SO2长期吸入对大鼠肺组织基因表达谱的影响

采用Affymetrix的基因芯片(RAE230A)技术,研究了SO2长期动态吸入(14mg/m3,1h/d,共30d)后大鼠肺组织基因表达谱的改变.结果表明,与对照组(CK)相比,SO2长期吸入后大鼠肺组织表达上调的基因有173个,其中包括79个已知基因和94个新基因,而表达下调的基因有85个,其中包括46个已知基因和39个新基因.表明:(1)长期吸入SO2的大鼠肺基因表达谱与其CK相比,表达有差异的基因涉及到脂肪酸代谢、免疫、炎症、氧化应激、原癌基因、肿瘤抑制基因和细胞外基质等,表明低剂量长期吸入SO2在体内的机理非常复杂;(2)SO2高剂量短期吸入与低剂量长期吸入后,大鼠肺组织基因表达谱的改变很不一致,表明二者在体内的作用机理不同;(3)SO2可引起多种基因的表达发生改变,这意味着多种基因的表达是易变的、不稳定的,在肺组织中可能存在着SO2诱发的表达不稳定型基因组.表1参19     

Ni2+金属结合肽的筛选和序列分析

利用噬菌体随机十二肽库对金属N i2 进行了结合肽筛选,经5轮生物淘洗、噬菌体扩增和DNA测序,获得8条多肽序列,分析发现其中富含组氨酸(4~6个/肽).结果表明,组氨酸的存在对蛋白质和金属N i2 的结合起着关键作用.图1表1参11     

乌鲁木齐市大气中SO2的灰色预测

根据灰色系统理论,联系乌鲁木齐市大气环境的实际状况,建立了精度检验为一级的灰色预测模型,并对大气中的SO2值进行了预测分析,结果表明,该预测模型具有较高的准确性、合理性和可信度.     

单甲脒盐酸盐农药在水体悬浮颗粒物上的吸附行为

用批量平衡法研究了单甲脒农药在三种水体悬浮颗粒物上的吸附规律，所得数据进行回分析后，发现吸附规律符合Ｆｒｅｕｎｄｉｌｉｃｈ方程，并且在悬浮颗粒物上的吸附能力随着颗粒物中有机碳含量的增加而稍有减少。     

单甲脒动物代谢的研究

采用气相色谱／傅立叶红外光谱和气相色谱／质谱仪分析大鼠肝脏中单甲脒的代谢产物，证明大鼠经口摄入单甲脒后，在肝脏中迅速代谢，其代谢中间产物为２，４－二甲基苯胺和含酰胺基的化全物。     

The use of the tergal gland defensive secretion in male intrasexual aggression of the rove beetle,Aleochara curtula (Coleoptera: Staphylinidae), measured by closed-loop-stripping-analyses and tandem bioassay — mass fragmentography

Summary 2-methyl-1,4-benzoquinone as a target compound of the tergal gland secretion of the rove beetle,Aleochara curtula, was quantified from the reservoirs of individual beetles. Males store less secretion than females, and they evaporate more of the secretion as measured by adsorption from the air (closed-loop-stripping-analysis). The amount of emitted quinone is increased during aggressive interactions of rival males. The pulsed emission of the secretion during aggression is demonstrated by a novel technique combining observation of behavior with the on-line measurement of target fragment ions by mass-spectrometry (tandem bioassay — mass fragmentography). The emission of the secretion is used as a weapon in combats between males and may result in the repulsion of subordinate males from the mating site, but may also serve to mimic females chemically in order to avoid aggressive encounters.     

拟面积多波长数据线性双组合解析萘,1—萘酚和2—萘酚同步荧光光谱的研究

本文研究了Δλ（λｅｍ－λｅｘ）为１３０ｎｍ和ＰＨ１２．０条件下，萘、１－萘粉和２－萘酚混合物的同步荧光光谱，获三者同步荧光峰信息，且萘被完全分辨，另外，提出用拟面积多波长线性双组合计算解析重叠的１－萘酚和２－萘酚同步荧光光谱，解析结果的精密度、组份间浓度比范围均较多波长线性回归、双峰增配平和一阶导数解析混合物同步荧光光谱结果为优。     

沈阳市区大气颗粒物元素组分及其分布

本研究采用美国安德逊五段冲击式采样器进行大气颗粒物采样，用中子活化法进行分析，获得４３种元素质量浓度，并求得各种元素的质量中值直径和几何标准差。     

A review of the chemical ecology of the Cerambycidae (Coleoptera)

Summary. This review summarizes the literature related to the chemical ecology of the Cerambycidae and provides a brief overview of cerambycid biology, ecology, economic significance, and management. Beetles in the family Cerambycidae have assumed increasing prominence as pests of forest and shade trees, shrubs, and raw wood products, and as vectors of tree diseases. Exotic species associated with solid wood packing materials have been notable tree killers in North American urban and peri-urban forests. In forested ecosystems native species respond to disturbances such as fires and windstorms, and initiate the biodeterioration of woody tissue. Eggs are laid by females, on or through the bark surface of stem and branch tissue of moribund, recently killed or decomposing woody plants; larval cerambycids (roundheaded woodborers) typically feed in the phloem and later in the xylem. Females will also, in some cases, select living hosts, e.g. adult conifer and angiosperm trees, for oviposition. Research on the chemical ecology of over 70 species has revealed many examples of attractive kairomones (such as floral volatiles, smoke volatiles, trunk and leaf volatiles, and bark beetle pheromones), repellents and deterrents, oviposition stimulants, short- and long-range sex pheromones, and defensive substances. Emerging generalities are that attractants tend to be monoterpenoids and phenolic esters; oviposition stimulants are monoterpenoids and flavanoids; short-range sex pheromones are female-produced, methyl-branched cuticular hydrocarbons; and long-range sex pheromones are male-produced -hydroxy ketones and (,)-diols ranging in length from 6 to 10 carbons. The latter compounds appear to originate from glands in the male thorax; putative defensive substances originate from metasternal secretory pores or mandibular glands. In one unusual case, a flightless, subterranean female that attacks sugar cane produces a sex pheromone that is derived from the amino acid isoleucine. With significantly more than 35,000 species of Cerambycidae worldwide, these generalities will be subject to change as more species are examined. Addendum The authors would like to point out that the electronic version is more accurate than the printed version.     

纳米TiO2光催化氧化异丙醇和丙酮反应的研究

分别研究了纳米TiO2 在主波长为 364nm的汞灯光照下催化氧化i C3H7OH和CH3COCH3水溶液的反应速率 .通过XRD ,TEM ,BET和FT IR PAS对催化剂进行表征 ,粉末的晶型主要为锐钛矿型 .平均粒径在 1 5nm左右 ,比表面积为 1 0 1 0± 0 2m2 ·g- 1 ,FT IR PAS的检测结果表明 ,CH3COCH3是i C3H7OH光催化氧化的中间产物 ,其光催化氧化反应为 :i C3H7OH [O]CH3COCH3[O]CH3COOH[O]…[O]CO2 H2 O