Hydrogen sulphide removal from landfill gas

Control of odours should be considered to be a fundamental issue in order to site, design and manage sanitary landfills. With regard to construction and demolition (C&;D) debris, landfilling was the mainly adopted solution in many European Countries; in particular, gypsum drywalls can produce high concentrations of hydrogen sulphide (H₂S) in landfill gas ranging from 7 ppm to 100 ppm. In some cases also dangerous concentrations until to 12,000 ppm were detected. In this paper H₂S removal efficiency in a lab-scale vertical packed scrubber was investigated. Hydrogen sulphide abatement was evaluated for inlet H₂S concentrations of 1000–100–10 ppm, adjusting scrubbing liquid pH in the range 9–12.5 by means of caustic soda (NaOH 2N solution). Moreover, best operating conditions for the system were defined as well as H₂S abatement along the tower and liquid recirculation effectiveness in case of inlet H₂S concentration of 10 ppm (typical odour concentration). Results showed that pH of 11.5 in scrubbing liquid could be considered the best value for removal of different inlet H₂S concentrations, also taking into account parasitical consumption of NaOH due to CO₂ absorption. Moreover, in case of continuous working of the system at H₂S concentration of 10 ppm, strong removal efficiency was already obtained with a packed bed height of about 70 cm. Significant performances were ensured after 1 h of constant activity, consuming about 3 ml of soda per cubic meter of polluted air. Subsequently liquid blowdown was necessary.     

道路车辆电气电子设备温度/湿度组合循环试验要点

温度/湿度组合循环试验本质上是一项气候环境的加速试验,失效较为集中。这里列出了若干关于试验的要点,供产品研发和试验人员把握。     

变频器故障波形预处理方法研究

电力电子设备在电力系统中的运用越来越广泛,其故障后对电力系统的运行影响也越来越大,从运行设备中提取波形用于诊断其相关故障的诊断方法的研究正在深入开展。由于现场采集波形的数据往往过于庞杂,不利于切中关键的故障特征,在研究用现场录波进行故障诊断前,首先要研究如何对实际采集的波形数据进行简化的方法。本文通过编制C＋＋程序,对故障录波简化过程进行了研究,并通过故障波形不同简化效果的对比说明了提高数据处理效率与减少波形特征损失的结合点的选取。     

2种UASB的ANAMMOX与反硝化协同作用对比研究

采用2套UASB-ANAMMOX反应器处理垃圾渗滤液,其中反应器2具有生物膜,对反应器在有机环境下的ANAMMOX与反硝化协同作用进行对比研究。在稳定期,反应器1和反应器2对氨氮、亚硝氮、TIN、COD的平均去除率分别为95.7%、95.9%、77.3%、70.3%和97.4%、96.4%、87.2%、74.8%。反应器1对TIN和COD最大容积去除率为112.2和107.7 g/(m3.d),反应器2对TIN和COD最大容积去除率为120.5和119.9 g/(m3.d)。结果表明,过高的负荷会对反应器产生抑制作用,且当抑制产生后协同作用难以恢复到原来水平。在厌氧氨氧化与反硝化协同作用良好时,pH值和碱度均存在特征性变化。总体上,反应器2比反应器1具有更强的厌氧氨氧化与反硝化协同作用和抗负荷冲击能力。     

Radiological hazards of TENORM in the wasted petroleum pipes

Disposal petroleum pipes containing sludge and scale as a technically enhanced natural occurring radioactive material (TENORM) leads to internal and external radiation hazards and then a significant radiation dose to the workers. In order to contribute to a future waste management policy related to the presence of TENORM in the disposal sites of wasted petroleum pipes, scale and sludge as TENORM wastes are collected form these disposal pipes for radiometric analysis. These pipes are imported from onshore oilfields at south Sinai governorate, Egypt. The highest mean ²²⁶Ra and ²²⁸Ra concentrations of 519 and 50 kBq/kg respectively, were measured in scale samples. Sludge lies within the normal range of radium concentration. The average absorbed dose caused by the exposure to the wasted pipes equal to 4.09 μGy h⁻¹ from sludge and 262 μGy h⁻¹ from scale. This is much higher than the acceptable level of 0.059 μGy h⁻¹. Due to radon inhalation, important radon related parameters are calculated which advantage in internal dose calculation. Fairly good correlation between real radium content and radon exhalation rate for sludge samples is obtained. The hazards from sludge come from its high emanation power for radon which equal to 3.83%. The obtained results demonstrate the need of screening oil residues for their radionuclide content in order to decide about their final disposal.     

电子与电器废弃物资源化处理技术

当今世界电子、电器工业快速发展,层出不穷的技术创新与持续膨胀的市场需求加速了电子与电器设备的更新换代,产生了大量的电子与电器废弃物(WEEE).鉴于WEEE所带来的严重的环境问题及其所含有的金属、贵金属、塑料及玻璃等高利用价值的材料,对WEEE进行资源化再循环处理已成为人们关注的热点.WEEE组成材料在密度、铁磁性、导电性等物理性质方面的较大差异使采用环境友好的机械物理方法对其进行资源化再循环处理成为可能.就WEEE拆解及其所含物质机械物理分离研究进展进行了综述.     

催化快速测定法测定高氯高浓度有机废液的化学需氧量

化学化工等行业产生大量含无机盐的高浓度难降解有机废水,介绍了氯离子浓度和有机物浓度都大大超过测定范围的有机废水COD的测定方法。该方法当氯离子的浓度在20000～60000mg/L时,相对误差在0.15%～5.8%之间;并有较高的精密度,6次平行测定的结果相对标准差<2%;加标回收率为99%～101%;与标准方法相比不存在显著性差异。     

机载电子元器件环境应力筛选初探

讨论了某直升机机载电子元器件在环境应力筛选过程中存在的主要问题及其解决方法。包括环境应力筛选的实施原则,筛选项目的确定,失效元器件分析情况及失效元器件的处理等问题。     

城市垃圾填埋场植树造林试验研究

通过在青岛湖岛垃圾场的现场试验,研究了城市垃圾填埋场上植树造林的方法、适宜树种的筛选以及影响树木成活和生长发育的主要因素。结果指出,垃圾中有机质发酵所产生的甲烷气体是抑制树木成活和生长的关键因素。覆土层除为树木提供支持和生存环境外,还能阻挡甲烷气体的逸出,因此,土层越厚,越有利于树木成活和生长。还对18种木本植物对甲烷气体的耐性进行了筛选。      

长江经济带工业来源危险废物污染与处理特征分析及监管对策建议

依据2017年环境统计数据, 分析了长江经济带工业危险废物的污染及处理特征:长江经济带危废产生 量较大的省份是江苏、浙江、云南、湖南和四川;危废种类主要是来源于化工、钢铁、有色和造纸行业的废酸、有色金属冶炼废物、废碱和焚烧处置残渣;各地对危废的处理情况各有优劣。根据以上特征,提出加强对重点 区域的监管和调度,针对特定行业和危废种类,建议出台最佳可行的处理技术,建立区域之间危废管理大平台,促进区域危废处理优势互补和均衡发展,挖掘企业自行处理能力,减轻危废集中处理压力。