全文获取类型
收费全文 | 2241篇 |
免费 | 464篇 |
国内免费 | 196篇 |
专业分类
安全科学 | 343篇 |
废物处理 | 18篇 |
环保管理 | 592篇 |
综合类 | 456篇 |
基础理论 | 923篇 |
环境理论 | 1篇 |
污染及防治 | 234篇 |
评价与监测 | 19篇 |
社会与环境 | 176篇 |
灾害及防治 | 139篇 |
出版年
2024年 | 1篇 |
2023年 | 29篇 |
2022年 | 47篇 |
2021年 | 60篇 |
2020年 | 60篇 |
2019年 | 104篇 |
2018年 | 105篇 |
2017年 | 164篇 |
2016年 | 154篇 |
2015年 | 151篇 |
2014年 | 140篇 |
2013年 | 446篇 |
2012年 | 167篇 |
2011年 | 192篇 |
2010年 | 130篇 |
2009年 | 112篇 |
2008年 | 104篇 |
2007年 | 118篇 |
2006年 | 86篇 |
2005年 | 52篇 |
2004年 | 55篇 |
2003年 | 70篇 |
2002年 | 87篇 |
2001年 | 67篇 |
2000年 | 67篇 |
1999年 | 30篇 |
1998年 | 18篇 |
1997年 | 16篇 |
1996年 | 17篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有2901条查询结果,搜索用时 265 毫秒
991.
A procedure has been developed for the analysis of metsulfuron‐methyl in the soil of field crops. The soil extracts are cleaned by repeated TLC, and metsulfuron‐methyl is simultaneously separated from its soil metabolites. Metsulfuron‐methyl is transformed by diazomethane into its N,N ‘‐dimethyl derivative which in the GC (electron capture detection) and GC‐MS apparatus is transformed into a benzisothiazole compound which is measured with great sensitivity. The sensitivity limit is 0.3 μg metsulfuron‐methyl kg‐1 dry soil. The results of the chemical analyses are confirmed by bioassays using sugar beet as test plant. Metsulfuron‐methyl was measured in the soil of two winter wheat crops after post‐emergence application in the spring of 6 g metsulfuron‐methyl ha‐1. In the 0–8 cm surface soil layer, the metsulfuron‐methyl soil half‐life was 78 days in 1997, and 67 days in 1998. During crop, metsulfuron‐methyl remained in the 0–8 cm surface soil layer. There, it was at a maximum concentration and herbicide efficiency in a 2 cm‐thick soil layer. This maximum concentration soil layer progressively moved down during crop, attaining the 4–6 cm surface soil layer at crop end. After the winter wheat harvest at the end of July, and the rotary‐tilling of the 0–10 cm surface soil layer before sowing of the green manures, 27% of the metsulfuron‐methyl initial dose still remained in the 0–10 cm surface soil layer. This residue progressively disappeared, and was no more detected at the middle of November. It had no, or only very low inhibiting effect on the growth of the green manures. Thus there is no concern about the possible phytotoxicity of persistent metsulfuron‐methyl soil residues towards the following crops, when metsulfuron‐methyl is applied at the rate of 6 g a.i.ha‐1. 相似文献
992.
Male albino rats were administered Cd and HCH daily for six weeks to study the effect of Cd on storage and metabolism of HCH. The results indicated a marked inhibition of the metabolism of HCH in the group dosed with HCH + Cd. The metabolic rate of HCH in the group dosed with HCH + Cd was also significantly lower than that in the group dosed with HCH alone. The hepatic content of Cd and Zn was significantly increased whereas a marked depletion of Cu and Fe was observed in the groups exposed to Cd and HCH + Cd. A high level of free Cd and Zn or a low level of Fe and Cu in liver seemed to play an important role in the metabolic inhibition observed in this study. 相似文献
993.
Methylation of chlorimuron‐ethyl with etheral solution of diazomethane gave ethyl‐2‐[[[[(4‐chloro‐6‐methoxy‐2‐pyrimidinyl) N‐methylamino] carbonyl] N‐methylamino] sulfonyl] benzoate (dimethyl derivative of chlorimuron‐ethyl) as the major product along with 4‐chloro‐6‐methoxy‐2‐N‐methylamino pyrimidine, 2‐aminomethyl sulfonyl benzoic acid, ethyl‐2‐[(N‐methylamino) sulfonyl] benzoate, ethyl‐2‐[N,N‐dimethylamino) sulfonyl] benzoate and o‐benzoic sulf‐N‐methylimide as the minor products. 相似文献
994.
Land and resource managers often use detection–nondetection surveys to monitor the populations of species that may be affected by factors such as habitat alteration, climate change, and biological invasions. Relative to mark‐recapture studies, using detection–nondetection surveys is more cost‐effective, and recent advances in statistical analyses allow the incorporation of detection probability, covariates, and multiple seasons. We examined the efficacy of using detection–nondetection data (relative to mark‐recapture data) for monitoring population trends of a territorial species, the California Spotted Owl (Strix occidentalis occidentalis). We estimated and compared the finite annual rates of population change (λt) and the resulting realized population change (Δt) from both occupancy and mark‐recapture data collected over 18 years (1993–2010). We used multiseason, robust‐design occupancy models to estimate that territory occupancy declined during our study (Δt = 0.702, 95% CI 0.552–0.852) due to increasing territory extinction rates ( = 0.019 [SE 0.012]; = 0.134 [SE 0.043]) and decreasing colonization rates ( = 0.323 [SE 0.124]; = 0.242 [SE 0.058]). We used Pradel's temporal‐symmetry model for mark‐recapture data to estimate that the population trajectory closely matched the trends in territory occupancy (Δt = 0.725, 95% CI 0.445–1.004). Individual survival was constant during our study ( = 0.816 [SE 0.020]; = 0.815 [SE 0.019]), whereas recruitment declined slightly ( = 0.195 [SE 0.032]; = 0.160 [SE 0.023]). Thus, we concluded that detection–nondetection data can provide reliable inferences on population trends, especially when funds preclude more intensive mark‐recapture studies. Relación entre Ocupación y Abundancia en una Especie Territorial, el Búho Moteado de California 相似文献
995.
资源产权与道德的起源:演化博弈论的诠释 总被引:1,自引:0,他引:1
论文在一个演化经济学视角下考察资源产权和道德(以下简称为产权和道德)自生自发问题。首先,简略地梳理了产权生发研究的历史;介绍了应用博弈论,特别是演化博弈论研究产权生发问题的近况,并指出其不足之处在于博弈支付的社会经济学含义模糊和无法揭示行为博弈与博弈环境相互作用、共同演化的过程。其次,扩展了生物遗传学中适应度的概念,使其适于社会演化分析;分析了社会经济学适应度的构成及其与竞争类型的关系。第三,为了说明行为博弈与博弈环境之间的相互作用关系,在传统复制者动态方程组中,引入状态方程(或组)。第四,采用改进后的复制者动态方程组分析产权和道德自生自发的机理和过程,指出产权和道德都是人类无节制争斗和无约束生育的产物。最后,分析了洛克社会的三大不足,及其继续演化的动力。 相似文献
996.
M. Díaz-Jaramillo N. Sandoval R. Barra P. Gillet C. Valdovinos 《Chemistry and Ecology》2013,29(4):308-319
Reproductive and population-level responses are ecologically relevant diagnostic tools for revealing the cost of long-term tolerance to contaminants. Spatial density distribution, seasonal density, biomass, size frequency histograms and oocytes stages in Perinereis gualpensis (Polychaeta: Nereididae) from a highly anthropogenically impacted estuary (Lenga, south-central Chile) were compared with low-polluted estuaries (Tubul and Raqui). Spatial distribution showed that the highest P. gualpensis abundances occur in the central (middle) estuarine area, establishing them as suitable zones for comparisons of estuaries. Middle areas also showed differences among estuaries in terms of population and reproductive responses. Mature stage oocytes and juvenile recruitment limited to certain seasons and low adult survival led to significant low densities and biomasses in Lenga individuals (p?.05). Conversely, high densities and biomass, continuous recruitment and mature oocyte occurrence were observed in Tubul–Raqui estuaries. These results reflected population and reproductive differences among high- and low-polluted estuaries, suggesting that chronic pollution status in Lenga estuary is a factor to be considered when evaluating these responses. 相似文献
997.
Jacques Henry 《Disasters》2013,37(2):293-316
This paper proposes an inductive analysis of the decision as to whether to return or to relocate by persons in the State of Louisiana, United States, who evacuated after Hurricanes Katrina and Rita in August and September 2005, respectively. Drawing on interviews with evacuees in these events and extensive fieldwork in the impacted area, the paper seeks to identify the folk dimensions of the decision‐making process, assess their arrangements, and situate the process in the larger context of risk and resilience in an advanced society. It suggests that, despite the material and emotional upheaval experienced by affected persons, the decision‐making process is a rational endeavour combining a definite set of tightly interconnected factors, involving material dimensions and substantive values that can act in concert or in conflict. In addition, it indicates that there are significant variations by geographic areas, homeownership, and kind of decision. Some theoretical implications, practical measures, and suggestions for future research are examined. 相似文献
998.
Quantitative determination of dimethylselenide and dimethyldiselenide in the breath of mice after addition of different selenium compounds to the drinking water is described. Breath samples are collected with a cryogenic trap and analyzed by gas chromatography with atomic absorption spectrometric detection. Detection limits down to 0.2 ng/100 g body weight are obtained. The pulmonary excretion of selenium metabolites after oral administration via drinking water or after intraperitoneal injection appears to be negligible. The bioconversion of the different selenium species is discussed. 相似文献
999.
A model predictive of the potential mutagenicity of organic compounds was devised by relating mutagenicity data obtained in the Ames reversion test to molecular structure parameters describing their hydrophobic, topological, steric and electronic properties. These included second order valence molecular connectivity index, parachor, molar refraction and polarizability of electrons. A classification rule was calculated, by means of discriminant analysis, using a training set of 117 compounds of various chemical classes. There was agreement between experimental data and theoretical expectations for the majority of compounds (70.9%), with homogeneous figures among the different chemical classes under scrutiny. An exception was represented by halogenated aliphatics with up to 3 C atoms, the mutagenicity of which was poorly predicted by the structural analysis model. 相似文献
1000.
To check the effect of possible deposition of organic contaminants in northern regions of the Earth due to atmospheric transport snow samples were collected in early March in 6 places in Russia and 4 in Finland including arctic territories. GC‐MS was used as an analytical tool to identify and quantify individual organic compounds belonging to the various classes. As a result more than 250 compounds were detected. The possible presence of more than 100 other priority pollutants from the US EPA list was also screened. 相似文献