全文获取类型
收费全文 | 502篇 |
免费 | 42篇 |
国内免费 | 219篇 |
专业分类
安全科学 | 8篇 |
废物处理 | 4篇 |
环保管理 | 74篇 |
综合类 | 353篇 |
基础理论 | 228篇 |
污染及防治 | 29篇 |
评价与监测 | 13篇 |
社会与环境 | 29篇 |
灾害及防治 | 25篇 |
出版年
2024年 | 3篇 |
2023年 | 9篇 |
2022年 | 21篇 |
2021年 | 24篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 20篇 |
2017年 | 25篇 |
2016年 | 34篇 |
2015年 | 23篇 |
2014年 | 34篇 |
2013年 | 60篇 |
2012年 | 44篇 |
2011年 | 42篇 |
2010年 | 46篇 |
2009年 | 31篇 |
2008年 | 21篇 |
2007年 | 35篇 |
2006年 | 37篇 |
2005年 | 24篇 |
2004年 | 22篇 |
2003年 | 29篇 |
2002年 | 17篇 |
2001年 | 17篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 14篇 |
1997年 | 11篇 |
1996年 | 11篇 |
1995年 | 10篇 |
1994年 | 8篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有763条查询结果,搜索用时 31 毫秒
91.
Influence of Indian mustard (Brassicajuncea) on rhizosphere soil solution chemistry in long-term contaminated soils: A rhizobox study 总被引:1,自引:0,他引:1
This study investigated the influence of Indian mustard (Brassica juncea) root exudation on soil solution properties (pH, dissolved
organic carbon (DOC), metal solubility) in the rhizosphere using a rhizobox. Measurement was conducted following the cultivation
of Indian mustard in the rhizobox filled four di erent types of heavy metal contaminated soils (two alkaline soils and two acidic
soils). The growth of Indian mustard resulted in a significant increase (by 0.6 pH units) in rhizosphere soil solution pH of acidic
soils and only a slight increase (< 0.1 pH units) in alkaline soils. Furthermore, the DOC concentration increased by 17–156 mg/L
in the rhizosphere regardless of soil type and the extent of contamination, demonstrating the exudation of DOC from root. Ion
chromatographic determination showed a marked increase in the total dissolved organic acids (OAs) in rhizosphere. While root exudates
were observed in all soils, the amount of DOC and OAs in soil solution varied considerably amongst di erent soils, resulting in
significant changes to soil solution metals in the rhizosphere. For example, the soil solution Cd, Cu, Pb, and Zn concentrations increased
in the rhizosphere of alkaline soils compared to bulk soil following plant cultivation. In contrast, the soluble concentrations of Cd, Pb,
and Zn in acidic soils decreased in rhizosphere soil when compared to bulk soils. Besides the influence of pH and DOC on metal
solubility, the increase of heavy metal concentration having high stability constant such as Cu and Pb resulted in a release of Cd and
Zn from solid phase to liquid phase. 相似文献
92.
A controlled hydroponic experiment was undertaken to investigate Cd uptake in relation to the activity of Cd species in solution other than the free ion (Cd2+) by maintaining a constant Cd2+ activity under variable SO42− and Cl− concentrations exposed to maize (Zea mays var. Cameron) plants. The objectives of these experiments were: (1) to distinguish and quantify the different uptake rates of free and inorganic-complexed Cd from nutrient solution, and (2) to model the uptake of Cd by maize with a Biotic Ligand Model (BLM) in a system which facilitates the close examination of root characteristics. Results of the current experiments suggest that, in addition to the free ion, CdSO40 complexes are important factors in determining Cd uptake in nutrient solution by maize plants. Higher nominal SO42− concentrations in solution generally resulted in a greater Cd accumulation by maize plants than predicted by the Cd2+ activity. A better integration of the complete dataset for the 3 harvest times (6, 9 and 11 days after treatment) was achieved by including consideration of both the duration of Cd exposure and especially the root surface area to express Cd uptake. Similarly, the fit of the BLM was also improved when taking into account exposure time and expressing uptake in terms of root morphological parameters. 相似文献
93.
Marek K. Jarecki Timothy B. Parkin Alvarus S.K. Chan Thomas C. Kaspar Thomas B. Moorman Jeremy W. Singer Brian J. Kerr Jerry L. Hatfield Raymond Jones 《Agriculture, ecosystems & environment》2009,134(1-2):29-35
Agriculture contributes 40–60% of the total annual N2O emissions to the atmosphere. Development of management practices to reduce these emissions would have a significant impact on greenhouse gas levels. Non-leguminous cover crops are efficient scavengers of residual soil NO3, thereby reducing leaching losses. However, the effect of a grass cover crop on N2O emissions from soil receiving liquid swine manure has not been evaluated. This study investigated: (i) the temporal patterns of N2O emissions following addition of swine manure slurry in a laboratory setting under fluctuating soil moisture regimes; (ii) assessed the potential of a rye (Secale cereale L.) cover crop to decrease N2O emissions under these conditions; and (iii) quantified field N2O emissions in response to either spring applied urea ammonium nitrate (UAN) or different rates of fall-applied liquid swine manure, in the presence or absence of a rye/oat winter cover crop. Laboratory experiments investigating cover crop effects N2O emissions were performed in a controlled environment chamber programmed for a 14 h light period, 18 °C day temperature, and 15 °C night temperature. Treatments with or without a living rye cover crop were treated with either: (i) no manure; (ii) a phosphorus-based manure application rate (low manure): or (iii) a nitrogen-based manure application rate (high manure). We observed a significant reduction in N2O emissions in the presence of the rye cover crop. Field experiments were performed on a fine-loamy soil in Central Iowa from October 12, 2005 to October 2, 2006. We observed no significant effect of the cover crop on cumulative N2O emissions in the field. The primary factor influencing N2O emission was N application rate, regardless of form or timing. The response of N2O emission to N additions was non-linear, with progressively more N2O emitted with increasing N application. These results indicate that while cover crops have the potential to reduce N2O emissions, N application rate may be the overriding factor. 相似文献
94.
我国主要蔬菜和粮油作物的砷含量与砷富集能力比较 总被引:19,自引:0,他引:19
根据国内外文献报道,对蔬菜和粮油作物中砷的累积特点和富集能力进行总结和分析.结果表明.清洁区和污染区蔬菜的砷含量变幅分别为0.001-1.07 mg·kg-1和0.001-8.51 mg·kg-1(鲜重),均值分别为0.035 mg·kg-1和0.068 mg·kg-1不同种类蔬菜的砷含量由大到小,依次为:叶菜类>根茎类>茄果类>鲜豆类;清洁区和污染区粮油作物的砷含量变幅分别为0.001-2.20 mg·kg-1和0.007-6.83 mg·kg-1(干重),均值分别为0.081 mg·kg-1和0.294 mg·kg-1,其中水稻的砷含量显著高于小麦和玉米.从富集系数来看,叶莱类蔬菜的砷富集系数最高,芹菜、蕹菜、茼蒿、芥菜等蔬菜的抗砷污染能力较弱.粮食作物玉米的抗砷污染能力较强.与蔬菜砷限量标准(GB4810-1994)相比,我国砷污染区的蔬菜中有32.2%的样本砷含量超标,其中叶菜类和根茎类的超标率分别为47.9%和12.8%.与粮食砷限量标准(GB4810-1994)比较,我国污染区粮油作物的样本砷超标率为34.8%,其中水稻的超标率高达42.9%.玉米和小麦的超标率均高于20%. 相似文献
95.
库布齐沙漠油蒿灌丛土壤呼吸速率时空变异特征研究 总被引:4,自引:0,他引:4
利用Li-840红外气体分析仪和Li-6400-09土壤呼吸气室组装而成的动态密闭土壤呼吸测定系统,于2006年生长季对内蒙古库布齐沙漠油蒿(Artemisia ordosica)生态系统2种不同类型土壤的土壤呼吸速率进行了野外测定,分析了日动态、季节动态及其对环境因子的响应,并阐述了油蒿灌丛空间异质性的特征.结果表明,油蒿灌丛的土壤呼吸速率日动态呈单峰曲线,在12:00左右有最大值.在适宜的水分和温度条件下,生长季里土壤呼吸速率在7~8月份出现最大值.土壤呼吸速率的季节动态与土壤含水量有显著的相关关系,表明水分是限制生长季干旱区灌丛土壤呼吸的最重要因子,分别可以解释油蒿冠幅下土壤和裸地的土壤呼吸速率2006年主要生长季节(5~9月)变化的75%和77%.油蒿灌丛土壤呼吸速率在空间尺度上存在着显著的异质性.油蒿冠幅覆盖下的土壤呼吸速率季节平均值为(155.58±15.20) mg·(m2·h)-1,要显著地大于灌丛间裸地的数值(110.50±6.77) mg·(m2·h)-1.2种不同类型土壤的土壤呼吸速率是由于根生物量的差异引起的,根生物量可以解释2006年生长季库布齐油蒿灌丛土壤呼吸速率空间异质性的43%.结果表明,在植被覆盖度异质性较大的灌丛生态系统中,要准确定量生态系统碳的释放时,必须充分考虑小尺度上土壤呼吸的空间异质性. 相似文献
96.
A. Araya P.V.V. Prasad P.H. Gowda I. Kisekka A.J. Foster 《Journal of the American Water Resources Association》2019,55(1):24-37
The Agricultural Production Systems sIMulator model validated in a prior study for winter wheat was used to simulate yield, aboveground crop biomass (BM), transpiration (T), and evapotranspiration under four irrigation capacities (ICs) (0, 1.7, 2.5, and 5 mm/day) with two nitrogen (N) application rates (N1, 94 kg N/ha; N2, 160 kg N/ha) to (1) understand the performance of winter wheat under different ICs and (2) develop crop water production function under various ICs and N rates. Evaluation was based on yield, aboveground crop BM, transpiration productivity (TP), crop water productivity (WP), and irrigation WP (IWP). Simulation results showed winter wheat yield increased with increase in N application rate and IC. However, the rate of yield increase gradually reduced with additional irrigation beyond 2.5 mm/day. A 5 mm/day IC required a total of 190 mm irrigation and produced a 5%–16% yield advantage over 2.5 mm/day. This indicates it is possible to reduce groundwater use for wheat by 50% incurring only 5%–16% yield loss relative to 5 mm/day. The TP and IWP for grain were slightly higher under IC of 1.7 mm/day (15.2–16.1 kg/ha/mm and 0.98–1.6 kg/m3) when compared to 5 mm/day (14.7–15.5 kg/ha/mm and 0.6–1.06 kg/m3), respectively. Since TP and IWPs are relatively higher under lower ICs, winter wheat could be a suitable crop under lower ICs in the region. Relationship between yield–T and yield–ET was linear with a slope of 15–16 and 9.5–10 kg/ha/mm, respectively. Editor's note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series. 相似文献
97.
通过在所构建的3组垂直流人工湿地(CW1、CW2、CW3)中添加不同ρ(DOC)(0、14、28 mg/L,DOC为溶解性有机碳)的美人蕉根系浸出液来模拟根系分泌物浓度变化,考察其对2种SEs(steroidal estrogens,类固醇雌激素)去除效果的影响. 结果表明:①虽然根系浸出液和根系分泌物中的ρ(DOC)存在差异,但二者成分比例类似,均含有多种小分子化合物(如氨基酸、多糖、有机酸、脂肪酸、醇、烷等),并且甘油含量均为最高. ②各组湿地对SEs的去除率表现为CW2>CW3≈CW1,CW2对E1(Estrone,雌酮)、EE2(17α-Ethinylestradiol,17α-乙炔基雌二醇)的去除率最高可分别达到86.9%、72.7%. ③各组湿地全细菌和AOB(ammonia oxidizing bacteria, 氨氧化细菌)平均密度大小表现为CW3>CW2>CW1,NOB(nitrite oxidation bacteria, 亚硝酸氧化细菌)平均密度大小表现为CW2>CW3>CW1,DNB(denitrifying bacteria, 反硝化细菌)平均密度大小表现为CW3>CW1≈CW2,各组湿地基质上生物膜的脱氢酶活性表现为CW2>CW1>CW3.研究显示,适量添加根系浸出液有利于SEs的去除,但根系浸出液中ρ(DOC)过高,可能会对植物根系和特定根系微生物(如NOB)的生长造成毒害作用,并抑制微生物活性,从而影响SEs的去除效果. 相似文献
98.
石油污染土壤物化修复前后生物毒性效应 总被引:2,自引:2,他引:0
采用作物种子的发芽率作为生态指标对石油污染土壤进行毒性分析,并以蚯蚓为实验生物,研究了石油污染物的生物效应及其对土壤生态系统的影响.结果表明,不同的作物种子对石油污染表现出不同的耐受性,对照清洁土壤,大多数作物种子的萌发都明显受到石油污染的抑制,其中受石油污染影响最严重的是黄豆、蚕豆、玉米.相比之下,在不同石油污染水平下绿豆具有较高的耐受性,且种子发芽率均在90%以上.蚯蚓在受到污染胁迫时,在生理水平上会发生明显的变化,进而影响其存活和生长能力,实验观测到随着石油污染加重蚯蚓存活时间显著下降.在高污染水平石油污染的土壤中(石油污染水平>30 000 mg.kg-1),蚯蚓的耐性降低,仅可以存活5 d左右,说明石油烃对蚯蚓的毒性较大,主要是因为蚯蚓直接与石油接触导致其中毒脱水而死亡.处理后油田污染土,即使在污染水平很低(≈30 mg.kg-1)的情况下,蚯蚓存活时间依然很短(3 d左右),是因为经过石油醚处理过的土壤,其营养物质也随着石油而被处理掉,而土壤中有机质等营养物对蚯蚓的生存具有很大影响. 相似文献
99.
UV-B辐射对大豆和黄瓜幼苗某些生理特性的影响 总被引:19,自引:2,他引:17
在植物生长室中,UV- B辐射明显降低黄瓜幼苗的根系活力,抑制程度随辐射时间的延长而增强.黄瓜和大豆幼苗的叶绿素和可溶性蛋白含量减少与UVB辐射时间长短呈正相关,但是类胡萝卜素减少幅度不大.UVB对Chlb 的破坏较Chla 严重,导致Chlab 比值增大.UVB虽增加大豆幼苗的SOD活性,但降低大豆幼苗的NR活性及其对温度变化的敏感性.分析认为,Chlab 比值和SOD 活性升高,有助于植物对UVB的适应 相似文献
100.
Upton Hatch Shrikant Jagtap Jim Jones Marshall Lamb 《Journal of the American Water Resources Association》1999,35(6):1551-1561
ABSTRACT: Climate change has the potential to have dramatic effects on the agricultural sector nationally and internationally as documented in many research papers. This paper reports on research that was focused on a specific crop growing area to demonstrate how farm managers might respond to climate-induced yield changes and the implications of these responses for agricultural water use. The Hadley model was used to generate climate scenarios for important agricultural areas of Georgia in 2030 and 2090. Linked crop response models indicated generally positive yield changes, as increased temperatures were associated with increased precipitation and CO2. Using a farm management model, differences in climate-induced yield impacts among crops led to changes in crop mix and associated water use; non-irrigated cropland received greater benefit since irrigated land was already receiving adequate moisture. Model results suggest that farm managers will increase cropping intensity by decreasing fallowing and increasing double cropping; corn acreage decreased dramatically, peanuts decreased moderately and cotton and winter wheat increased. Water use on currently irrigated cropland fell. The potential for increased water use through conversion of agriculturally important, but currently non-irrigated, growing areas is substantial. 相似文献