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The novel carbon dioxide(CO2) adsorbents with a high capture effciency were prepared through impregnating the as-synthesized MCM-41 with three kinds of amines,namely diethylenetriamine(DETA) ,triethylenetetramine(TETA) and 2-amino-2-methyl-1-propanol(AMP) .The resultant samples were characterized by small angle X-ray diffraction and low temperature N2 adsorption.The synthesis way not only saves the energy or extractor to remove the template but also is environmentally friendly due to the absence of the potential pollutants such as toluene.CO2 capture was investigated in a dynamic packed column.The sample impregnated by TETA showed the highest adsorption capacity,approximately 2.22 mmol/g at 60°C due to its highest amino-groups content among the three amines.The CO2 adsorption behavior was also investigated with the deactivation model,which showed an excellent prediction for the breakthrough curves. 相似文献
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TiO2晶须在深度净化饮用水过程中失活原因分析 总被引:1,自引:0,他引:1
研究了TiO2晶须在光催化深度净化饮用水过程中失活的原因及相应的再生方法.对TiO2薄膜失活前后的AFM、XRD表征,以及对失活前后TiO2晶须酸洗液的ICP分析表明,TiO2晶须失活的主要原因是难溶性碳酸钙在催化剂表面的沉积.由于自来水中钙离子的存在以及有机物光催化降解过程中产生的二氧化碳,生成的难溶性碳酸钙覆盖在催化剂的表面,影响了紫外光的透光率,限制了光生电子和光生空穴的生成,导致催化剂的光催化能力逐渐下降直至失活;失活的催化剂通过1 mol/L的盐酸酸洗4 h后,光催化活性可以恢复到95%左右;多次失活/再生的催化剂的光催化活性保持较好的稳定性. 相似文献
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The herbicide paraquat belongs to the group of the bipyridylium salts. In California, it is used primarily for control of broad-leaved grasses in fruit orchards and plantations, as a cotton defoliant, and for inter-row control in many crop and non-crop areas. In plants, paraquat causes the formation of reactive radicals leading to cell membrane damage and ultimately rapid desiccation. Soil clay minerals have a greater influence on paraquat adsorption and inactivation compared with soil organic matter following an application. Degradation mechanisms include photolysis, chemical, and microbial degradation, but these processes are generally extremely slow. In California during 2000–2014, paraquat was used primarily for the cultivation of almonds, cotton, alfalfa, and grapes: median value for an application and annual mass applied statewide were 0.53 kg ion/ha and 280 Mg, respectively. Paraquat was undetected in groundwater as a non-point source pollutant. Detections in surface waters (0.42–3.6 μg/L) were <1%. In earthworms and other invertebrates there is limited paraquat accumulation as toxic effects are mitigated via soil inactivation. Paraquat is among the most embryotoxic contaminants for bird eggs, but not to adult; it causes toxic and teratogenic effects in amphibians, and toxic effects in honeybees, fish, and other aquatic species. 相似文献
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TiO2 nanotubes (TiNT) were prepared by a hydrothermal treatment and modified by three kinds of amines,namely ethylenediamine,polyetherimide and tetraethylenepentamine (TEPA),to study their CO2 adsorption properties from gas streams.The resultant samples were characterized by X-ray diffraction,transmission electron microscopy,and infrared spectroscopy,as well as low temperature N 2 adsorption.CO2 capture was investigated in a dynamic packed column at 30℃.TEPA-modified TiO2 nanotubes showed the highest adsorption capacity of 167.64 mg/g because it had the highest amino-group content among the three amines.CO2 fixation on TiNT impregnated by TEPA was investigated at 30,50,and 70℃,and the adsorption capacity increased slightly with temperature.Following the adsorption step,the sorbents were regenerated by temperature programmed desorption,and the TiNT-TEPA sample,as CO2 sorbent,was found to be readily regenerated and energy-efficient.The cycle test also revealed that the TiNT-TEPA adsorbent is fairly stable,with only a 5% drop in the adsorption capacity after 10 adsorption/desorption cycles.In addition,the CO2 adsorption behavior was investigated with the deactivation model,and which showed an excellent prediction for the TiNT-TEPA breakthrough curves. 相似文献
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宁南霉素对烟草花叶病毒的生物活性 总被引:6,自引:2,他引:6
研究了宁南霉素 (Ningnanmycin)对烟草花叶病毒 (tobaccomosaicvirus,TMV)的预防、治疗和钝化作用 .结果表明 ,宁南霉素喷施 5d后接种TMV ,对烟草花叶病毒的预防效果为 5 8.4 1% ;宁南霉素浓度为 15 0~ 2 0 0 μg/mL时 ,对烟草花叶病毒的治疗效果达 79.6 5 %~ 84 .96 % ,治疗效果最好为接种TMV 1d后喷施 2 0 0 μg/mL宁南霉素 ;宁南霉素对烟草花叶病毒的钝化效果为 76 .99%~ 83.19% ,混合 4 5min的TMV与宁南霉素等体积混合液效果更好 .试验证明 ,宁南霉素对烟草花叶病有很好的治疗作用 ,对烟草花叶病毒有显著的钝化效果 .图 1表 3参 15 相似文献
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以TiO2(P25)为催化剂,研究了玻璃平板反应器在室内典型冬季工况紫外光催化降解甲苯的特性。甲苯的初试浓度为0~14mg/m3。实验发现,随着浓度的增大,甲苯的降解速率先增加,在达到一个最大值后急剧减小。一个考虑了催化剂钝化的动力学模型能很好的解释这种现象。文章提出了钝化区、最大反应速率、抑止浓度等概念,对光催化型净化器的设计与选用有非常重要的指导意义。 相似文献