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Diffusion experiments through hardened cement pastes (HCP) using tritiated water (HTO) and 22Na+, considered to be conservative tracers, have been carried out in triplicates in a glove box under a controlled nitrogen atmosphere. Each experiment consisted of a through-diffusion test followed by an out-diffusion test.The experimental data were inversely modelled applying an automated Marquardt–Levenberg procedure. The analysis of the through-diffusion data allowed the extraction of values for the effective diffusion coefficients, De, and the rock capacity factor, α. Good agreement between measured and calculated tracer breakthrough curves was achieved using both a simple diffusion model without sorption and a diffusion/linear sorption model. The best-fit Kd-values were found to be consistent with Rd-values measured in previous batch-sorption experiments.The best-fit values from the through-diffusion tests were then used to predict the results of subsequent out-diffusion experiments. Good agreement between experimental data and predictions was achieved only for the case of linear sorption.Isotopic exchange can only partially account for both the amount of tracer taken up in the batch-sorption tests and the measured retardation in the diffusion experiments and, hence, additional mechanisms have to be invoked to explain the data. 相似文献
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Perchlorate as an environmental contaminant 总被引:5,自引:0,他引:5
Urbansky ET 《Environmental science and pollution research international》2002,9(3):187-192
Perchlorate anion (ClO4-) has been found in drinking water supplies throughout the southwestern United States. It is primarily associated with releases of ammonium perchlorate by defense contractors, military operations, and aerospace programs. Ammonium perchlorate is used as a solid oxidant in missile and rocket propulsion systems. Traces of perchlorate are found in Chile saltpeter, but the use of such fertilizer has not been associated with large scale contamination. Although it is a strong oxidant, perchlorate anion is very persistent in the environment due to the high activation energy associated with its reduction. At high enough concentrations, perchlorate can affect thyroid gland functions, where it is mistakenly taken up in place of iodide. A safe daily exposure has not yet been set, but is expected to be released in 2002. Perchlorate is measured in environmental samples primarily by ion chromatography. It can be removed by anion exchange or membrane filtration. It is destroyed by some biological and chemical processes. The environmental occurrence, toxicity, analytical chemistry, and remediative approaches are discussed. 相似文献
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本文研究了N_(1923)萃淋树脂对汞(Ⅱ)吸萃的性能、溶液的酸效应、吸附等温线、吸附速率及体系温度等对吸萃分配比的影响.用饱和容量法、等摩尔系列法、斜率法等对吸萃物组成进行了探讨.并用红外光谱法、核磁共振谱法对吸萃机理进行了分析. 相似文献
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利用钙型斜发沸石处理氨氮废水 总被引:1,自引:0,他引:1
介绍了用钙型斜发沸石处理氨氮废水的方法,研究了钙型斜发沸石对氨氮废水的吸附性能、洗脱蒸氨曲线和斜发沸石在氢氧化钙溶液中的损失。实验结果表明:钙型斜发沸石对铵离子具有很高的选择性和离子交换能力。可长期在氢氧化钙溶液中使用。该方法具有投资低、高效、节能、操作稳定等特点。在处理废水的同时又可回收氨,可创造一定的经济效益。具有较好的应用价值。 相似文献
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钙型斜发沸石铵离子交换平衡的研究 总被引:6,自引:0,他引:6
测定了在不同pH值下人工改型所得钙型斜发沸石对NH4^ 的全交换容量、对NH4^ 的等温交换平衡曲线,进一步研究了其部分热力学特性。结果表明,钙型斜发沸石对NH4^ 交换总量随pH值的升高而降低,在pH值为7时为79.321mmol/100g,该离子交换过程可自发进行,且其选择性随温度的升高而降低。研究成果可为沸石法处理含氨氮废水的进一步研究提供一定的理论依据。 相似文献
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