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951.
Yanqing Zhou Chenyang Liu Yili Wang Xiaolin Li Junyi Li Shuoxun Dong Haotian Hao Yao Tong 《环境科学学报(英文版)》2022,34(10):18-29
Bimetallic oxides composites have received an increasing attention as promising adsorbents for aqueous phosphate (P) removal in recent years. In this study, a novel magnetic composite MZLCO was prepared by hybridizing amorphous Zr-La (carbonate) oxides (ZLCO) with nano-Fe3O4 through a one-pot solvothermal method for efficient phosphate adsorption. Our optimum sample of MZLCO-45 exhibited a high Langmuir maximum adsorption capacity of 96.16 mg P/g and performed well even at low phosphate concentration. The phosphate adsorption kinetics by MZLCO-45 fitted well with the pseudo-second-order model, and the adsorption capacity could reach 79% of the ultimate value within the first 60 min. The phosphate adsorption process was highly pH-dependent, and MZLCO-45 performed well over a wide pH range of 2.0-8.0. Moreover, MZLCO-45 showed a strong selectivity to phosphate in the presence of competing ions (Cl−, NO3−, SO42−, HCO3−, Ca2+, and Mg2+) and a good reusability using the eluent of NaOH/NaCl mixture, then 64% adsorption capacity remained after ten recycles. The initial 2.0 mg P/L in municipal wastewater and surface water could be efficiently reduced to below 0.1mg P/L by 0.07 g/L MZLCO-45, and the phosphate removal efficiencies were 95.7% and 96.21%, respectively. Phosphate adsorption mechanisms by MZLCO-45 could be attributed to electrostatic attraction and the inner-sphere complexation via ligand exchange forming Zr/La-O-P, -OH and CO32− groups on MZLCO-45 surface played important roles in the ligand exchange process. The existence of oxygen vacancies could accelerate the phosphate absorption rate of the MZLCO-45 composites. 相似文献
952.
针对目前我国城市内河普遍遭到污染的问题,在分析影响内河水质因素的基础上,选取BOD5(五日生化需氧量)、CODcr(化学需氧量)、石油类、挥发酚、NH3-N(氨氮)、总磷等6个主要因素作为评价因子,建立了城市内河水质评价的投影寻踪分析模型,采用人口迁移算法对评价模型进行优化,并将该模型应用于南宁市10条内河水质的评价与排序。研究表明,用投影寻踪回归分析法进行水质评价,避免了传统评价方法由于主观原因造成的误差,评价结果合理可信、方法简单,为我国城市内河水质的评价提供了新途径。 相似文献
953.
本文通过对岷江干流(成都段)地表水和地下水的综合研究,分别提出了地表水污染防治对策和地下水水质防护措施,划分出了地表水防治不同时期的目标以及地下水开采管理目标。 相似文献
954.
为诠释尾矿库溃坝后水砂演进过程,提升尾矿库事故灾害应急处置能力,采用无人机倾斜摄影技术获取尾矿库全息影像,建立尾矿库三维数字高程模型,导入三维流体计算软件对尾矿库进行溃坝事故推演。结果表明:尾矿库实景三维模型能高精度还原尾矿库实际情况,尾矿库溃坝将淹没库区临时厂房建筑及下游村落;其中,上游沟谷临时厂房建筑水位高程最大达8 m,尾砂淤积厚度最高达10.5 m,下游沟谷村落水位高程最大达10 m,尾砂淤积厚度最高达2.5 m;通过对库区下游布设监测点,得出各监测点处水位高程和尾砂淤积厚度变化规律,分析溃坝主要影响区域。研究结果可为尾矿库风险防控、应急响应工作提供借鉴。 相似文献
955.
为阐明黄土高原典型区域土壤轻组有机碳(LFOC)和重组有机碳(HFOC)含量随土壤类型、土层和土地利用方式的变化规律,分析了从北向南依次分布的干润砂质新成土(神木)、黄土正常新成土(延安)和土垫旱耕人为土(杨凌)等典型土壤剖面(0~200 cm)LFOC和HFOC含量及分布特征。结果表明,从南到北,土壤LFOC和HFOC含量均显著下降 (P<0.05),整体来看,黄土高原典型区域土壤LFOC含量占有机碳比例偏低;LFOC含量及在土壤有机碳中的分配比例随土层加深而递减,其比例变化范围为1%~26%;土地利用方式对浅层土壤LFOC和HFOC含量影响较为显著,草地土壤0~60 cm土层LFOC和HFOC含量均高于同层次农田土壤(P<0.05),60 cm土层以下差异不显著;土壤LFOC和HFOC含量与微生物量碳、微生物量氮含量均呈极显著正相关关系(P<0.01),前者的相关性系数更高,分别为0.841和0.507,表明土壤LFOC与微生物关系非常密切,是土壤微生物重要的碳和能量来源,极易受土地利用方式和微生物活性影响,同时表明用LFOC的变化更能快速有效地说明土壤碳库的变化规律。 相似文献
956.
退耕还林工程(Sloping land conversion program, SLCP)可快速改变土地利用/覆被格局。论文以黄土高原典型沟壑区--陕西省安塞县为例,利用MSS/TM/ETM+卫星遥感影像,获取研究区6个时期土地利用/覆被的时空信息,通过统计模型,定量分析了研究区SLCP对土地利用/覆被格局的影响。草地、耕地及林地为研究区三大主要土地利用/覆被类型,研究区土地利用/覆被变化整体处于不平衡态势;整个研究时段内,耕地先增后减,整体减少38.4%;林地先减后增,整体增加4.36%;灌木林地和草地减少,而未成林造林地快速增加;SLCP显著加强了耕地的递减趋势,并大幅增加了未成林造林地面积,至2010年未成林造林地面积显著大于天然林地的面积。这些变化可能具有降低土壤侵蚀与产流量、改善土壤结构、增加土壤碳吸收等效应;SLCP能提高农民收入,且大部分农民支持SLCP;但其负面效应亦不可忽视。研究将有助于对SLCP效应的全面理解,并可为该区生态恢复工程的规划与决策及生态环境保护提供参考。 相似文献
957.
Martin H. David Erhard F. Joeres Eric D. Loucks Kenneth W. Potter Stuart S. Rosenthal 《Journal of the American Water Resources Association》1988,24(1):141-148
ABSTRACT: Water level fluctuations of the Great Lakes often have created regional controversies among the states and Canadian provinces that share this vast resource. Even though the 100-year range of their water levels is only four to five feet, episodes of high and low Great Lakes water levels have been a recurring problem throughout the twentieth century. The possibility of increased diversion and consumptive use has exacerbated the existing conflicts over how to manage this water resource. A research project evaluated the effects of interbasin diversion on the Great Lakes system and on the industries that depend on the maintenance of historical water levels, namely hydropower and commercial navigation. The simulation approach employed in this research and some of the important findings are presented. The approach is similar to that used in recent government studies of Great Lakes water level regulation. Several significant modifications were made specifically addressing the diversion issue. Aggregate annual impacts to hydropower and shipping resulting from a diversion of 10,000 cubic feet per second were found to vary from 60 to 100 million dollars. Increases in impacts as a function of diversion rate are nonlinear for the navigation industry. 相似文献
958.
Peter G. Ashton James B. Pickens Coryell Ohlander Bruce Benninghoff 《Journal of the American Water Resources Association》1980,16(4):738-744
ABSTRACT: Decisionmaking associated with the Nation's 1.7 billion acres of forest and range land has become increasingly complicated because of the rise in competition for resource use and in the awareness of environmental and social effects. This system analysis approach uses four models to synthesize pertinent masses of information into measures of economic, environmental, and social impacts. The system results can be used to help evaluate alternative national programs. The models are:
959.
研究土地利用变化与生态系统服务价值(ESV)的演变对优化喀斯特脆弱山区的土地资源配置和推进生态恢复具有重要意义。以贵州省瓮安县为例,利用2001年、2011年、2019年3期遥感影像数据,通过CA-Markov模型预测2027年土地利用格局,定量分析研究区2001—2027年土地利用和ESV的时空演变趋势。结果表明:瓮安县土地利用类型以林地和耕地为主,耕地向林地的转移较为剧烈,林地和建设用地面积持续增加,建设用地和水域的动态度最大;ESV总体呈上升趋势,耕地向林地转移是ESV增加的主要贡献项,ESV增加区域主要发生在瓮安县西部和东北部地区,未来ESV低值区仍分布在中部城镇地区;服务类型产生的ESV主要以土壤形成与保护服务为主,其次为水源涵养服务和生物多样性保护;林地和耕地是引起研究区ESV变化的敏感因子,研究区ESV对改进的价值系数缺乏弹性。研究期内瓮安县土地利用结构变化显著,生态系统服务价值明显提升。
相似文献960.
OUYANG Zhi-yun ZHAO Tong-qian WANG Ru-song Leif SDERLUND ZHANG Qiao-xian 《环境科学学报(英文版)》2004,16(5):765-769
Umited water resources, increasing demand, low use efficiency, and serious pollution result in severe water resource difficult in China. The evaluation of addressing water problems and the search for effective countermeasures that ensure sustainable water use are key to China‘ s sustainable development. The “compound water security“ consists of food security, life security, environmental security, and economic security. By establishing a conceptual model, the water security of China has been simulated in terms of four scenarios called BAU(the business-as-usual scenario), TEC(the technology and economics scenario), IVL(the institution, values, and lifestyles scenario) and TSD(toward sustainable development) in this paper. The results indicated that water crises, especially water shortages, are being experienced now and will continue to do so for a relatively long time in China and that it is possible to reach a basic balance between supply and demand of water and grain under the TSD developing pattern by a series of approaches including technological innovation, policy adjustments, and behaviour inducement. 相似文献