitoring of ambient air quality is done following thestandard procedure prescribed in IS: 5182. In addition the concentration of lead, zinc, copper, iron, manganese, cadmium metals in SPM is also monitored. The ambient air quality is monitored in the months of September and November 1999, respectively, to represent monsoon and winter seasons. The SPM concentration observed at all the five locations in the winterseason is more than the permissible limits for commercial andindustrial areas. However, in the monsoon season, the SPM concentration is higher than the permissible limit at the twocommercial locations, i.e., ISM gate and Bankmore, while it isless than the prescribed limit for industrial areas at the remaining three locations. At the ISM gate and Bankmore the SPM generation is mainly by vehicular traffic while at other three locations it was in addition due to mining and other activities.     

沈阳市大气可吸入颗粒物水溶性组分的因子分析

选取沈阳市6个监测点位,采集2005年冬、春、夏、秋大气可吸入颗粒物样本。用安捷伦7500型电感耦合等离子体质谱仪分析PM10中19种水溶性组分。用因子分析法分析了沈阳市大气可吸入颗粒物水溶性组分的来源。     

Direct supercritical fluid extraction from water

Abstract

This paper describes the development of apparatus suitable for direct supercritical fluid extraction of organics from water. Results are presented for the extraction of pentachlorophenol present in water at concentrations of the order of 0.1 ppm. The effect of changes in apparatus design and supercritical fluid flow rate on recovery are discussed.     

Assessing audit impact and thoroughness of VCS forest carbon offset projects

Voluntary markets transacted over $66 million USD of forest carbon offsets in 2016, according to Forest Trends, and over 99% of those offset projects were audited to a standard, primarily the Verified Carbon Standard (VCS). We provide a table characterizing all 70 validated and verified forest carbon projects employing the VCS version 3.0 currently-in-use (December 2011–July 2017). We also examine two separate aspects of the audit process––impact and thoroughness––to assess the effectiveness of the costly audit process, which can consume up to one-third of offset revenue. Audit impact we measure in terms of reduction in the number of offsets from ex ante estimated to ex post approved. Audit thoroughness we measure both directly in terms of the number of auditor hours worked per project and also indirectly in terms of the total number of Corrective Action Requests (CARs)/Non-Conformity Reports (NCRs) auditors prescribe. In terms of impact, we find that Afforestation/Reforestation/Restoration (A/R/R) and Improved Forest Management (IFM) projects, though only constituting 5% of total verified offsets, demonstrate significant (p < = 0.05) reductions from ex ante estimated to ex post approved offsets, likely because auditors can easily scrutinize carbon stocks/emission factors for the commercial tree species involved in these project types. In terms of thoroughness, we find that higher ex ante estimates correlate with more total auditor hours worked and total CARs/NCRs prescribed for three of four project activity types, likely because auditors perceive larger ex ante projects as higher risk. We conclude with recommendations for the VCS to empower auditors to scrutinize carbon stocks/emissions factors from avoided deforestation projects, and also to continue to flag high ex ante projects as higher risk.     

Biospheric influence on carbon dioxide measurements in Italy

The study concerning carbon dioxide measurements taken during the 1997, 1998 and 1999 summer campaigns at two different altitude stations and biospheric conditions are presented. The higher station (Mt. Cimone, 2165 m a.s.l.) is characterised by 360° free horizon and is located on a rocky mountain while the lower (Ninfa lake, 1550 m a.s.l.) is located inside the red spruce and beech forest. The different behaviour of CO₂ at the two mountain stations has been registered. It shows the strong effect of nighttime soil emission and vegetation respiration on CO₂ mixing ratio increases and of diurnal vegetative activity on CO₂ concentration decreases at the lower measurement site. The baseline character of the higher measurement site has been confirmed by comparison of CO₂ diurnal amplitudes recorded at the two stations.     

Soil organic carbon dynamics of croplands in European Russia: estimates from the “model of humus balance”

The Model of Humus Balance was used to estimate the influence of climate effects and changing agricultural practices on carbon (C) levels in soddy–podzolic soils in the Russian Federation for the years 2000–2050. The model was linked with a spatial database containing soil, climate and farming management layers for identification of spatial change of C sequestration potential. Analysis of relationships between C, soil texture and climate indicated that compared with a business-as-usual scenario, adaptation measures could increase the number of polygons storing soil organic carbon (SOC) by 2010–2020. The rate of possible C loss is sensitive to the different climate scenarios, with a maximum potential for SOC accumulation expected in 2030–2040, thereafter decreasing to 2050. The effect is most pronounced for the arid part of the study area under the emission scenario with the highest rate of increase in atmospheric CO₂ concentration, supporting findings from the dynamic SOC model, RothC. C sequestration during the study period was permanent for clay and clay loam soils with a C content of more than 2%, suggesting that C sequestration should be focused on highly fertile, fine-textured soils. We also show that spatial heterogeneity of soil texture can be a source of uncertainty for estimates of SOC dynamics at the regional scale. Figures in color are available at     

基于社会网络分析的江西各地市公路行业碳排放的关联与分异特征研究

针对各地公路碳排放的空间差异与关联特征，制定合理的低碳策略，实现各地协同碳减排，是行业可持续发展的热点问题。以江西省为研究对象，采用空间自相关、社会网络分析和引力模型等分析11地市公路行业碳排放的空间差异与关联，识别社会网络的结构特征及其演变趋势，明确不同地市在网络中的地位和作用，结果显示：（1）公路货运是公路行业碳排放的最主要来源；（2）江西省公路行业碳排放整体上呈现空间随机分布，不存在全局的空间聚集性，且局部空间聚集特征不断变化；（3）公路行业碳排放网络逐渐从南昌、新余双中心结构演变为南昌为主的单中心结构，网络的协同作用整体呈减弱趋势，核心地市对外围地市的影响力和带动作用不足。     

“碳中和”愿景下我国碳排放现状和减排路径

控制以CO₂为主的温室气体排放，“力争2030年前实现碳达峰，争取2060年前实现碳中和”是我国近年来面临的重大任务。碳排放研究是实现“双碳”目标的基础和前提，从碳排放测算、碳排放影响因素分析、行业碳排放研究三个方面对我国碳排放研究现状进行梳理，对近年来研究的重点方向、主要成果和目前存在的主要问题进行分析，并结合我国的“双碳”目标提出现阶段我国“以完善政策标准与加大政府扶持为基础，以产业结构调整与新兴产业发展、能源结构调整与新能源技术发展为核心，以探索CCUS（碳捕集、利用与封存）技术和增加碳汇及对居民低碳消费倾向的引导和培养为导向”的碳减排路径。